Synthesis of electroactive molecular clips for a supramolecular recognition of neutral molecules

Date du colloque&nbsp;: 07/2009</p

Synthesis and properties of electro or photoactive molecular clips and baskets for a supramolecular recognition

Date du colloque&nbsp;: 05/2009</p

Synthèse et propriétés de clips et paniers moléculaires électro- ou photoactifs pour une reconnaissance supramoléculaire

Date du colloque&nbsp;: 09/2010</p

Synthèse de clips moléculaires électroactifs pour la reconnaissance supramoléculaire de molécules neutres planes ou tridimensionnelles

National audienc

Interface instability in shear banding flow

We report on the spatio-temporal dynamics of the interface in shear-banding flow of a wormlike micellar system (cetyltrimethylammonium bromide and sodium nitrate in water) during a start-up experiment. Using the scattering properties of the induced structures, we demonstrate the existence of an instability of the interface between bands along the vorticity direction. Different regimes of spatio-temporal dynamics of the interface are indentified along the stress plateau. We build a model based on the flow symetry which qualitatively describes the observed patterns

A Fused Donor−Acceptor System Based on an Extended Tetrathiafulvalene and a Ruthenium Complex of Dipyridoquinoxaline

An application of the Horner−Wadsworth−Emmons reaction carried out on a ruthenium compound as the electrophilic precursor is described for the synthesis of fused donor−acceptor system 1 based on an extended tetrathiafulvalene and a ruthenium complex of dipyridoquinoxaline units

Molecular clips and tweezers hosting neutral guests

Intense current interest in supramolecular chemistry is devoted to the construction of molecular assemblies displaying controlled molecular motion associated to recognition. On this ground, molecular clips and tweezers have focused an increasing attention. This tutorial review points out the recent advances in the construction of always more sophisticated molecular clips and tweezers, illustrating their remarkably broad structural variety and focusing on their binding ability towards neutral guests. A particular attention is brought to recent findings in dynamic molecular tweezers whose recognition ability can be regulated by external stimuli. Porphyrin-based systems will not be covered here as this very active field has been recently reviewed

Dual Signaling System with an Extended-Tetrathiafulvalene–Phenanthroline Dyad Acting as an Electrooptical Cation Chemosensor

A tetrathiafulvalene donor has been annulated to 2,3-di(1H-2-pyrrolyl)quinoxaline affording a new chemosensor 1, which shows a unique optical selectivity and reactivity for the fluoride ion over other anions in CH2Cl2 leading to a colorimetric response. Electrochemical polymerization of 1 occurred in the presence of fluoride

Time scales in shear banding of wormlike micelles

Transient stress and birefringence measurements are performed on wormlike micellar solutions that "shear band", i.e. undergo flow-induced coexistence of states of different viscosities along a constant stress "plateau". Three well-defined relaxation times are found after a strain rate step between two banded flow states on the stress plateau. Using the Johnson-Segalman model, we relate these time scales to three qualitatively different stages in the evolution of the bands and the interface between them: band destabilization, reconstruction of the interface, and travel of the fully formed interface. The longest timescale is then used to estimate the magnitude of the (unknown) "gradient" terms that must be added to constitutive relations to explain the history independence of the steady flow and the plateau stress selection