Fragmentation of ice by low velocity impact

Low velocity impact experiments (0.14 to l km/s) carried out in polycrystalline water ice targets at 257 and 81 K resulted in interactions which can be assigned to four fragmentation classes, cratering, erosion, disruption, and total fragmentation. Specific kinetic energies for the transitions between these classes range from l x 10^5 to 7 x 10^5 ergs/g for 81 K ice and from 3 x 10^5 to ~ 2 x 10^6 ergs/g for 257 K ice. These values are about one to two orders of magnitude below those for silicate rocks. The mass vs. cumulative number distribution of fragments in our experiments can be described by a simple power law, similar to that observed in fragmented rocks in both the laboratory and in nature. The logarithmic slopes of cumulative number vs. fragment weight vary between - 0.9 and - 1.8 decreasing with increasing projectile energy and are approximately independent of target temperature. The shapes of fragments resulting from erosion and disruption of ice targets are significantly less spherical for 257 K targets than for 81 K targets. Fragment sphericity increases with increasing projectile energy at 257 K, but no similar trend is observed for 81 K ice. Our results support the hypothesis that the specific projectile energy is a measure for target comminution for a relatively wide range of projectile energies and target masses. We apply our results to the collisional interaction of icy planetary bodies and find that the complete destruction of a target body with radii between 50 m and 100 km· range from 10^(17) to 10^(27) ergs. Energies corresponding to basaltic bodies of the same size range from 10^(18) to 10^(28) ergs. Our experiments suggest that regolith components on icy planets resemble those on rocky planetary bodies in size and shape. We predict that the initial shapes of icy particles in the Saturnian ring system were roughly spherical. The initial mass distribution of ring particles should follow a power law with a slope of ~ - 1.5

The shock wave equation of state of brucite Mg(OH)_2

New equation of state (EOS) data for brucite Mg(OH)_2 shocked between 12 and 60 GPa are reported. When combined with earlier data of Simakov et al. (1974), it is found that brucite EOS data between 12 and 97 GPa can be fit with a single linear U_s-u_p relationship: U_s = 4.76(0.11) + 1.35(0.05) u_p. The third order Birch-Murnaghan equation parameters are: K_(os) = 51 ± 4 GPa and K′_(os) = 5.0 ± 0.4. The lack of a U_s-u_p discontinuity indicates that no phase transformation with a significant volume change occurs to at least 97 GPa. However, thermodynamic and theoretical Hugoniot calculations suggest brucite may dehydrate with only a small volume change. A lower bound for this dehydration pressure under shock conditions is inferred to be 26 GPa. We report the first partial release states measured for this material. The data are in quantitative agreement with earlier shock recovery experiments (Lange and Ahrens, 1984). Volatilization upon release begins at pressures as low as 12 GPa, much less than predicted by the shock entropy method. Calculated phase boundaries using the present EOS data are consistent with experimental data and indicate that brucite is unlikely to be stable under lower mantle conditions. However, brucite data, in conjunction with data for silicates and oxides, can be used to infer the effect of H_2O on lower mantle properties. At high pressure, bulk sound velocities calculated for MgO and Mg(OH)_2 are very similar, indicating that the presence of hydrous assemblages in the lower mantle may not produce anomalous bulk seismic velocities. Comparison of densities in brucite and other high-pressure phases under mantle conditions indicates that the water content of the lower mantle is between 0 and 3 wt %

Shock wave apparatus for studying minerals at high pressure and impact phenomena on planetary surfaces

Shock wave and experimental impact phenomena research on geological and planetary materials is being carried out using two propellant (18 and 40 mm) guns (up to 2.5 km/sec) and a two‐stage light gas gun (up to 7 km/sec). Equation of state measurements on samples initially at room temperature and at low and high temperatures are being conducted using the 40 mm propellant apparatus in conjunction with Helmholtz coils, and radiative detectors and, in the case of the light gas gun, with streak cameras. The 18 mm propellant gun is used for recovery experiments on minerals, impact on cryogenic targets, and radiative post‐shock temperature measurements

Following the steps of a reaction by direct imaging of many individual molecules

The dehydrogenation and dechlorination of FeOEP-Cl on Cu(111) has been studied in detail by scanning tunneling microscopy. Although, it is not possible to follow the reaction of an individual molecule, the complete pathway of the reaction with 22 inequivalent intermediate states and the rates of the involved processes are revealed. This is achieved by combining the analysis of a large data set showing thousands of molecules in the different stages of the reaction with numerical simulations

Levosimendan for resuscitating the microcirculation in patients with septic shock: A randomized controlled study

__Introduction:__ The purpose of the present study was to investigate microcirculatory blood flow in patients with septic shock treated with levosimendan as compared to an active comparator drug (i.e. dobutamine). The primary end point was a difference of ≥ 20% in the microvascular flow index of small vessels (MFIs) among groups. __Methods:__ The study was designed as a prospective, randomized, double-blind clinical trial and performed in a multidisciplinary intensive care unit. After achieving normovolemia and a mean arterial pressure of at least 65 mmHg, 40 septic shock patients were randomized to receive either levosimendan 0.2 μg·kg-1·min-1(n = 20) or an active comparator (dobutamine 5 μg·kg-1·min-1; control; n = 20) for 24 hours. Sublingual microcirculatory blood flow of small and medium vessels was assessed by sidestream dark-field imaging. Microcirculatory variables and data from right heart catheterization were obtained at baseline and 24 hours after randomization. Baseline and demographic data were compared by means of Mann-Whitney rank sum test or chi-square test, as appropriate. Microvascular and hemodynamic variables were analyzed using the Mann-Whitney rank sum test. __Results:__ Microcirculatory flow indices of small and medium vessels increased over time and were significantly higher in the levosimendan group as compared to the control group; P = .02; MFIs 2.9. The relative increase of perfused vessel density vs. baseline was significantly higher in the levosimendan group than in the control group. In addition, the heterogeneity index decreased only in the levosimendan group. There was no statistically significant correlation between systemic and microcirculatory flow variables within each group. __Conclusions:__ Compared to a standard dose of 5 μg·kg-1·min-1of dobutamine, levosimendan at 0.2 μg·kg-1·min-1improved sublingual microcirculatory blood flow in patients with septic shock, as reflected by changes in microcirculatory flow indices of small and medium vessels.Trial registration: NCT00800306

Hepatopulmonary syndrome in patients with chronic liver disease: role of pulse oximetry

BACKGROUND: Hepatopulmonary syndrome (HPS) is a rare complication of liver diseases of different etiologies and may indicate a poor prognosis. Therefore, a simple non-invasive screening method to detect HPS would be highly desirable. In this study pulse oximetry was evaluated to identify patients with HPS. METHODS: In 316 consecutive patients with liver cirrhosis (n = 245), chronic hepatitis (n = 69) or non-cirrhotic portal hypertension (n = 2) arterial oxygen saturation (SaO(2)) was determined using a pulse oximeter. In patients with SaO(2 )≤92% in supine position and/or a decrease of ≥4% after change from supine to upright position further diagnostic procedures were performed, including contrast-enhanced echocardiography and perfusion lung scan. RESULTS: Seventeen patients (5.4%) had a pathological SaO(2). Four patients (1.3%) had HPS. HPS patients had a significant lower mean SaO(2 )in supine (89.7%, SD 5.4 vs. 96.0%, SD 2.3; p = 0.003) and upright position (84.3%, SD 5.0 vs. 96.0%, SD 2.4; p = 0.001) and had a lower mean PaO(2 )(56.2 mm Hg, SD 15.2 vs. 71.2 mm Hg, SD 20.2; p = 0.02) as compared to patients without HPS. The mean ΔSaO(2 )(difference between supine and upright position) was 5.50 (SD 7) in HPS patients compared to non-HPS patients who showed no change (p = 0.001). There was a strong correlation between shunt volume and the SaO(2 )values (R = -0.94). CONCLUSION: Arterial SaO(2 )determination in supine and upright position is a useful non-invasive screening test for HPS and correlates well with the intrapulmonary shunt volume