5,027 research outputs found
Factors determining exchange rates : a simple model and empirical tests
An abstract for this article is not availableEquilibrium (Economics)
Multiconfiguration Time-Dependent Hartree-Fock Treatment of Electronic and Nuclear Dynamics in Diatomic Molecules
The multiconfiguration time-dependent Hartree-Fock (MCTDHF) method is
formulated for treating the coupled electronic and nuclear dynamics of diatomic
molecules without the Born- Oppenheimer approximation. The method treats the
full dimensionality of the electronic motion, uses no model interactions, and
is in principle capable of an exact nonrelativistic description of diatomics in
electromagnetic fields. An expansion of the wave function in terms of
configurations of orbitals whose dependence on internuclear distance is only
that provided by the underlying prolate spheroidal coordinate system is
demonstrated to provide the key simplifications of the working equations that
allow their practical solution. Photoionization cross sections are also
computed from the MCTDHF wave function in calculations using short pulses.Comment: Submitted to Phys Rev
Room-temperature ballistic transport in narrow graphene strips
We investigate electron-phonon couplings, scattering rates, and mean free
paths in zigzag-edge graphene strips with widths of the order of 10 nm. Our
calculations for these graphene nanostrips show both the expected similarity
with single-wall carbon nanotubes (SWNTs) and the suppression of the
electron-phonon scattering due to a Dirichlet boundary condition that prohibits
one major backscattering channel present in SWNTs. Low-energy acoustic phonon
scattering is exponentially small at room temperature due to the large phonon
wave vector required for backscattering. We find within our model that the
electron-phonon mean free path is proportional to the width of the nanostrip
and is approximately 70 m for an 11-nm-wide nanostrip.Comment: 5 pages and 5 figure
Random walk on the range of random walk
We study the random walk X on the range of a simple random walk on †d in dimensions dâ„4. When dâ„5 we establish quenched and annealed scaling limits for the process X, which show that the intersections of the original simple random walk path are essentially unimportant. For d=4 our results are less precise, but we are able to show that any scaling limit for X will require logarithmic corrections to the polynomial scaling factors seen in higher dimensions. Furthermore, we demonstrate that when d=4 similar logarithmic corrections are necessary in describing the asymptotic behavior of the return probability of X to the origin
The Lazy Bureaucrat Scheduling Problem
We introduce a new class of scheduling problems in which the optimization is
performed by the worker (single ``machine'') who performs the tasks. A typical
worker's objective is to minimize the amount of work he does (he is ``lazy''),
or more generally, to schedule as inefficiently (in some sense) as possible.
The worker is subject to the constraint that he must be busy when there is work
that he can do; we make this notion precise both in the preemptive and
nonpreemptive settings. The resulting class of ``perverse'' scheduling
problems, which we denote ``Lazy Bureaucrat Problems,'' gives rise to a rich
set of new questions that explore the distinction between maximization and
minimization in computing optimal schedules.Comment: 19 pages, 2 figures, Latex. To appear, Information and Computatio
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Improved Log(gf) Values for Lines of Ti I and Abundance Determinations in the Photospheres of the Sun and Metal-Poor Star HD 84937 (Accurate Transition Probabilities for Ti I)
New atomic transition probability measurements for 948 lines of Ti I are reported. Branching fractions from Fourier transform spectra and from spectra recorded using a 3 m echelle spectrometer are combined with published radiative lifetimes from laser-induced fluorescence measurements to determine these transition probabilities. Generally good agreement is found in comparisons to the NIST Atomic Spectra Database. The new Ti I data are applied to re-determine the Ti abundance in the photospheres of the Sun and metal-poor star HD 84937 using many lines covering a range of wavelength and excitation potential to explore possible non-local thermal equilibrium effects. The variation of relative Ti/Fe abundance with metallicity in metal-poor stars observed in earlier studies is supported in this study.NSF AST-1211055, AST-0908978, AST-1211585NSF REU grant AST-1004881ESO Science Archive Facility 073.D-0024, 266.D-5655NASA NAS 5-26555Astronom
A chemical ionization mass spectrometer for continuous underway shipboard analysis of dimethylsulfide in near-surface seawater
A compact, low-cost atmospheric pressure, chemical ionization mass spectrometer ("mini-CIMS") has been developed for continuous underway shipboard measurements of dimethylsulfide (DMS) in seawater. The instrument was used to analyze DMS in air equilibrated with flowing seawater across a porous Teflon membrane equilibrator. The equilibrated gas stream was diluted with air containing an isotopically-labeled internal standard. DMS is ionized at atmospheric pressure via proton transfer from water vapor, then declustered, mass filtered via quadrupole mass spectrometry, and detected with an electron multiplier. The instrument described here is based on a low-cost residual gas analyzer (Stanford Research Systems), which has been modified for use as a chemical ionization mass spectrometer. The mini-CIMS has a gas phase detection limit of 220 ppt DMS for a 1 min averaging time, which is roughly equivalent to a seawater DMS concentration of 0.1 nM DMS at 20°C. The mini-CIMS has the sensitivity, selectivity, and time response required for underway measurements of surface ocean DMS over the full range of oceanographic conditions. The simple, robust design and relatively low cost of the instrument are intended to facilitate use in process studies and surveys, with potential for long-term deployment on research vessels, ships of opportunity, and large buoys
Improved V II log() Values, Hyperfine Structure Constants, and Abundance Determinations in the Photospheres of the Sun and Metal-poor Star HD 84937
New experimental absolute atomic transition probabilities are reported for
203 lines of V II. Branching fractions are measured from spectra recorded using
a Fourier transform spectrometer and an echelle spectrometer. The branching
fractions are normalized with radiative lifetime measurements to determine the
new transition probabilities. Generally good agreement is found between this
work and previously reported V II transition probabilities. Use of two
spectrometers, independent radiometric calibration methods, and independent
data analysis routines enables a reduction in systematic uncertainties, in
particular those due to optical depth errors. In addition, new hyperfine
structure constants are measured for selected levels by least squares fitting
line profiles in the FTS spectra. The new V II data are applied to high
resolution visible and UV spectra of the Sun and metal-poor star HD 84937 to
determine new, more accurate V abundances. Lines covering a range of wavelength
and excitation potential are used to search for non-LTE effects. Very good
agreement is found between our new solar photospheric V abundance, log
{\epsilon}(V) = 3.95 from 15 V II lines, and the solar-system meteoritic value.
In HD 84937, we derive [V/H] = -2.08 from 68 lines, leading to a value of
[V/Fe] = 0.24.Comment: 32 pages, 7 tables (3 machine-readable), 8 figures; accepted for
publication in ApJ
Conformal invariance in two-dimensional turbulence
Simplicity of fundamental physical laws manifests itself in fundamental
symmetries. While systems with an infinity of strongly interacting degrees of
freedom (in particle physics and critical phenomena) are hard to describe, they
often demonstrate symmetries, in particular scale invariance. In two dimensions
(2d) locality often promotes scale invariance to a wider class of conformal
transformations which allow for nonuniform re-scaling. Conformal invariance
allows a thorough classification of universality classes of critical phenomena
in 2d. Is there conformal invariance in 2d turbulence, a paradigmatic example
of strongly-interacting non-equilibrium system? Here, using numerical
experiment, we show that some features of 2d inverse turbulent cascade display
conformal invariance. We observe that the statistics of vorticity clusters is
remarkably close to that of critical percolation, one of the simplest
universality classes of critical phenomena. These results represent a new step
in the unification of 2d physics within the framework of conformal symmetry.Comment: 10 pages, 5 figures, 1 tabl
Distribution of sizes of erased loops of loop-erased random walks in two and three dimensions
We show that in the loop-erased random walk problem, the exponent
characterizing probability distribution of areas of erased loops is
superuniversal. In d-dimensions, the probability that the erased loop has an
area A varies as A^{-2} for large A, independent of d, for 2 <= d <= 4. We
estimate the exponents characterizing the distribution of perimeters and areas
of erased loops in d = 2 and 3 by large-scale Monte Carlo simulations. Our
estimate of the fractal dimension z in two-dimensions is consistent with the
known exact value 5/4. In three-dimensions, we get z = 1.6183 +- 0.0004. The
exponent for the distribution of durations of avalanche in the
three-dimensional abelian sandpile model is determined from this by using
scaling relations.Comment: 25 pages, 1 table, 8 figure
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