101,455 research outputs found
The vibrational predissociation spectroscopy of hydrogen cluster ions
The first infrared spectra of protonated hydrogen clusters in the gas phase have been observed. Predissociation spectra were taken with a tandem mass spectrometer: mass selected hydrogen cluster ions were irradiated inside a rf ion trap by a tunable infrared laser, and the fragment ions created by photodissociation of the clusters were mass selected and detected. Spectra for each product channel were measured by counting fragment ions as a function of laser frequency. Low resolution spectra (Deltanu=10 cm^−1) in the region from 3800 to 4200 cm^−1 were observed for the ions H + 5, H + 7, and H + 9 at 3910, 3980, and 4020 cm−1, respectively. A band was also observed for H + 5 at 3532 cm^−1. No rotational structure was resolved. The frequencies of the band maxima agree well with the frequencies predicted by previous ab initio calculations for the highest modes
Subleading Shape-Function Effects and the Extraction of |V_ub|
We derive a class of formulae relating moments of B -> Xu l nu to B -> Xs
gamma in the shape function region, where m_X^2 ~ m_b Lambda_QCD. We also
derive an analogous class of formulae involving the decay B -> Xs l+ l-. These
results incorporate Lambda_QCD/m_b power corrections, but are independent of
leading and subleading hadronic shape functions. Consequently, they enable one
to determine |V_ub|/|V_tb V_ts*| to subleading order in a model-independent
way.Comment: 23 page
Infrared spectra of the cluster ions H7O<sup> + </sup><sub>3</sub>·H2 and H9O<sup> + </sup><sub>4</sub>·H2
Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O + 3 ·H2 and H9O + 4 ·H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm^−1, with a resolution of 1.2 cm^−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O + 3 and H9O + 4
Symmetric Triple Well with Non-Equivalent Vacua: Instantonic Approach
We show that for the triple well potential with non-equivalent vacua,
instantons generate for the low lying energy states a singlet and a doublet of
states rather than a triplet of equal energy spacing. Our energy splitting
formulae are also confirmed numerically. This splitting property is due to the
presence of non-equivalent vacua. A comment on its generality to multi-well is
presented.Comment: 10 pages, 3 figures, 2 tables; minor changes; added reference
Acetylene terminated matrix resins
The synthesis of resins with terminal acetylene groups has provided a promising technology to yield high performance structural materials. Because these resins cure through an addition reaction, no volatile by-products are produced during the processing. The cured products have high thermal stability and good properties retention after exposure to humidity. Resins with a wide variety of different chemical structures between the terminal acetylene groups are synthesized and their mechanical properties studied. The ability of the acetylene cured polymers to give good mechanical properties is demonstrated by the resins with quinoxaline structures. Processibility of these resins can be manipulated by varying the chain length between the acetylene groups or by blending in different amounts of reactive deluents. Processing conditions similar to the state-of-the-art epoxy can be attained by using backbone structures like ether-sulfone or bis-phenol-A. The wide range of mechanical properties and processing conditions attainable by this class of resins should allow them to be used in a wide variety of applications
Monolithic arrays of surface emitting laser NOR logic devices
Monolithic, cascadable, laser-logic-device arrays have been realized and characterized. The monolithic surface-emitting laser logic (SELL) device consists of an AlGaAs superlattice lasing around 780 nm connected to a heterojunction phototransistor (HPT) in parallel and a resistor in series. Arrays up to 8×8 have been fabricated, and 2×2 arrays show uniform characteristics. The optical logic output is switched off with 40 μW incident optical input
Monolithic arrays of surface emitting laser NOR logic devices
Monolithic, cascadable, laser-logic-device arrays have been realized and characterized. The monolithic surface-emitting laser logic (SELL) device consists of an AlGaAs superlattice lasing around 780 nm connected to a heterojunction phototransistor (HPT) in parallel and a resistor in series. Arrays up to 8×8 have been fabricated, and 2×2 arrays show uniform characteristics. The optical logic output is switched off with 40 μW incident optical input
Fractional ac Josephson effect in unconventional superconductors
For certain orientations of Josephson junctions between two p_x-wave or two
d-wave superconductors, the subgap Andreev bound states produce a 4pi-periodic
relation between the Josephson current I and the phase difference phi: I ~
sin(phi/2). Consequently, the ac Josephson current has the fractional frequency
eV/h, where V is the dc voltage. In the tunneling limit, the Josephson current
is proportional to the first power (not square) of the electron tunneling
amplitude. Thus, the Josephson current between unconventional superconductors
is carried by single electrons, rather than by Cooper pairs. The fractional ac
Josephson effect can be observed experimentally by measuring frequency spectrum
of microwave radiation from the junction.Comment: 8 pages, 3 figures, RevTEX 4; v2. - minor typos corrected in proof
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