Coupling haze and cloud microphysics in WASP-39b's atmosphere based on JWST observations

We present a study on the coupling of haze and clouds in the atmosphere of WASP-39b. We developed a cloud microphysics model simulating the formation of Na2S and MgSiO3 condensates over photochemical hazes in gas giant atmospheres. We apply this model to WASP-39b, recently observed with the JWST to study how these heterogeneous components may affect the transit spectrum. We simulate both morning and evening terminators independently and average their transit spectra. While MgSiO3 formation has negligible impact on the spectrum, Na2S condensates produce gray opacities in the water band, in agreement with HST and JWST observations. Moreover, the formation of Na2S on the morning side depletes the atmosphere of its sodium content, decreasing the strength of the Na line. Combining morning and evening profiles results in a good fit of the Na observations. These nominal results assume a small Na2S/haze contact angle (5.7{\deg}). Using a larger value (61{\deg}) reduces the cloud density and opacity, but the effect on the Na profile and spectral line remains identical. In addition, the presence of haze in the upper atmosphere reproduces the UV-visible slope observed in the HST and VLT data and contributes to the opacity between the water bands at wavelengths below 2 microns. The averaged spectra are rather insensitive to the variation of eddy diffusion and haze mass flux tested in this study, though the UV-visible slope, probing the haze layer above the clouds, is affected. Finally, our disequilibrium chemistry model, including photochemistry, reproduces the SO2 and CO2 absorption features observed.Comment: 19 pages, 16 figure

A physically derived eddy parameterization for giant planet atmospheres with application on hot-Jupiter atmospheres

We present a parameterization for the eddy diffusion profile of gas giant exoplanets based on physical phenomena and we explore how the parameterized eddy profile impacts the chemical composition, the thermal structure, the haze microphysics, and the transit spectra of 8 hot-Jupiters. Our eddy parameterization depends on the planetary intrinsic temperature (T$_{int}$ ), we thus evaluate how the increase of this parameter to values higher than those typically used ($\sim$100K) impacts the atmospheric structure and composition. Our investigation demonstrates that despite the strong impact of T$_{int}$ on the chemical composition of the deep atmosphere, the upper atmosphere is not affected for T$_{eq}$ $>$ 1300 K owing to high altitude quench levels at these conditions. Below this threshold, however, the larger atmospheric temperatures produced by increasing T$_{int}$ affect the quenched chemical composition. Our parameterization depends on two parameters, the eddy magnitude at the radiative-convective boundary (K$_0$) and the corresponding magnitude at the homopause (K$_{top}$). We demonstrate that, when using common K$_0$ and K$_{top}$ values among most of the different planet cases studied, we derive transit spectra consistent with Hubble Space Telescope observations. Moreover, our simulations show that increasing the eddy profile enhances the photochemical production of haze particles and reduces their average radius, thus providing a steeper UV-Visible slope. Finally, we demonstrate for WASP-39b that the James Webb Space Telescope observations provide improved constraints for the hazes and clouds and we show that both components seem necessary to interpret the combined transit spectrum from HST and JWST observations.Comment: 19 pages, 12 figure

Photochemical hazes in sub-Neptunian atmospheres with focus on GJ 1214 b

We study the properties of photochemical hazes in super-Earths/mini-Neptunes atmospheres with particular focus on GJ1214b. We evaluate photochemical haze properties at different metallicities between solar and 10000$\times$solar. Within the four orders of magnitude change in metallicity, we find that the haze precursor mass fluxes change only by a factor of $\sim$3. This small diversity occurs with a non-monotonic manner among the different metallicity cases, reflecting the interaction of the main atmospheric gases with the radiation field. Comparison with relative haze yields at different metallicities from laboratory experiments reveals a qualitative similarity with our theoretical calculations and highlights the contributions of different gas precursors. Our haze simulations demonstrate that higher metallicity results into smaller average particle sizes. Metallicities at and above 100$\times$solar with haze formation yields of $\sim$10$\%$ provide enough haze opacity to satisfy transit observation at visible wavelengths and obscure sufficiently the H$_2$O molecular absorption features between 1.1 $\mu$m and 1.7 $\mu$m. However, only the highest metallicity case considered (10000$\times$solar) brings the simulated spectra into closer agreement with transit depths at 3.6 $\mu$m and 4.5 $\mu$m indicating a high contribution of CO/CO$_2$ in GJ1214b's atmosphere. We also evaluate the impact of aggregate growth in our simulations, in contrast to spherical growth, and find that the two growth modes provide similar transit signatures (for D$_f$=2), but with different particle size distributions. Finally, we conclude that the simulated haze particles should have major implications for the atmospheric thermal structure and for the properties of condensation clouds

Titan Haze

The Titan haze exerts a dominating influence on surface visibility and atmospheric radiative heating at optical and near-infrared wavelengths and our desire to understand surface composition and atmospheric dynamics provides a strong motivation to study the properties of the haze. Prior to the Cassini/Huygens missions the haze was known to be global in extent, with a hemispheric contrast asymmetry, with a complicated structure in the polar vortex region poleward of about 55 deg latitude, and with a distinct layer near 370 km altitude outside of the polar vortex at the time of the Voyager 2 flyby. The haze particles measured by the Pioneer and Voyager spacecraft were both highly polarizing and strongly forward scattering, a combination that seems to require an aggregation of small (several tens of nm radius) primary particles. These same properties were seen in the Cassini orbiter and Huygens Probe data. The most extensive set of optical measurements were made inside the atmosphere by the Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens Probe. At the probe location as determined by the DISR measurements the average haze particle contained about 3000 primary particles whose radius is about 40 nm. Three distinct vertical regions were seen in the DISR data with differing particle properties. Refractive indices of the particles in the main haze layer resemble those reported by Khare et al. between O.3S and about 0.7 micron but are more absorbing than the Khare et al. results between 0.7 micron and the long-wavelength limit of the DISR spectra at 1.6 micron. These and other results are described by Tomasko et al., and a broader summary of results was given by Tomasko and West,. New data continue to stream in from the Cassini spacecraft. New data analyses and new laboratory and model results continue to move the field forward. Titan's 'detached' haze layer suffered a dramatic drop in altitude near equinox in 2009 with implications for the circulation and seasonal change in the stratosphere. The book chapter associated with this talk will also present new material on thermal-infrared data analysis and on new developments in laboratory work and haze microphysical modeling

Detection of Na, K, and H₂O in the hazy atmosphere of WASP-6b

We present new observations of the transmission spectrum of the hot Jupiter WASP-6b both from the ground with the Very Large Telescope FOcal Reducer and Spectrograph (FORS2) from 0.45 to 0.83 μm, and space with the Transiting Exoplanet Survey Satellite from 0.6 to 1.0 μm and the Hubble Space Telescope (HST) Wide Field Camera 3 from 1.12 to 1.65 μm. Archival data from the HST Space Telescope Imaging Spectrograph (STIS) and Spitzer are also re-analysed on a common Gaussian process framework, of which the STIS data show a good overall agreement with the overlapping FORS2 data. We also explore the effects of stellar heterogeneity on our observations and its resulting implications towards determining the atmospheric characteristics of WASP-6b. Independent of our assumptions for the level of stellar heterogeneity we detect Na I, K I, and H2O absorption features and constrain the elemental oxygen abundance to a value of [O/H] ≃ -0.9 ± 0.3 relative to solar. In contrast, we find that the stellar heterogeneity correction can have significant effects on the retrieved distributions of the [Na/H] and [K/H] abundances, primarily through its degeneracy with the sloping optical opacity of scattering haze species within the atmosphere. Our results also show that despite this presence of haze, WASP-6b remains a favourable object for future atmospheric characterization with upcoming missions such as the James Webb Space Telescope

The Hubble Space Telescope PanCET Program: An Optical to Infrared Transmission Spectrum of HAT-P-32Ab

We present a 0.3-5 μm transmission spectrum of the hot Jupiter HAT-P-32Ab observed with the Space Telescope Imaging Spectrograph and Wide Field Camera 3 instruments mounted on the Hubble Space Telescope, combined with Spitzer Infrared Array Camera photometry. The spectrum is composed of 51 spectrophotometric bins with widths ranging between 150 and 400 Å, measured to a median precision of 215 ppm. Comparisons of the observed transmission spectrum to a grid of 1D radiative-convective equilibrium models indicate the presence of clouds/hazes, consistent with previous transit observations and secondary eclipse measurements. To provide more robust constraints on the planet's atmospheric properties, we perform the first full optical to infrared retrieval analysis for this planet. The retrieved spectrum is consistent with a limb temperature of $1248^{+92}_{-92}K$, a thick cloud deck, enhanced Rayleigh scattering, and ∼10× solar $H_2O$ abundance. We find log($Z/Z_☉$) = $2.41^{+0.06}_{-0.07}$, and compare this measurement with the mass-metallicity relation derived for the solar system