Remote Sensing of CDOM, CDOM Spectral Slope, and Dissolved Organic Carbon in the Global Ocean

A Global Ocean Carbon Algorithm Database (GOCAD) has been developed from over 500 oceanographic field campaigns conducted worldwide over the past 30 years including in situ reflectances and coincident satellite imagery, multi- and hyperspectral Chromophoric Dissolved Organic Matter (CDOM) absorption coefficients from 245715 nm, CDOM spectral slopes in eight visible and ultraviolet wavebands, dissolved and particulate organic carbon (DOC and POC, respectively), and inherent optical, physical, and biogeochemical properties. From field optical and radiometric data and satellite measurements, several semi-analytical, empirical, and machine learning algorithms for retrieving global DOC, CDOM, and CDOM slope were developed, optimized for global retrieval, and validated. Global climatologies of satellite-retrieved CDOM absorption coefficient and spectral slope based on the most robust of these algorithms lag seasonal patterns of phytoplankton biomass belying Case 1 assumptions, and track terrestrial runoff on ocean basin scales. Variability in satellite retrievals of CDOM absorption and spectral slope anomalies are tightly coupled to changes in atmospheric and oceanographic conditions associated with El Nio Southern Oscillation (ENSO), strongly covary with the multivariate ENSO index in a large region of the tropical Pacific, and provide insights into the potential evolution and feedbacks related to sea surface dissolved carbon in a warming climate. Further validation of the DOC algorithm developed here is warranted to better characterize its limitations, particularly in mid-ocean gyres and the southern oceans

Neural Networks as a Tool for Constructing Continuous NDVI Time Series from AVHRR and MODIS

The long term Advanced Very High Resolution Radiometer-Normalized Difference Vegetation Index (AVHRR-NDVI) record provides a critical historical perspective on vegetation dynamics necessary for global change research. Despite the proliferation of new sources of global, moderate resolution vegetation datasets, the remote sensing community is still struggling to create datasets derived from multiple sensors that allow the simultaneous use of spectral vegetation for time series analysis. To overcome the non-stationary aspect of NDVI, we use an artificial neural network (ANN) to map the NDVI indices from AVHRR to those from MODIS using atmospheric, surface type and sensor-specific inputs to account for the differences between the sensors. The NDVI dynamics and range of MODIS NDVI data at one degree is matched and extended through the AVHRR record. Four years of overlap between the two sensors is used to train a neural network to remove atmospheric and sensor specific effects on the AVHRR NDVI. In this paper, we present the resulting continuous dataset, its relationship to MODIS data, and a validation of the product

UV/Vis+ Photochemistry Database : Structure, Content and Applications

Acknowledgments This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors. However, the authors are indebted to those colleagues who support us in maintaining the database through the provision of spectral and other photochemical data and information. The National Center for Atmospheric Research is operated by the University Coporation for Atmopsheric Research, under the sponsorship of the National Science Foundation. Disclaimer: The views expressed in this paper are those of the authors and do not necessarily represent the views or policies of the U.S.EPA. Mention of trade names or products does not convey and should not be interpreted as conveying official U.S. EPA approval, endorsement, or recommendation.Peer reviewedPublisher PD

Remote Sensing of CDOM, CDOM Spectral Slope, and Dissolved Organic Carbon in the Global Ocean

A Global Ocean Carbon Algorithm Database (GOCAD) has been developed from over 500 oceanographic field campaigns conducted worldwide over the past 30 years including in situ reflectances and coincident satellite imagery, multi- and hyperspectral Chromophoric Dissolved Organic Matter (CDOM) absorption coefficients from 245⁻715 nm, CDOM spectral slopes in eight visible and ultraviolet wavebands, dissolved and particulate organic carbon (DOC and POC, respectively), and inherent optical, physical, and biogeochemical properties. From field optical and radiometric data and satellite measurements, several semi-analytical, empirical, and machine learning algorithms for retrieving global DOC, CDOM, and CDOM slope were developed, optimized for global retrieval, and validated. Global climatologies of satellite-retrieved CDOM absorption coefficient and spectral slope based on the most robust of these algorithms lag seasonal patterns of phytoplankton biomass belying Case 1 assumptions, and track terrestrial runoff on ocean basin scales. Variability in satellite retrievals of CDOM absorption and spectral slope anomalies are tightly coupled to changes in atmospheric and oceanographic conditions associated with El Niño Southern Oscillation (ENSO), strongly covary with the multivariate ENSO index in a large region of the tropical Pacific, and provide insights into the potential evolution and feedbacks related to sea surface dissolved carbon in a warming climate. Further validation of the DOC algorithm developed here is warranted to better characterize its limitations, particularly in mid-ocean gyres and the southern oceans

PM_2.5 Modeling and Historical Reconstruction over the Continental USA Utilizing GOES-16 AOD

In this study, we present a nationwide machine learning model for hourly PM2.5 estimation for the continental United States (US) using high temporal resolution Geostationary Operational Environmental Satellites (GOES-16) Aerosol Optical Depth (AOD) data, meteorological variables from the European Center for Medium Range Weather Forecasting (ECMWF) and ancillary data collected between May 2017 and December 2020. A model sensitivity analysis was conducted on predictor variables to determine the optimal model. It turns out that GOES16 AOD, variables from ECMWF, and ancillary data are effective variables in PM2.5 estimation and historical reconstruction, which achieves an average mean absolute error (MAE) of 3.0 μg/m3, and a root mean square error (RMSE) of 5.8 μg/m3. This study also found that the model performance as well as the site measured PM2.5 concentrations demonstrate strong spatial and temporal patterns. Specifically, in the temporal scale, the model performed best between 8:00 p.m. and 11:00 p.m. (UTC TIME) and had the highest coefficient of determination (R2) in Autumn and the lowest MAE and RMSE in Spring. In the spatial scale, the analysis results based on ancillary data show that the R2 scores correlate positively with the mean measured PM2.5 concentration at monitoring sites. Mean measured PM2.5 concentrations are positively correlated with population density and negatively correlated with elevation. Water, forests, and wetlands are associated with low PM2.5 concentrations, whereas developed, cultivated crops, shrubs, and grass are associated with high PM2.5 concentrations. In addition, the reconstructed PM2.5 surfaces serve as an important data source for pollution event tracking and PM2.5 analysis. For this purpose, from May 2017 to December 2020, hourly PM2.5 estimates were made for 10 km by 10 km and the PM2.5 estimates from August through November 2020 during the period of California Santa Clara Unite (SCU) Lightning Complex fires are presented. Based on the quantitative and visualization results, this study reveals that a number of large wildfires in California had a profound impact on the value and spatial-temporal distributions of PM2.5 concentrations

Autonomous Learning of New Environments with a Robotic Team Employing Hyper-Spectral Remote Sensing, Comprehensive In-Situ Sensing and Machine Learning

This paper describes and demonstrates an autonomous robotic team that can rapidly learn the characteristics of environments that it has never seen before. The flexible paradigm is easily scalable to multi-robot, multi-sensor autonomous teams, and it is relevant to satellite calibration/validation and the creation of new remote sensing data products. A case study is described for the rapid characterisation of the aquatic environment, over a period of just a few minutes we acquired thousands of training data points. This training data allowed for our machine learning algorithms to rapidly learn by example and provide wide area maps of the composition of the environment. Along side these larger autonomous robots two smaller robots that can be deployed by a single individual were also deployed (a walking robot and a robotic hover-board), observing significant small scale spatial variability

Decoding Physical and Cognitive Impacts of Particulate Matter Concentrations at Ultra-Fine Scales

The human body is an incredible and complex sensing system. Environmental factors trigger a wide range of automatic neurophysiological responses. Biometric sensors can capture these responses in real time, providing clues about the underlying biophysical mechanisms. In this prototype study, we demonstrate an experimental paradigm to holistically capture and evaluate the interactions between an environmental context and physiological markers of an individual operating that environment. A cyclist equipped with a biometric sensing suite is followed by an environmental survey vehicle during outdoor bike rides. The interactions between environment and physiology are then evaluated though the development of empirical machine learning models, which estimate particulate matter concentrations from biometric variables alone. Here, we show biometric variables can be used to accurately estimate particulate matter concentrations at ultra-fine spatial scales with high fidelity (r2 = 0.91) and that smaller particles are better estimated than larger ones. Inferring environmental conditions solely from biometric measurements allows us to disentangle key interactions between the environment and the body. This work sets the stage for future investigations of these interactions for a larger number of factors, e.g., black carbon, CO2, NO/NO2/NOx, and ozone. By tapping into our body’s ‘built-in’ sensing abilities, we can gain insights into how our environment influences our physical health and cognitive performance