786 research outputs found
Preparation of Ni–YSZ thin and thick films on metallic interconnects as cell supports. Applications as anode for SOFC
In this work, we propose the preparation of a duplex anodic layer composed of both a thin (100 nm) and a thick film (10 lm) with Ni–YSZ material. The support of this anode is a metallic substrate, which is the interconnect of the SOFC unit cell. The metallic support limits the temperature of thermal treatment at 800 C to keep a good interconnect mechanical behaviour and to reduce corrosion. We have chosen to elaborate anodic coatings by sol–gel route coupled with dip-coating process, which are low cost techniques and allow working with moderate temperatures. Thin films are obtained by dipping interconnect substrate into a sol, and thick films into an optimized slurry. After thermal treatment at only 800 C, anodic coatings are adherent and homogeneous. Thin films have compact microstructures that confer ceramic protective barrier on metal surface. Further coatings of 10 lm thick are porous and constitute the active anodic material
Investigation of Graded La2NiO4+ Cathodes to Improve SOFC Electrochemical Performance
Mixed ionic and electronic conducting MIEC oxides are promising materials for use as cathodes in solid oxide fuel cells SOFCs due to their enhanced electrocatalytic activity compared with electronic conducting oxides. In this paper, the MIEC oxide La2NiO4+ was prepared by the sol-gel route. Graded cathodes were deposited onto yttria-stabilized zirconia YSZ pellets by dip-coating, and electrochemical impedance spectroscopy studies were performed to characterize the symmetrical cell performance. By adapting the slurries, cathode layers with different porosities and thicknesses were obtained. A ceria gadolinium oxide CGO barrier layer was introduced, avoiding insulating La2Zr2O7 phase formation and thus reducing resistance polarization of the cathode. A systematic correlation between microstructure, composition, and electrochemical performance of these cathodes has been performed. An improvement of the electrochemical performance has been demonstrated, and a reduction in the area specific resistance ASR by a factor of 4.5 has been achieved with a compact interlayer of La2NiO4+ between the dense electrolyte and the porous La2NiO4+ cathode layer. The lowest observed ASR of 0.11 cm2 at 800°C was obtained from a symmetrical cell composed of a YSZ electrolyte, a CGO interlayer, an intermediate compact La2NiO4+ layer, a porous La2NiO4+ electrode layer, and a current collection layer of platinum paste
Viscous stabilization of 2D drainage displacements with trapping
We investigate the stabilization mechanisms due to viscous forces in the
invasion front during drainage displacement in two-dimensional porous media
using a network simulator. We find that in horizontal displacement the
capillary pressure difference between two different points along the front
varies almost linearly as function of height separation in the direction of the
displacement. The numerical result supports arguments taking into account the
loopless displacement pattern where nonwetting fluid flow in separate strands
(paths). As a consequence, we show that existing theories developed for viscous
stabilization, are not compatible with drainage when loopless strands dominate
the displacement process.Comment: The manuscript has been substantially revised. Accepted in Phys. Rev.
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Immigrant community integration in world cities
As a consequence of the accelerated globalization process, today major cities
all over the world are characterized by an increasing multiculturalism. The
integration of immigrant communities may be affected by social polarization and
spatial segregation. How are these dynamics evolving over time? To what extent
the different policies launched to tackle these problems are working? These are
critical questions traditionally addressed by studies based on surveys and
census data. Such sources are safe to avoid spurious biases, but the data
collection becomes an intensive and rather expensive work. Here, we conduct a
comprehensive study on immigrant integration in 53 world cities by introducing
an innovative approach: an analysis of the spatio-temporal communication
patterns of immigrant and local communities based on language detection in
Twitter and on novel metrics of spatial integration. We quantify the "Power of
Integration" of cities --their capacity to spatially integrate diverse
cultures-- and characterize the relations between different cultures when
acting as hosts or immigrants.Comment: 13 pages, 5 figures + Appendi
Simulating temporal evolution of pressure in two-phase flow in porous media
We have simulated the temporal evolution of pressure due to capillary and
viscous forces in two-phase drainage in porous media. We analyze our result in
light of macroscopic flow equations for two-phase flow. We also investigate the
effect of the trapped clusters on the pressure evolution and on the effective
permeability of the system. We find that the capillary forces play an important
role during the displacements for both fast and slow injection rates and both
when the invading fluid is more or less viscous than the defending fluid. The
simulations are based on a network simulator modeling two-phase drainage
displacements on a two-dimensional lattice of tubes.Comment: 12 pages, LaTeX, 14 figures, Postscrip
Permeability Prediction from Mercury Injection Capillary Pressure: An Example from the Perth Basin, Western Australia
For shale gas reservoirs, permeability is one of the most important—and difficult—parameters to determine. Typical shale matrix permeabilities are in the range of 10 microdarcy–100 nanodarcy, and are heavily dependent on the presence of natural fractures for gas transmissibility. Permeability is a parameter used to measure the ability of a rock to convey fluid. It is directly related to porosity and depends on the pore geometry features, such as tortuosity, pore shape and pore connectivity. Consequently, rocks with similar porosity can exhibit different permeability. Generally, permeability is measured in laboratories using core plugs. In some cases, however, it is difficult to obtain suitable core plugs. In these instances, other approaches can be used to predict permeability, which are chiefly based on mathematical and theoretical models. The approach followed in this peer-reviewed paper is to correlate permeability with capillary pressure data from mercury injection measurements. The theoretical and empirical equations, introduced in the literature for various conventional and unconventional reservoir rocks, have been used to predict permeability. Estimated gas shale permeabilities are then compared with results from transient and steady state methods on small pieces of rocks embedded in a resin disk. The study also attempts to establish a suitable equation that is applicable to gas shale formations and to investigating the relationship between permeability and porosity
Human mobility: Models and applications
This is the author accepted manuscript. The final version is available from the publisher via the DOI in this recordRecent years have witnessed an explosion of extensive geolocated datasets related to human movement, enabling scientists to quantitatively study individual and collective mobility patterns, and to generate models that can capture and reproduce the spatiotemporal structures and regularities in human trajectories. The study of human mobility is especially important for applications such as estimating migratory flows, traffic forecasting, urban planning, and epidemic modeling. In this survey, we review the approaches developed to reproduce various mobility patterns, with the main focus on recent developments. This review can be used both as an introduction to the fundamental modeling principles of human mobility, and as a collection of technical methods applicable to specific mobility-related problems. The review organizes the subject by differentiating between individual and population mobility and also between short-range and long-range mobility. Throughout the text the description of the theory is intertwined with real-world applications.US Army Research Offic
Creep via dynamical functional renormalization group
We study a D-dimensional interface driven in a disordered medium. We derive
finite temperature and velocity functional renormalization group (FRG)
equations, valid in a 4-D expansion. These equations allow in principle for a
complete study of the the velocity versus applied force characteristics. We
focus here on the creep regime at finite temperature and small velocity. We
show how our FRG approach gives the form of the v-f characteristics in this
regime, and in particular the creep exponent, obtained previously only through
phenomenological scaling arguments.Comment: 4 pages, 3 figures, RevTe
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