Characterizing volcanic ash density and its implications on settling dynamics

Volcanic ash clouds are carefully monitored as they present a significant hazard to humans and aircraft. The primary tool for forecasting the transport of ash from a volcano is dispersion modelling. These models make a number of assumptions about the size, sphericity and density of the ash particles. Few studies have measured the density of ash particles or explored the impact that the assumption of ash density might have on the settling dynamics of ash particles. In this paper, the raw apparent density of 23 samples taken from 15 volcanoes are measured with gas pycnometry, and a negative linear relationship is found between the density and the silica content. For the basaltic ash samples, densities were measured for different particle sizes, showing that the density is approximately constant for particles smaller than 100 µm, beyond which it decreases with size. While this supports the current dispersion model used by the London Volcanic Ash Advisory Centre (VAAC), where the density is held at a constant (2.3 g cm-3), inputting the measured densities into a numerical simulation of settling velocity reveals a primary effect from the silica content changing this constant. The VAAC density overestimates ash removal times by up to 18 %. These density variations, including those varying with size beyond 100 µm, also impact short-range particle-size distribution (PSD) measurements and satellite retrievals of ash

On the cross-section of Dark Matter using substructure infall into galaxy clusters

We develop a statistical method to measure the interaction cross-section of Dark Matter, exploiting the continuous minor merger events in which small substructures fall into galaxy clusters. We find that by taking the ratio of the distances between the galaxies and Dark Matter, and galaxies and gas in accreting sub-halos, we form a quantity that can be statistically averaged over a large sample of systems whilst removing any inherent line-of-sight projections. In order to interpret this ratio as a cross-section of Dark Matter we derive an analytical description of sub-halo infall which encompasses; the force of the main cluster potential, the drag on a gas sub-halo, a model for Dark Matter self-interactions and the resulting sub-halo drag, the force on the gas and galaxies due to the Dark Matter sub-halo potential, and finally the buoyancy on the gas and Dark Matter. We create mock observations from cosmological simulations of structure formation and find that collisionless Dark Matter becomes physically separated from X-ray gas by up to 20h^-1 kpc. Adding realistic levels of noise, we are able to predict achievable constraints from observational data. Current archival data should be able to detect a difference in the dynamical behaviour of Dark Matter and standard model particles at 6 sigma, and measure the total interaction cross-section sigma/m with 68% confidence limits of +/- 1cm2g^-1. We note that this method is not restricted by the limited number of major merging events and is easily extended to large samples of clusters from future surveys which could potentially push statistical errors to 0.1cm^2g^-1.Comment: 14 pages, 11 figure

Understanding the Effect of Body Weight on Muscle Activity During Unilateral Hopping

Running can be described as a series of bilateral single-legged jumps and landings. Interestingly, single-legged jumps and landings are qualitatively more difficult unilaterally than bilaterally known as bilateral deficit syndrome (BDS). For example, one leg will produce less mechanical energy while jump squatting unilaterally than it would produce if both legs worked synchronously. The analysis of dynamic conditions under different levels of body weight support of the hopping movement may prove useful to understanding the bilateral deficit. Purpose: To compare muscle activity of the lower extremity during single-legged hopping at different levels of body weight support. Methods: The research study was recently approved by the Institutional Review Board and data collection has begun. Therefore, no data are presented in the abstract at this time. Subjects will be equipped with electromyography (EMG) leads to measure muscle activity of the rectus femoris, semitendinosus, medial gastrocnemius, and tibialis anterior. Subjects will be asked to perform 5 trials of hopping forwards at a preferred speed (PS) for 1 minute at varying levels of body weight (80%, 70%, 60%, 50%, 40%). EMG data of all four muscles will be compared across the separate body weight control conditions

Reliability and Validity of a Smartphone-Based Inclinometer Application Measuring Shoulder Internal Rotation

This study intended to evaluate the reliability and validity of a smartphone-based inclinometer application and compare these results to those of the standard clinical goniometer. The study measured the internal shoulder rotation of 19 men and 20 women. One third-year physical therapy student took all the smartphone-based inclinometer measurements, and another took all the clinical standard goniometer measurements. The subjects were randomly placed into set amounts of internal rotation, and then the two measurements were taken. The study found no significant difference between the smartphone-based inclinometer and the goniometer. The reliability between the app and the goniometers was good to excellent

Microstructural investigation supporting an abrupt stress induced transformation in amorphous carbon films

The intrinsic stress of carbon thin films deposited by filtered cathodic arc was investigated as a function of ion energy and Ar background gas pressure. The microstructure of the films was analyzed using transmission electron microscopy, electron energy loss spectroscopy, and Raman spectroscopy. The stress at given substrate bias was reduced by the presence of an Ar background gas and by the presence of a Cu underlayer deposited onto the substrate prior to deposition. Auger electron spectroscopy depth profiles showed no evidence of Ar incorporation into the films. A sharp transition from a sp2 to sp3 rich phase was found to occur at a stress of 6.5±1.5 GPa, independent of the deposition conditions. The structural transition at this value of stress is consistent with available data taken from the literature and also with the expected value of biaxial stress at the phase boundary between graphite and diamond at room temperature. The microstructure of films with stress in the transition region near 6.5 GPa was consistent with a mixture of sp2 and sp3 rich structures

Spiropyran-based reversible, light-modulated sensing with reduced photofatigue

Switchable materials have tremendous potential for application in sensor development that could be applied to many fields. We are focusing on emerging area of wireless sensor networks due to the potential impact of this concept in society. Spiropyran-based sensors are probably the most studied type of photoswitchable sensing devices. They suffer from many issues but photofatigue, insufficient selectivity and lack of sensitivity are probably the most important characteristics that hinder their wider application. Here, we are address these issues and demonstrate that covalent attachment of modified spiropyran into a polymeric film significantly reduces photodegradation. The observed signal loss after 12th cycle of switching between the spiropyran and merocyanine forms is only about 27% compared to the loss of 57% of the initial signal in an equivalent experiment based on non-immobilized spiropyran. This has enabled us to demonstrate at least five reversible cycles of detection of an ion of interest (in our case H+) with minimal signal loss. Furthermore, we demonstrate that the sensitivity can be increased by incorporation of additional binding groups in the parent spiropyran molecule. Using molecular modelling to calculate the relevant bond lengths as a measure of interaction between MC and H+, the calculated increase of H-bond strength is approximately an order of magnitude for a derivative containing a methoxy group incorporated in the o-position of the parent spiropyran in comparison to the equivalent unsubstituted phenol. This theoretical result was found to correspond very well with experimental observation. As a result, we have increased the sensitivity to H+ by approximately one order of magnitude

Implementation and performance analysis of bridging Monte Carlo moves for off-lattice single chain polymers in globular states

Bridging algorithms are global Monte Carlo moves which allow for an efficient sampling of single polymer chains. In this manuscript we discuss the adaptation of three bridging algorithms from lattice to continuum models, and give details on the corrections to the acceptance rules which are required to fulfill detailed balance. For the first time we are able to compare the efficiency of the moves by analyzing the occurrence of knots in globular states. For a flexible homopolymer chain of length N=1000, independent configurations can be generated up to two orders of magnitude faster than with slithering snake moves.Comment: 12 pages, 5 figures, preprint submitted to computer physics communication

Can municipality-based post-discharge follow-up visits including a general practitioner reduce early readmission among the fragile elderly (65+ years old)?::a randomized controlled trial

Objective. To evaluate how municipality-based post-discharge follow-up visits including a general practitioner and municipal nurse affect early readmission among high-risk older people discharged from a hospital department of internal medicine. Design and setting. Centrally randomized single-centre pragmatic controlled trial comparing intervention and usual care with investigator-blinded outcome assessment. Intervention. The intervention was home visits with a general practitioner and municipal nurse within seven days of discharge focusing on medication, rehabilitation plan, functional level, and need for further health care initiatives. The visit was concluded by planning one or two further visits. Controls received standard health care services. Patients. People aged 65 + years discharged from Holbæk University Hospital, Denmark, in 2012 considered at high risk of readmission. Main outcome measures. The primary outcome was readmission within 30 days. Secondary outcomes at 30 and 180 days included readmission, primary health care, and municipal services. Outcomes were register-based and analysis used the intention-to-treat principle. Results. A total of 270 and 261 patients were randomized to intervention and control groups, respectively. The groups were similar in baseline characteristics. In all 149 planned discharge follow-up visits were carried out (55%). Within 30 days, 24% of the intervention group and 23% of the control group were readmitted (p = 0.93). No significant differences were found for any other secondary outcomes except that the intervention group received more municipal nursing services. Conclusion. This municipality-based follow-up intervention was only feasible in half the planned visits. The intervention as delivered had no effect on readmission or subsequent use of primary or secondary health care services