54 research outputs found

    Solid flux in travelling fluidized bed operating in square-nosed slugging regime

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    The performance of gas-fluidized bed reactors depends significantly on their hydrodynamics. Among the important properties that dictate the characteristics of a gas-fluidized bed, local solid flux plays a significant role, influencing vital parameters such as bed-to-surface heat exchange and solid circulation rate. Developing techniques that can provide accurate measurements of solid flux is extremely important for: 1) assessing the accuracy of other measurement techniques applicable to industrial units, and 2) validation of CFD models. Comparison of different measurement techniques that provide similar hydrodynamic information is helpful in assessing the errors associated with each methodology. Most measurement techniques for obtaining solid flux in gas-fluidized beds are based on intrusive probes that can simultaneously measure solid velocity and voidage. Previously (1), the novel travelling fluidized bed (TFB) was operated to determine particle velocity from radioactive particle tracking (RPT), positron emission particle tracking (PEPT) and borescopy with silica sand particles of mean diameter 292 μm at superficial gas velocities from 0.4 to 0.6 m/s. In this study, the TFB, operated under identical conditions, was deployed to compare RPT and PEPT for the investigation of solid flux in square-nosed slugging. Both techniques provided solid flux data of the same order, but there were significant quantitative differences. Differing physical properties of tracer particles and the bed material, and differences in the tracer localization techniques are among the factors that contributed to the observed discrepancies. The results provide useful insights on the merits and challenges associated with advanced techniques for measuring solids flux in gas-fluidized beds. REFERENCES S. Tebianian, K. Dubrawski, N. Ellis, R. A. Cocco, R. Hays, S.B.R. Karri, T. W. Leadbeater, D.J. Parker, J. Chaouki, R. Jafari, P. Garcia-Trinanes, J.P.K. Seville, J.R. Grace. Comparison of Particle Velocity Measurement Techniques in a Fluidized Bed Operating in the Square-Nosed Slugging Flow Regime. Powder Technol., 2015. doi:http://dx.doi.org/10.1016/j.powtec.2015.08.040

    Introduction: looking beyond the walls

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    In its consideration of the remarkable extent and variety of non-university researchers, this book takes a broader view of ‘knowledge’ and ‘research’ than in the many hot debates about today’s knowledge society, ‘learning age’, or organisation of research. It goes beyond the commonly held image of ‘knowledge’ as something produced and owned by the full-time experts to take a look at those engaged in active knowledge building outside the university walls

    Modern microwave methods in solid state inorganic materials chemistry: from fundamentals to manufacturing

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    Understanding the sex difference in vulnerability to adolescent depression: an examination of child and parent characteristics

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    This study examined sex differences in risk factors associated with adolescent depression in a large sample of boys and girls. Moderation and mediation explanatory models of the sex difference in likelihood of depression were examined. Findings indicate that the factors associated with depression in adolescent boys and girls are quite similar. All of the variables considered were associated with depression, but sex did not moderate the impact of vulnerability factors on likelihood of depression diagnosis. However, negative self-perceptions in the domains of achievement, global self-worth, and physical appearance partially mediated the relationship between sex and depression. Further, girls had higher levels of positive self-perceptions in interpersonal domains that acted as suppressors and reduced the likelihood of depression in girls. These findings suggest that girls' higher incidence of depression is due in part to their higher levels of negative self-perceptions, whereas positive interpersonal factors serve to protect them from depressive episodes

    Iron Behaving Badly: Inappropriate Iron Chelation as a Major Contributor to the Aetiology of Vascular and Other Progressive Inflammatory and Degenerative Diseases

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    The production of peroxide and superoxide is an inevitable consequence of aerobic metabolism, and while these particular "reactive oxygen species" (ROSs) can exhibit a number of biological effects, they are not of themselves excessively reactive and thus they are not especially damaging at physiological concentrations. However, their reactions with poorly liganded iron species can lead to the catalytic production of the very reactive and dangerous hydroxyl radical, which is exceptionally damaging, and a major cause of chronic inflammation. We review the considerable and wide-ranging evidence for the involvement of this combination of (su)peroxide and poorly liganded iron in a large number of physiological and indeed pathological processes and inflammatory disorders, especially those involving the progressive degradation of cellular and organismal performance. These diseases share a great many similarities and thus might be considered to have a common cause (i.e. iron-catalysed free radical and especially hydroxyl radical generation). The studies reviewed include those focused on a series of cardiovascular, metabolic and neurological diseases, where iron can be found at the sites of plaques and lesions, as well as studies showing the significance of iron to aging and longevity. The effective chelation of iron by natural or synthetic ligands is thus of major physiological (and potentially therapeutic) importance. As systems properties, we need to recognise that physiological observables have multiple molecular causes, and studying them in isolation leads to inconsistent patterns of apparent causality when it is the simultaneous combination of multiple factors that is responsible. This explains, for instance, the decidedly mixed effects of antioxidants that have been observed, etc...Comment: 159 pages, including 9 Figs and 2184 reference
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