137 research outputs found
Cold collisions of C anions with Li and Rb atoms in hybrid traps
We present a theoretical investigation of reactive and non-reactive
collisions of Li and Rb atoms with C molecular anions at low
temperatures in the context of sympathetic cooling in hybrid trap experiments.
Based on recently reported accurate potential energy surfaces for the singlet
and triplet states of the Li-C and Rb-C systems, we show
that the associative electronic detachment reaction is slow if the colliding
partners are in their ground state, but fast if they are excited. The results
are expected to be representative of the alkali-metal series. We also
investigate rotationally inelastic collisions in order to explore the cooling
of the translational and rotational degrees of freedom of C in hybrid
ion-atom traps. The effect of micromotion is taken into account by considering
Tsallis distributions of collision energies. We show that the translational
cooling occurs much more rapidly than rotational cooling and that the presence
of excited atoms leads to losses of anions on a timescale comparable to that of
rotational cooling.Comment: ICPEAC 2019 conferenc
Ab initio calculation of the 66 low lying electronic states of HeH: adiabatic and diabatic representations
We present an ab initio study of the HeH molecule. Using the quantum
chemistry package MOLPRO and a large adapted basis set, we have calculated the
adiabatic potential energy curves of the first 20 , 19
, 12 , 9 , 4 and 2 electronic
states of the ion in CASSCF and CI approaches. The results are compared with
previous works. The radial and rotational non-adiabatic coupling matrix
elements as well as the dipole moments are also calculated. The asymptotic
behaviour of the potential energy curves and of the various couplings between
the states is also studied. Using the radial couplings, the diabatic
representation is defined and we present an example of our diabatization
procedure on the states.Comment: v2. Minor text changes. 28 pages, 18 figures. accepted in J. Phys.
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Supplemental material: Dynamics of the isotope exchange reaction of D with H3+, H2D+, and D2H+
No abstract has been provided for this article at this time
Noise estimation in cardiac x-ray imaging: a machine vision approach
YesWe propose a method to automatically parameterize noise in cardiac x-ray image
sequences. The aim was to provide context-sensitive imaging information for
use in regulating dose control feedback systems that relates to the experience
of human observers. The algorithm locates and measures noise contained in
areas of approximately equal signal level. A single noise metric is derived from
the dominant noise components based on their magnitude and spatial location
in relation to clinically relevant structures. The output of the algorithm was
compared to noise and clinical acceptability ratings from 28 observers viewing
40 different cardiac x-ray imaging sequences. Results show good agreement and
that the algorithm has the potential to augment existing control strategies to
deliver x-ray dose to the patient on an individual basis.This work has been performed in the project PANORAMA, funded by grants 335 from Belgium, Italy, France, the Netherlands, United Kingdom, and the ENIAC Joint Undertaking
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