Atomic layer deposited protective layers

This paper reviews the use of Atomic Layer Deposition (ALD) in protective coatings. Because of the growth principle ALD allows the deposition of dense conformal films on substrates of different size and shape. Recently, ALD has received increasingly interest in deposition of protective coatings. In protective coatings oxides are the most common materials and especially Al, Ti, and Ta oxides have been applied. The use of nanolaminates enables improving the protection properties. Since ALD films are pinhole-free and often thin they are used to protect against moisture, radiation, out-gassing but not often against corrosion of metals. Very good moisture barriers are obtained with thin ALD oxide layers on polymers and cardboard. This property is also very attractive in encapsulation of OLEDs. In studies of energy technology materials protection of electrodes in Li-ion batteries, fuel cells and supercapacitors by ALD has been reported and significant improvement in the stability has been achieved. Yet another area is protection of silver jewelry from tarnishing by a thin oxide layer. In traditional corrosion protection of metals ALD films have proven to be useful in tailoring of interfaces and sealing of defects in coatings made by other techniques. © 2017 Trans Tech Publications, Switzerland.Peer reviewe

Coating and functionalization of high density ion track structures by atomic layer deposition

In this study flexible TiO 2 coated porous Kapton membranes are presented having electron multiplication properties. 800 nm crossing pores were fabricated into 50 m thick Kapton membranes using ion track technology and chemical etching. Consecutively, 50 nm TiO 2 films were deposited i nto the pores of the Kapton membranes by atomic layer deposition using Ti( i OPr) 4 and water as precursors at 250 °C. The TiO 2 films and coated membranes were studied by scanning electro n microscopy (SEM), X - ray diffraction (XRD) and X - ray reflectometry (XRR). Au metal electrod e fabrication onto both sides of the coated foils was achieved by electron beam evaporation. The electron multipliers were obtained by joining 3 two coated membranes separated by a conductive spacer. The results show that electron multiplication can be achie ved using ALD - coated flexible ion track polymer foils

Eräiden rikkakasvihävitteiden teho perunalla

Compared to the untreated control the use fo various herbicides has given yield increases of 6 11 tons per hectare. Prometryne (Gesagard 50) and terbutryne (Igran 50) gave highly significant differences in results compared to the untreated control. The effects of various chemicals, however, did not differ from each other significantly. On the average, the best weed control and highest yield increases were obtained with linuron, followed by terbutryne and prometryn. Results of MCPA and cyanazine were not as good. Prometryne and cyanazine did not have an equally good effect on weeds, and probably for this reason, they did not give good yield results consistently

Europium substitution effects in superconducting YBa2Cu4O8 synthesized under one atmosphere oxygen pressure

Y1−xEuxBa2Cu4O8 powder samples, with x=0, 0.25, 0.5, 0.75, and 1.0, were synthesized at ambient pressure using either an acetate-tartrate sol-gel method or a LiF flux process. The lattice parameters and purity of the samples were checked using X-ray diffraction. The superconducting transition was monitored by magnetic-susceptibility measurements. Replacing yttrium with europium increased the unit-cell volume, decreased the orthorhombicity (b/a) and the critical temperature. The hyperfine interactions at the europium site were studied by Eu151 Mössbauer spectroscopy. The complete quadrupole Hamiltonian of the 21.5-keV γ transition of Eu151 was successfully applied in the analyses of the Mössbauer spectra. The Mössbauer parameters obtained were found to resemble those measured for the EuBa2Cu3Cu3O7−δ (1:2:3) system. It was demonstrated that magnetic alignment of the crystallites could not be obtained with an 11.7-T field, contrary to the 1:2:3 and other high-Tc systems. The magnetic susceptibility for 1:2:4 single crystals appears to be isotropic.Peer reviewe

Ultrathin Oxide Films by Atomic Layer Deposition on Graphene

In this paper, a method is presented to create and characterize mechanically robust, free standing, ultrathin, oxide films with controlled, nanometer-scale thickness using Atomic Layer Deposition (ALD) on graphene. Aluminum oxide films were deposited onto suspended graphene membranes using ALD. Subsequent etching of the graphene left pure aluminum oxide films only a few atoms in thickness. A pressurized blister test was used to determine that these ultrathin films have a Young's modulus of 154 \pm 13 GPa. This Young's modulus is comparable to much thicker alumina ALD films. This behavior indicates that these ultrathin two-dimensional films have excellent mechanical integrity. The films are also impermeable to standard gases suggesting they are pinhole-free. These continuous ultrathin films are expected to enable new applications in fields such as thin film coatings, membranes and flexible electronics.Comment: Nano Letters (just accepted

Assessing the utilization of the decision to implement a palliative goal for the treatment of cancer patients during the last year of life at Helsinki University Hospital : a historic cohort study

Background: To avoid aggressive treatments at the end-of-life and to provide palliative care (PC), physicians need to terminate futile anti-cancer treatments and define the palliative goal of the treatment in time. This single center study assesses the practices used to make the decision that leads to treatment with a palliative goal, i.e., the PC decision and its effect on anti-cancer treatments at the end of life. Material and methods: Patients with a cancer diagnosis treated in tertiary hospital during 1st January 2013 - 31st December 2014 and deceased by the end of 2014 were identified in the hospital database (N = 2737). Of these patients, 992 were randomly selected for this study. The PC decision was screened from patient records, i.e., termination of cancer-specific treatments and a focus on symptom-centered PC. Results: The PC decision was defined in 82% of the patients during the last year of life (49% >30 days and 33%Peer reviewe

Syysviljojen talvituhosienien torjunta PCNB:llä

Tehdyissä kokeissa vuosina 1966—69 on Kotkaniemen koetilalla Vihdissä saatu PCNB-käsittelyllä useimmiten huomattavia sadonlisäyksiä rukiilla ja syysvehnällä. Alustavat kokeet osoittavat, että 50 %:sen PCNB-ruiskutejauheen, joka sisältää täyteaineena ammoniumsulfaattia, levitys alkutalven löyhälle lumelle tai sijoitus lumen läpi rivilannoituskoneella lannoitteeseen sekoitettuna maan pinnalle, antaa yhtä hyviä tuloksia kuin ennen lumen tuloa tapahtunut levityskin

Songs and Writings : Oral and Literary Cultures in Early-Modern Finland

Laulut ja kirjoitukset: suullinen ja kirjallinen kulttuuri uuden ajan alun Suomessa (Songs and writings: oral and literary culture in early-modern Finland) has been written at the crossroads of historical and folkloristic studies. Our purpose is to study the interface of literary and oral cultures in early modern Finland, focusing on the sixteenth and seventeenth centuries. The book renews the understanding of exchange between the learned culture of clergymen and the culture of commoners, or “folk”. What happened when the Reformation changed the position of the vernacular language to literary and ecclesiastical, and when folk beliefs seem to have become an object for more intensive surveillance and correction? How did clergymen understand and use the versatile labels of popular belief, paganism, superstition and Catholic fermentation? Why did they choose particular song languages, poetic modes and melodies for their Lutheran hymns and literary poems, and why did they avoid oral poetics in certain contexts while accentuating it in others? How were the hagiographical traditions representing the international medieval literary or “great” tradition adapted to “small” folk traditions, and how did they persist and change after the Reformation? What happened to the cult of the Virgin Mary in local oral traditions? This book studies the relations and mutual influences of oral and literary cultures in Finland during the long period stretching from late Middle Ages to the nineteenth century. The Reformation, the process of turning vernacular languages into literary ones, the rise of new early-modern territorial principalities, and the reorganisation of the whole Baltic Sea area in the sixteenth century and after all affected both people’s everyday lives and the spheres of the sacred. The learned elites became interested in folk beliefs and practices as they started to argue about and order their own religious practices in a new way. Lutheran congregational singing spread from the German area to the northern Baltic Sea regions. The first Finnish sixteenth-century reformers admired the new Germanic models and avoided the Finnic vernacular Kalevala-metre idiom, while their successors picked up many vernacular traits, most notably alliteration, in their ecclesiastical poetry and hymns. Over the following centuries, the new features introduced via new Lutheran hymns such as accentual metres, end-rhymes and strophic structures were infusing into oral folk poetry, although this took place also via secular oral and literary routes. On the other hand, seventeenth-century scholars cultivated a new academic interest in what they understood as “ancient Finnish poetry”. The main source materials studied in this book are from the Reformation period and immediately after, when Finnish clergymen wrote their first comments and depictions of folk beliefs and worked to create Lutheran hymns in Finnish, and also largely from the nineteenth century, when most Finnish folk poetry and older oral traditions were collected. These later folklore materials are used here to shed light on the transformations of folk beliefs and poetic forms during the centuries that followed the Reformation. The emphasis is on the areas which formed the old medieval diocese of Turku (Swedish Åbo) or what the Swedish rulers called the province of Österland (Lat. Osterlandia, later Finlandia) west from the border of Nöteborg (Finnish Pähkinäsaari) between Sweden and the Grand Duchy of Novgorod in 1323. In addition, some other sources, especially from the Finnic and Scandinavian areas, are used as comparative material.Peer reviewe

WOˇˇ3ˇˇˇ photocatalysts: Influence of structure and composition

Hexagonal (h-) and monoclinic (m-) WO 3 nanoparticles with controlled composition (oxidized/yellow color or partially reduced/blue color) were prepared through annealing (NH 4) x WO 3- y . The formation, structure, composition, morphology, and optical properties of the samples were analyzed by powder X-ray diffraction, scanning and transmission electron microscopy combined with electron diffraction, and Raman, X-ray photoelectron, 1H magic angle spinning nuclear magnetic resonance, diffuse reflectance ultraviolet-visual, and photoluminescence spectroscopy. Their photocatalytic properties were tested by decomposing methyl orange in the aqueous phase and acetone in the gas phase. Oxidized m-WO 3 (m-WO 3 ox) was the most active photocatalyst both in the aqueous and in the gas phase, followed by the oxidized h-WO 3 (h-WO 3 ox) sample. Reduced h-WO 3 (h-WO 3 red) and m-WO 3 (m-WO 3 red) exhibited much lower activity. Thus, in contrast to TiO 2, where crystalline structure (rutile or anatase) plays a key effect in photocatalysis, for WO 3, it is the composition that is of greatest importance: the more oxidized the WO 3 sample, the better a photocatalyst it is. The crystal structure of WO 3 has only an indirect effect, in that it influences the composition of WO 3 samples. While oxidized m-WO 3 is completely oxidized, oxidized h-WO 3 is always in a partially reduced state due to the presence of stabilizing positive ions in its hexagonal channels. Consequently, an oxidized monoclinic WO 3 material will always provide better photocatalytic activity than an oxidized hexagonal one. © 2012 Elsevier Inc. All rights reserved

Laulut ja kirjoitukset: Suullinen ja kirjallinen kulttuuri uuden ajan alun Suomessa

"Songs and writings: oral and literary cultures in early-modern Finland renews the understanding of exchange between the learned culture of clergymen and the culture of commoners, or “folk”. What happened when the Reformation changed the position of the oral vernacular language to literary and ecclesiastical, and when folk beliefs seem to have become an object for more intensive surveillance and correction? How did clergymen understand and use the versatile labels of popular belief, paganism, superstition and Catholic fermentation? Why did they choose particular song languages, poetic modes and melodies for their Lutheran hymns and literary poems, and why did they avoid oral poetics in certain contexts while accentuating it in others? How were the hagiographical traditions representing the international medieval literary or “great” tradition adapted to “small” folk traditions, and how did they persist and change after the Reformation? What happened to the cult of the Virgin Mary in local oral traditions? The first Finnish 16th-century reformers admired the new Germanic models of Lutheran congregational hymns and avoided the Finnic vernacular Kalevala-metre idiom, while their successors picked up many vernacular traits, most notably alliteration, in their ecclesiastical poetry and hymns. Over the following centuries, the new features introduced via new Lutheran hymns such as accentual metres, end-rhymes and strophic structures were infusing into oral folk poetry, although this took place also via secular oral and literary routes. On the other hand, seventeenth-century scholars cultivated a new academic interest in what they understood as “ancient Finnish poetry”. The book has an extensive English Summary for the international readership.