417 research outputs found
Organic bilayer photovoltaics for efficient indoor light harvesting
Indoor organic photovoltaics (OPVs) are a potential niche application for organic semiconductors due to their strong and well-matched absorption with the emission of indoor lighting. However, due to extremely low photocurrent generation, the device parameters critical for efficient indoor OPVs differ from those under 1 Sun conditions. Herein, these critical device parametersârecombination loss and shunt resistance (Rsh)âare identified and it is demonstrated that bilayer OPVs are suitable for indoor PV applications. Compared to bulk-heterojunction (BHJ), the open-circuit voltage loss of bilayer devices under low light intensities is much smaller, consistent with a larger surface photovoltage response, indicating suppressed recombination losses. The bilayer devices show a higher fill factor at low light intensities, resulting from high Rsh afforded by the ideal interfacial contacts between the photoactive and the charge transport layers. The high Rsh enables bilayer devices to perform well without a light-soaking process. Finally, the charge carriers are extracted rapidly in bilayers, which are attributed to strongly suppressed trap states possibly induced by isolated domains and non-ideal interfacial contacts in BHJs. This study highlights the excellent suitability of bilayer OPVs for indoor applications and demonstrates the importance of device architecture and interfacial structures for efficient indoor OPVs
IBIS/PICsIT in-flight performances
PICsIT (Pixellated Imaging CaeSium Iodide Telescope) is the high energy
detector of the IBIS telescope on-board the INTEGRAL satellite. PICsIT operates
in the gamma-ray energy range between 175 keV and 10 MeV, with a typical energy
resolution of 10% at 1 MeV, and an angular resolution of 12 arcmin within a
\~100 square degree field of view, with the possibility to locate intense point
sources in the MeV region at the few arcmin level. PICsIT is based upon a
modular array of 4096 independent CsI(Tl) pixels, ~0.70 cm^2 in cross-section
and 3 cm thick. In this work, the PICsIT on-board data handling and science
operative modes are described. This work presents the in-flight performances in
terms of background count spectra, sensitivity limit, and imaging capabilities.Comment: 8 pages, 4 figures. Accepted for publication on A&A, special issue on
First Science with INTEGRA
Measurement of the non-linearity in the gamma-ray response of the GAGG:Ce inorganic scintillator
A characteristic of every inorganic scintillator crystal is its light yield,
i.e., the amount of emitted scintillation photons per unit of energy deposited
in the crystal. Light yield is known to be usually non-linear with energy,
which impacts the spectroscopic properties of the scintillator. Cerium-doped
gadolinium-aluminium-gallium garnet (GAGG:Ce) is a recently developed
scintillator with several interesting properties, which make it very promising
for space-based gamma-ray detectors, such as in the HERMES nanosatellite
mission. In this paper we report an accurate measurement of the GAGG:Ce
non-linearity in the 20-662 keV gamma-ray energy interval, using a setup
composed of three samples of GAGG:Ce crystals read out by Silicon Drift
Detectors (SDDs).Comment: 22 pages, 11 figures. Accepted for publication in NIM
Outburst of the X-ray transient SAX J1818.6-1703 detected by INTEGRAL in September 2003
During the observation of the Galactic-center field by the INTEGRAL
observatory on September 9, 2003, the IBIS/ISGRI gamma-ray telescope detected a
short (several-hours-long) intense (~380 mCrab at the peak) outburst of hard
radiation from the X-ray transient SAX J1818.6-1703. Previously, this source
was observed only once in 1998 during a similar short outburst. We present the
results of our localization, spectral and timing analyses of the object and
briefly discuss the possible causes of the outburst. The release time of the
bulk of the energy in such an outburst is appreciably shorter than the
accretion (viscous) time that characterizes the flow of matter through a
standard accretion disk.Comment: 16 pages, 7 figures, to be published in Astronomy Letters, v. 31, n.
10, p. 672 (2005
GAME: Grb and All-sky Monitor Experiment
We describe the GRB and All-sky Monitor Experiment (GAME) mission submitted
by a large international collaboration (Italy, Germany, Czech Repubblic,
Slovenia, Brazil) in response to the 2012 ESA call for a small mission
opportunity for a launch in 2017 and presently under further investigation for
subsequent opportunities. The general scientific objective is to perform
measurements of key importance for GRB science and to provide the wide
astrophysical community of an advanced X-ray all-sky monitoring system. The
proposed payload was based on silicon drift detectors (~1-50 keV), CdZnTe (CZT)
detectors (~15-200 keV) and crystal scintillators in phoswich (NaI/CsI)
configuration (~20 keV-20 MeV), three well established technologies, for a
total weight of ~250 kg and a required power of ~240 W. Such instrumentation
allows a unique, unprecedented and very powerful combination of large field of
view (3-4 sr), a broad energy energy band extending from ~1 keV up to ~20 MeV,
an energy resolution as good as ~300 eV in the 1-30 keV energy range, a source
location accuracy of ~1 arcmin. The mission profile included a launch (e.g., by
Vega) into a low Earth orbit, a baseline sky scanning mode plus pointed
observations of regions of particular interest, data transmission to ground via
X-band (4.8 Gb/orbit, Alcantara and Malindi ground stations), and prompt
transmission of GRB / transient triggers.Comment: 13 pages, 8 figures, published in International Journal of Modern
Physics
Scientific prospects in soft gamma-ray astronomy enabled by the LAUE project
This paper summarizes the development of a successful project, LAUE,
supported by the Italian Space Agency (ASI) and devoted to the development of
long focal length (up to 100 m) Laue lenses for hard X--/soft gamma--ray
astronomy (80-600 keV). The apparatus is ready and the assembling of a
prototype lens petal is ongoing. The great achievement of this project is the
use of bent crystals. From measurements obtained on single crystals and from
simulations, we have estimated the expected Point Spread Function and thus the
sensitivity of a lens made of petals. The expected sensitivity is a few
photons cm s keV. We discuss a number of
open astrophysical questions that can settled with such an instrument aboard a
free-flying satellite.Comment: 17 pages, 18 figures, published in Proceedings of the SPIE, Volume
8861, id. 886106 17 pp. (2013
A large spin-up rate measured with INTEGRAL in the High Mass X-ray Binary Pulsar SAXJ2103.5+4545
The High Mass X-ray Binary Pulsar SAXJ2103.5+4545 has been observed with
INTEGRAL several times during the last outburst in 2002-2004. We report a
comprehensive study of all INTEGRAL observations, allowing a study of the pulse
period evolution during the recent outburst. We measured a very rapid spin-up
episode, lasting 130days, which decreased the pulse period by 1.8s. The spin-up
rate, pdot=-1.5e-7 s/s, is the largest ever measured for SAXJ2103.5+4545, and
it is among the fastest for an accreting pulsar. The pulse profile shows
evidence for temporal variability, apparently not related to the source flux or
to the orbital phase. The X-ray spectrum is hard and there is significant
emission up to 150keV. A new derivation of the orbital period, based on RXTE
data, is also reported.Comment: 8 pages, 7 figures, accepted for publication in A&
Molecular orientation-dependent energetic shifts in solution-processed non-fullerene acceptors and their impact on organic photovoltaic performance
The non-fullerene acceptors (NFAs) employed in state-of-art organic photovoltaics (OPVs) often exhibit strong quadrupole moments which can strongly impact on material energetics. Herein, we show that changing the orientation of Y6, a prototypical NFA, from face-on to more edge-on by using different processing solvents causes a significant energetic shift of up to 210âmeV. The impact of this energetic shift on OPV performance is investigated in both bilayer and bulk-heterojunction (BHJ) devices with PM6 polymer donor. The device electronic bandgap and the rate of non-geminate recombination are found to depend on the Y6 orientation in both bilayer and BHJ devices, attributed to the quadrupole moment-induced band bending. Analogous energetic shifts are also observed in other common polymer/NFA blends, which correlates well with NFA quadrupole moments. This work demonstrates the key impact of NFA quadruple moments and molecular orientation on material energetics and thereby on the efficiency of high-performance OPVs
The X-Gamma Imaging Spectrometer (XGIS) onboard THESEUS
A compact and modular X and gamma-ray imaging spectrometer (XGIS) has been
designed as one of the instruments foreseen on-board the THESEUS mission
proposed in response to the ESA M5 call. The experiment envisages the use of
CsI scintillator bars read out at both ends by single-cell 25 mm 2 Silicon
Drift Detectors. Events absorbed in the Silicon layer (lower energy X rays) and
events absorbed in the scintillator crystal (higher energy X rays and
Gamma-rays) are discriminated using the on-board electronics. A coded mask
provides imaging capabilities at low energies, thus allowing a compact and
sensitive instrument in a wide energy band (~2 keV up to ~20 MeV). The
instrument design, expected performance and the characterization performed on a
series of laboratory prototypes are discussed.Comment: To be published in the Proceedings of the THESEUS Workshop 2017
(http://www.isdc.unige.ch/theseus/workshop2017.html), Journal of the Italian
Astronomical Society (Mem.SAIt), Editors L. Amati, E. Bozzo, M. Della Valle,
D. Gotz, P. O'Brien. Details on the THESEUS mission concept can be found in
the white paper Amati et al. 2017 (arXiv:171004638) and Stratta et al. 2017
(arXiv:1712.08153
First AGILE Catalog of High Confidence Gamma-Ray Sources
We present the first catalog of high-confidence gamma-ray sources detected by
the AGILE satellite during observations performed from July 9, 2007 to June 30,
2008. Catalogued sources are detected by merging all the available data over
the entire time period. AGILE, launched in April 2007, is an ASI mission
devoted to gamma-ray observations in the 30 MeV - 50 GeV energy range, with
simultaneous X-ray imaging capability in the 18-60 keV band. This catalog is
based on Gamma-Ray Imaging Detector (GRID) data for energies greater than 100
MeV. For the first AGILE catalog we adopted a conservative analysis, with a
high-quality event filter optimized to select gamma-ray events within the
central zone of the instrument Field of View (radius of 40 degrees). This is a
significance-limited (4 sigma) catalog, and it is not a complete flux-limited
sample due to the non-uniform first year AGILE sky coverage. The catalog
includes 47 sources, 21 of which are associated with confirmed or candidate
pulsars, 13 with Blazars (7 FSRQ, 4 BL Lacs, 2 unknown type), 2 with HMXRBs, 2
with SNRs, 1 with a colliding-wind binary system, 8 with unidentified sources.Comment: Revised version, 15 pages, 3 figures, 3 tables. To be published in
Astronomy and Astrophysics. Text improved and clarified. Refined analysis of
complex regions of the Galactic plane yields a new list of high-confidence
sources including 47 sources (compared with the 40 sources appearing in the
first version
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