Locally Periodic Versus Globally Periodic Infinite Words

AbstractWe call a one-way infinite word w over a finite alphabet (ρ,l)-repetitive if all long enough prefixes of w contain as a suffix a ρth power (or more generally a repetition of order ρ) of a word of length at most l. We show that each (2,4)-repetitive word is ultimately periodic, as well as that there exist continuum many, and hence also nonultimately periodic, (2,5)-repetitive words. Further, we characterize nonultimately periodic (2,5)-repetitive words both structurally and algebraically

Testing the INCA model in a small agricultural catchment in southern Finland

International audienceNutrient leaching from agricultural production is still recognised as a major environmental problem in Finland. To estimate agricultural nitrogen loading under changing land-use and climate conditions, the Integrated Nitrogen Model for Catchments (INCA) was applied in Savijoki, a small (15.4 km2) agricultural catchment, which represents the intensively cultivated areas in south-western Finland. Hydrological calibration and testing of the INCA model was first carried out in Savijoki during 1981?2000. In spite of heterogeneous soil and land-use conditions, INCA was able to reproduce the overall hydrological regime in the stream. The model was calibrated further in respect of nitrogen processes during 1995?2000. The model was able, reasonably well, to simulate the overall annual dynamics of the inorganic N concentrations in the stream water and the annual N export from the catchment. The average simulated NO3-N export was 550 kg N km?2 yr?1 and the observed one (constituting more than half of the annual total N export) was 592 kg N km?2 yr?1. For NH4-N, the simulated export was somewhat higher than that measured but NH4-N was only 4% of the total N export. In spite of some underestimation of flow and N concentration during extreme hydrological conditions, the INCA model proved to be a useful tool for analysing flow pattern and inorganic nitrogen leaching in a small agricultural catchment, characterised by a rapid response to rainfall. Keywords: nitrogen, integrated modelling, hydrology, catchment, agricultur

Modelling impacts of climate and deposition changes on nitrogen fluxes in northern catchments of Norway and Finland

International audienceThe Integrated Nitrogen model for Catchments (INCA) was applied to three upland catchments in Norway and Finland to assess the possible impacts of climate change and nitrogen (N) deposition on concentrations and fluxes of N in streamwater in cold regions of Europe. The study sites cover gradients in climate and N deposition from the southern boreal Øygard Brook (2.6 km2) in SW Norway, via the southern/middle boreal Simojoki River (3610 km2) in northern Finland to the sub-arctic Dalelva Brook (3.2 km2) in northern Norway. The INCA scenario simulations included future N deposition scenarios (current legislation and maximum feasible reduction) and climate scenarios for 2050 (ECHAM4/OPYC3; HadCM3) treated separately and in combination. As a result of climate change, the INCA model predicted markedly reduced duration and amounts of snow cover in all catchments. The occurrence of winter rainfall and melting periods was predicted to become more frequent so that more frequent floods in winter will to a large extent replace the regular snowmelt flood in spring. At the northernmost catchment, Dalelva, the predicted temperature increase might result in a doubling of the net mineralisation rate, thereby greatly increasing the amount of available inorganic N. At all catchments, the increased N supply was predicted to be largely balanced by a corresponding increase in N retention, and relatively small increases in NO3- leaching rates were predicted. This dynamic relationship is, however, strongly dependent on the temperature responses of the key N transformation processes modelled. A future reduction in N emissions and deposition, as agreed under current legislation, would have pronounced effects on concentrations of NO3- in streamwater at the southernmost catchment, Øygard, even following a climate change around 2050. At the more remote Dalelva and Simojoki catchments, the N emission reductions will be small compared to the internal N recycling processes, and climate change will to a large extent offset the effects of reduced N deposition. Keywords: catchments, surface water, scenarios, climate, hydrology, nitrogen deposition, nitrate leachin

Nanopartikkeleiden laserablaatio nestefaasissa

Tiivistelmä. Nanopartikkeleiden laserablaatio nestefaasissa on nanopartikkeleiden valmistustapa, joka perustuu laserin kykyyn saada materia irtoamaan kiinteästä aineesta. Väliaineena oleva neste mahdollistaa nanopartikkeleiden monipuolisen jatkokäytön erilaisissa sovelluksissa. Tämän kirjallisuuskatsauksen tavoitteena on kuvata, miten nanopartikkeleiden laserablaatio nestefaasissa tapahtuu, mitä ovat sen koeasetelman osat ja miten osien parametrit vaikuttavat tapahtumiin. Lisäksi käsitellään nanopartikkeleiden sovellutuksia. Tutkielma on toteutettu kuvailevana kirjallisuuskatsauksena. Käytetyt tutkimukset sisältävät kirjallisuuskatsauksia ja kirjoja, jotka käsittelevät aihetta yleisluontoisesti sekä koeparametrien vaikutuksia käsitteleviä tutkimuksia

A quasi-three-dimensional model for predicting rainfall-runoff processes in a forested catchment in Southern Finland

International audienceRunoff generation in a forested catchment (0.18 km2) was simulated using a quasi-three-dimensional rainfall-runoff model. The model was formulated over a finite grid where water movement was assumed to be dominantly vertical in the unsaturated soil zone and horizontal in the saturated soil. The vertical soil moisture distribution at each grid cell was calculated using a conceptual approximation to the one-dimensional Richards equation. The approximation allowed the use of a simple soil surface boundary condition and an efficient solution to the water table elevation over the finite grid. The approximation was coupled with a two-dimensional ground water model to calculate lateral soil water movement between the grid cells and exfiltration over saturated areas, where runoff was produced by the saturation-excess mechanism. Runoff was an input to a channel network, which was modelled as a nonlinear reservoir. The proposed approximation for the vertical soil moisture distribution in unsaturated soil compared well to a numerical solution of the Richards equation during shallow water table conditions, but was less satisfactory during prolonged dry periods. The simulation of daily catchment outflow was successful with the exception of underprediction of extremely high peak flows. The calculated water table depth compared satisfactorily with the measurements. An overall comparison with the earlier results of tracer studies indicated that the modelled contribution of direct rainfall/snowmelt in streamflow was higher than the isotopically traced fraction of event-water in runoff. The seasonal variation in the modelled runoff-contributing areas was similar to that in the event-water-contributing areas from the tracer analysis

Intensification of UV-C tertiary treatment : Disinfection and removal of micropollutants by sulfate radical based Advanced Oxidation Processes

This study explores the enhancement of UV-C tertiary treatment by sulfate radical based Advanced Oxidation Processes (SR-AOPs), including photolytic activation of peroxymonosulfate (PMS) and persulfate (PS) and their photocatalytic activation using Fe(II). Their efficiency was assessed both for the inactivation of microorganisms and the removal or micropollutants (MPs) in real wastewater treatment plant effluents. Under the studied experimental range (UV-C dose 5.7-57 J/L; UV-C contact time 3 to 28 s), the photolysis of PMS and PS (0.01 mM) increased up to 25% the bacterial removal regarding to UV-C system. The photolytic activation of PMS led to the total inactivation of bacteria (approximate to 5.70 log) with the highest UV-C dose (57 J/L). However, these conditions were insufficient to remove the MPs, being required oxidant's dosages of 5 mM to remove above 90% of carbamazepine, diclofenac, atenolol and triclosan. The best efficiencies were achieved by the combination of PMS or PS with Fe(II), leading to the total removal of the MPs using a low UV-C dosage (19 J/L), UV-C contact time (9 s) and reagent's dosages (0.5 mM). Finally, high mineralization was reached ( > 50%) with photocatalytic activation of PMS and PS even with low reagent's dosages.Peer reviewe

Overexpression of chloroplast NADPH-dependent thioredoxin reductase in Arabidopsis enhances leaf growth and elucidates in vivo function of reductase and thioredoxin domains

Plant chloroplasts have versatile thioredoxin systems including two thioredoxin reductases and multiple types of thioredoxins. Plastid-localized NADPH-dependent thioredoxin reductase (NTRC) contains both reductase (NTRd) and thioredoxin (TRXd) domains in a single polypeptide and forms homodimers. To study the action of NTRC and NTRC domains in vivo, we have complemented the ntrc knockout line of Arabidopsis with the wild type and full-length NTRC genes, in which 2-Cys motifs either in NTRd, or in TRXd were inactivated. The ntrc line was also transformed either with the truncated NTRd or TRXd alone. Overexpression of wild-type NTRC promoted plant growth by increasing leaf size and biomass yield of the rosettes. Complementation of the ntrc line with the full-length NTRC gene containing an active reductase but an inactive thioredoxin domain, or vice versa, recovered wild-type chloroplast phenotype and, partly, rosette biomass production, indicating that the NTRC domains are capable of interacting with other chloroplast thioredoxin systems. Overexpression of truncated NTRd or TRXd in ntrc background did not restore wild-type phenotype. Modelling of the 3-dimensional structure of the NTRC dimer indicates extensive interactions between the NTR domains and the TRX domains further stabilize the dimeric structure. The long linker region between the NTRd and TRXd, however, allows flexibility for the position of the TRXd in the dimer. Supplementation of the TRXd in the NTRC homodimer model by free chloroplast thioredoxins indicated that TRXf is the most likely partner to interact with NTRC. We propose that overexpression of NTRC promotes plant biomass yield both directly by stimulation of chloroplast biosynthetic and protected pathways controlled by NTRC and indirectly via free chloroplast thioredoxins. Our data indicate that overexpression of chloroplast thiol redox-regulator has a potential to increase biofuel yield in plant and algal species suitable for sustainable bioene