Framework for the energetic assessment of South and South-East Asia fixed chimney bull’s trench kiln

One of the major sources of fuel consumption and greenhouse gas emission in South and South-East Asia is brick manufacturing. One of the most commonly implemented technologies for brick manufacturing in this region is the fixed chimney Bull’s trench kiln (FCBTK). This type of technology largely depends on manual labour and is very inefficient when compared to more modern technologies. Because the adoption of more advanced technologies is hindered by the socio-economical background, the much needed innovations in the brick sector are necessarily related to improving/modifying the FCBTK already operational. However, few scientific studies have been conducted on FCBTK probably due to the basic level of technological development. Such studies are however important to systematically and methodologically assess the challenges and solutions in FCBTK. In this study we develop a thermo-energetic model to evaluate the importance of the parameters pertained to FCBTK construction and operation. The prospective of this study is to build an initial thermo-energetic framework that will serve as a basis to investigate possible energetic improvements

Molten salts and nuclear energy production

Molten salts (fluorides or chlorides) have been taken in consideration very soon in nuclear energy production researches. This was initially due to their advantageous physical properties: good heat transfer capacity, radiation insensitivity, high boiling point, .. and they can be used in various situations: heat transfer, core coolants with solid fuels, liquid fuel in molten salt reactor, solvents for spent nuclear solid fuel in the case of pyro- reprocessing, fusion. Molten salt reactors which are one of the six innovative concepts chosen by the Generation IV international forum may be particularly interesting in the case of waste incinerators or of the thorium cycle. As the neutron balance is very tight, the possibility to quickly extract poisoning fission products is very attractive. The most important questions addressed to demonstrate the scientific feasibility of Molten Salt Reactor will be reviewed

Effects of burying and removing dead leaves from the ground on the development of scab epidemics in an apple organic orchard.

Ascospores produced on scabbed leaves in the leaf litter constitute the primary inoculum causing scab infections in apple orchards during the year. The trial, carried out in a commercial organic orchard, permitted to evaluate the effects of the removal of dead leaves located on the inter-row supplemented by the ploughing in of the leaves left on the row, on the development of scab epidemics. From the first recorded contamination to harvest time, lesions on leaves and fruits were counted to determine reduction in disease incidence and severity, compared with the untreated plots. Disease severity as a function of the distance from the untreated plot was also observed, to evaluate the spore dispersal gradient within the orchard. The results show that the ploughing in and the removal of the litter reduced disease incidence by 62% on leaves, and by almost 82% on fruits to harvest. Moreover, measurements of the dispersal gradient show that the spores do not disperse, or little, beyond 20m of the untreated zone

High Metallicity Mg II Absorbers in the z < 1 Lyman alpha Forest of PKS 0454+039: Giant LSB Galaxies?

We report the discovery of two iron-group enhanced high-metallicity Mg II absorbers in a search through 28 Lyman Alpha forest clouds along the PKS 0454+039 sight line. Based upon our survey and the measured redshift number densities of W_r(MgII) <= 0.3 A absorbers and Lyman Alpha absorbers at z ~ 1, we suggest that roughly 5% of Lyman Alpha absorbers at z < 1 will exhibit "weak" Mg II absorption to a 5-sigma W_r(2796) detection limit of 0.02 A. The two discovered absorbers, at redshifts z = 0.6248 and z = 0.9315, have W_r(Lya) = 0.33 and 0.15 A, respectively. Based upon photoionization modeling, the H I column densities are inferred to be in the range 15.8 <= log N(HI) <= 16.8 cm^-2. For the z = 0.6428 absorber, if the abundance pattern is solar, then the cloud has [Fe/H] > -1; if its gas-phase abundance follows that of depleted clouds in our Galaxy, then [Fe/H] > 0 is inferred. For the z = 0.9315 absorber, the metallicity is [Fe/H] > 0, whether the abundance pattern is solar or suffers depletion. Imaging and spectroscopic studies of the PKS 0454+039 field reveal no candidate luminous objects at these redshifts. We discuss the possibility that these Mg II absorbers may arise in the class of "giant" low surface brightness galaxies, which have [Fe/H] >= -1, and even [Fe/H] >= 0, in their extended disks. We tentatively suggest that a substantial fraction of these "weak" Mg II absorbers may select low surface brightness galaxies out to z ~ 1.Comment: Accepted The Astrophysical Journal; 25 pages; 6 encapsulated figure

Mass spectrometric identification of [4Fe-4S](NO)x intermediates of nitric oxide sensing by regulatory iron-sulfur cluster proteins

Nitric oxide (NO) can function as both a cytotoxin and a signalling molecule. In both cases, reaction with iron–sulfur (Fe–S) cluster proteins plays an important role because Fe–S clusters are reactive towards NO and so are a primary site of general NO-induced damage (toxicity). This sensitivity to nitrosylation is harnessed in the growing group of regulatory proteins that function in sensing of NO via an Fe–S cluster. Although information about the products of cluster nitrosylation is now emerging, detection and identification of intermediates remains a major challenge, due to their transient nature and the difficulty in distinguishing spectroscopically similar iron-NO species. Here we report studies of the NO-sensing Fe–S cluster regulators NsrR and WhiD using non-denaturing mass spectrometry, in which non-covalent interactions between the protein and Fe/S/NO species are preserved. The data provide remarkable insight into the nitrosylation reactions, permitting identification, for the first time, of protein-bound mono-, di- and tetranitrosyl [4Fe–4S] cluster complexes ([4Fe–4S](NO), [4Fe–4S])(NO) 2 and [4Fe–4S](NO) 4 ) as intermediates along pathways to formation of product Roussin's red ester (RRE) and Roussin's black salt (RBS)-like species. The data allow the nitrosylation mechanisms of NsrR and WhiD to be elucidated and clearly distinguished

The scatter and evolution of the global hot gas properties of simulated galaxy cluster populations

We use the cosmo-OWLS suite of cosmological hydrodynamical simulations to investigate the scatter and evolution of the global hot gas properties of large simulated populations of galaxy groups and clusters. Our aim is to compare the predictions of different physical models and to explore the extent to which commonly-adopted assumptions in observational analyses (e.g. self-similar evolution) are violated. We examine the relations between (true) halo mass and the X-ray temperature, X-ray luminosity, gas mass, Sunyaev-Zel'dovich (SZ) flux, the X-ray analogue of the SZ flux ($Y_X$) and the hydrostatic mass. For the most realistic models, which include AGN feedback, the slopes of the various mass-observable relations deviate substantially from the self-similar ones, particularly at late times and for low-mass clusters. The amplitude of the mass-temperature relation shows negative evolution with respect to the self-similar prediction (i.e. slower than the prediction) for all models, driven by an increase in non-thermal pressure support at higher redshifts. The AGN models predict strong positive evolution of the gas mass fractions at low halo masses. The SZ flux and $Y_X$ show positive evolution with respect to self-similarity at low mass but negative evolution at high mass. The scatter about the relations is well approximated by log-normal distributions, with widths that depend mildly on halo mass. The scatter decreases significantly with increasing redshift. The exception is the hydrostatic mass-halo mass relation, for which the scatter increases with redshift. Finally, we discuss the relative merits of various hot gas-based mass proxies.Comment: 31 pages (21 before appendices), 19 figures, 12 tables, accepted by MNRAS after minor revisio

Redox-Sensing Iron–Sulfur Cluster Regulators

Significance: Iron–sulfur cluster proteins carry out multiple functions, including as regulators of gene transcription/translation in response to environmental stimuli. In all known cases, the cluster acts as the sensory module, where the inherent reactivity/fragility of iron–sulfur clusters with small/redox-active molecules is exploited to effect conformational changes that modulate binding to DNA regulatory sequences. This promotes an often substantial reprogramming of the cellular proteome that enables the organism or cell to adapt to, or counteract, its changing circumstances. Recent Advances: Significant progress has been made recently in the structural and mechanistic characterization of iron–sulfur cluster regulators and, in particular, the O2 and NO sensor FNR, the NO sensor NsrR, and WhiB-like proteins of Actinobacteria. These are the main focus of this review. Critical Issues: Striking examples of how the local environment controls the cluster sensitivity and reactivity are now emerging, but the basis for this is not yet fully understood for any regulatory family. Future Directions: Characterization of iron–sulfur cluster regulators has long been hampered by a lack of high-resolution structural data. Although this still presents a major future challenge, recent advances now provide a firm foundation for detailed understanding of how a signal is transduced to effect gene regulation. This requires the identification of often unstable intermediate species, which are difficult to detect and may be hard to distinguish using traditional techniques. Novel approaches will be required to solve these problems

The Population of Weak Mg II Absorbers I. A Survey of 26 QSO HIRES/Keck Spectra

We present a search for "weak" MgII absorbers [those with W_r(2796) < 0.3 A in the HIRES/Keck spectra of 26 QSOs. We found 30, of which 23 are newly discovered. The spectra are 80% complete to W_r(2796) = 0.02 A and have a cumulative redshift path of ~17.2 for the redshift range 0.4 < z < 1.4. The number of absorbers per unit redshift, dN/dz, is seen to increase as the equivalent width threshold is decreased; we obtained dN/dz = 1.74+/-0.10 for our 0.02 <= W_r(2796) < 0.3 A sample. The equivalent width distribution follows a power law with slope -1.0; there is no turnover down to W_r(2796) = 0.02 A at = 0.9. Weak absorbers comprise at least 65% of the total MgII absorption population, which outnumbers Lyman limit systems (LLS) by a factor of 3.8+/-1.1; the majority of weak MgII absorbers must arise in sub-LLS environments. Tentatively, we predict that ~5% of the Lyman-alpha forest clouds with W_r(1215) > 0.1 A will have detectable MgII absorption to W_r,min(2796) = 0.02 A and that this is primarily a high-metallicity selection effect (Z/Z_sun] > -1). This implies that MgII absorbing structures figure prominently as tracers of sub-LLS environments where gas has been processed by stars. We compare the number density of W_r(2796) > 0.02 A absorbers with that of both high and low surface brightness galaxies and find a fiducial absorber size of 35h^-1 to 63h^-1 kpc, depending upon the assumed galaxy population and their absorption properties. The individual absorbing "clouds" have W_r(2796) <= 0.15 A and their narrow (often unresolved) line widths imply temperatures of ~25,000 K. We measured W_r(1548) from CIV in FOS/HST archival spectra and, based upon comparisons with FeII, found a range of ionization conditions (low, high, and multi-phase) in absorbers selected by weak MgII.Comment: Accepted Version: 43 pages, PostScript figures embedded; accepted to ApJ; updated version includes analysis of CIV absorptio