33,306 research outputs found
Archaeological building investigation and evaluation : City Tower, Todd Street, Manchester
In July 2016, Salford Archaeology was commissioned by Unique Boutique Hotels
(Manchester) Ltd to undertake an historic building investigation of the former Cathedral
School on Todd Street, Manchester (centred on SJ 8406 9886). Following the demolition of
the building in November 2016, Bowmer & Kirkland Ltd commissioned Salford Archaeology
to carry out an archaeological evaluation on the land. Both elements of the project were
required as part of a redevelopment scheme.
The historic building investigation was commensurate with a Level I-type survey, and the
evaluation comprised the excavation of a single trench, which aimed to establish the presence
or absence of buried archaeological remains within the proposed development area.
An archaeological desk-based assessment compiled in 2010 demonstrated that the study area
had the potential for the survival of remains relating to 18th- and 19th-century buildings,
including housing, public houses and a series of schools. The site’s proximity to the original
medieval core of Manchester also raised the possibility for earlier medieval remains being
present in uncellared areas of the site, particularly within a former central courtyard.
The historic building investigation concluded that the remnants of the former Cathedral
School had been subject to considerable remodelling and alterations during the later 19th and
20th centuries, particularly in the basement and ground floor, with a resultant loss of historic
fabric. The investigation has enabled an appropriate record of the building to be completed
prior to its demolition.
The evaluation trench excavated across the study area revealed that basements had removed
all remains at the south-east and north-west ends of the trench. Natural gravels were observed
between these basements, but did not contain any features of archaeological significance. The
natural gravels were tested by excavating a sondage to 4.2m, and were shown to be consistent
throughout, becoming much more indurated at depth.
The results obtained from the evaluation trenches have indicated that no remains of
archaeological significance survive within the study area, and that no further archaeological
work in advance of development is merited
SERPent: Automated reduction and RFI-mitigation software for e-MERLIN
The Scripted E-merlin Rfi-mitigation PipelinE for iNTerferometry (SERPent) is an automated reduction and RFI-mitigation procedure utilising the SumThreshold methodology (Offringa et al., 2010a), originally developed for the LOFAR pipeline. SERPent is written in the Parseltongue language enabling interaction with the Astronomical Image Processing Software (AIPS) program. Moreover, SERPent is a simple ‘out of the box’ Python script, which is easy to set up and is free of compilers. In addition to the flagging of RFI affected visibilities, the script also flags antenna zero-amplitude dropouts and Lovell telescope phase calibrator stationary scans inherent to the e-MERLIN system.
Both the flagging and computational performances of SERPent are presented here, for e-MERLIN commissioning datasets for both L-band (1.3–1.8 GHz) and C-band (4–8 GHz) observations. RFI typically amounts to <20%–25% for the more problematic L-band observations and <5% for the generally RFI quieter C-band. The level of RFI detection and flagging is more accurate and delicate than visual manual flagging, with the output immediately ready for AIPS calibration. SERPent is fully parallelised and has been tested on a range of computing systems. The current flagging rate is at 110 GB day−1 on a ‘high-end’ computer (16 CPUs, 100 GB memory) which amounts to ∼6.9 GB CPU−1 day−1, with an expected increase in performance when e-MERLIN has completed its commissioning.
The refining of automated reduction and calibration procedures is essential for the e-MERLIN legacy projects and future interferometers such as the SKA and the associated pathfinders (MeerKAT and ASKAP), where the vast data sizes (>TB) make traditional astronomer interactions unfeasible
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Exploring non-adiabaticity to CO reduction reaction through ab initio molecular dynamics simulation
Non-adiabatic chemical reaction refers to the electronic excitation during reactions. This effect cannot be modeled by the ground-state Born-Oppenheimer molecular dynamics (BO-MD), where the electronic structure is at the ground state for every step of ions' movement. Although the non-adiabatic effect has been explored extensively in gas phase reactions, its role in electrochemical reactions, such as water splitting and CO2 reduction, in electrolyte has been rarely explored. On the other hand, electrochemical reactions usually involve electron transport; thus, a non-adiabatic process can naturally play a significant role. In this work, using one-step CO2 reduction as an example, we investigated the role of the non-adiabatic effect in the reaction. The reaction barriers were computed by adiabatic BO-MD and non-adiabatic real-time time dependent density functional theory (rt-TDDFT). We found that by including the non-adiabatic effect, rt-TDDFT could increase the reaction barrier up to 6% compared to the BO-MD calculated barrier when the solvent model is used to represent water. Simulations were carried out using explicit water molecules around the reaction site under different overpotentials, and similar non-adiabatic effects were found
DEFECT PHENOMENA IN SUPERCONDUCTING OXIDES AND ANALOGOUS CERAMIC OXIDES
In this review we discuss defect phenomena in superconducting oxides. We survey those aspects of oxide superconductors which relate them most closely to conventional ceramic oxides, concentrating on processes and behaviour related to defects. We also identify areas of difference between two types of oxide.Theoretical modelling of conventional oxides has been extremely effective, and we emphasize that some of these modelling tools can be exploited for the superconducting oxides too. In particular, we stress those methods and ideas that provide a framework for understanding behaviour, those that provide a datasbase of good quantitative experiments and those that provide an established and tested approach to quantitative modelling as a guide to prediction, optimization and extrapolation.Much progress has been made in both theory and experiment, but some problems do remain and these have not been omitted from our discussions. There is potential to exploit past work on defects in oxides, so as to control defect processes and microstructure and hence to enhance performance
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Wannier–Koopmans method calculations for transition metal oxide band gaps
The widely used density functional theory (DFT) has a major drawback of underestimating the band gaps of materials. Wannier–Koopmans method (WKM) was recently developed for band gap calculations with accuracy on a par with more complicated methods. WKM has been tested for main group covalent semiconductors, alkali halides, 2D materials, and organic crystals. Here we apply the WKM to another interesting type of material system: the transition metal (TM) oxides. TM oxides can be classified as either with d0 or d10 closed shell occupancy or partially occupied open shell configuration, and the latter is known to be strongly correlated Mott insulators. We found that, while WKM provides adequate band gaps for the d0 and d10 TM oxides, it fails to provide correct band gaps for the group with partially occupied d states. This issue is also found in other mean-field approaches like the GW calculations. We believe that the problem comes from a strong interaction between the occupied and unoccupied d-state Wannier functions in a partially occupied d-state system. We also found that, for pseudopotential calculations including deep core levels, it is necessary to remove the electron densities of these deep core levels in the Hartree and exchange–correlation energy functional when calculating the WKM correction parameters for the d-state Wannier functions
Polyandrous females avoid costs of inbreeding
Why do females typically mate with more than one male? Female mating patterns have broad implications for sexual selection, speciation and conflicts of interest between the sexes, and yet they are poorly understood. Matings inevitably have costs, and for females, the benefits of taking more than one mate are rarely obvious. One possible explanation is that females gain benefits because they can avoid using sperm from genetically incompatible males, or invest less in the offspring of such males. It has been shown that mating with more than one male can increase offspring viability, but we present the first clear demonstration that this occurs because females with several mates avoid the negative effects of genetic incompatibility. We show that in crickets, the eggs of females that mate only with siblings have decreased hatching success. However, if females mate with both a sibling and a non-sibling they avoid altogether the low egg viability associated with sibling matings. If similar effects occur in other species, inbreeding avoidance may be important in understanding the prevalence of multiple mating
The accurate staging of ovarian cancer using 3T magnetic resonance imaging - a realistic option
Objectives: The aim of the study was to determine whether staging primary ovarian cancer using 3.0 Tesla (3T) magnetic resonance imaging (MRI) is comparable to surgical staging of the disease. Design: A retrospective study consisting of a search of the pathology database to identify women with ovarian pathology from May 2004 to January 2007. Setting: All women treated for suspected ovarian cancer in our cancer centre region. Sample: All women suspected of ovarian pathology who underwent 3T MRI prior to primary surgical intervention between May 2004 and January 2007. Methods: All women found to have ovarian pathology, both benign and malignant, were then cross checked with the magnetic resonance (MR) database to identify those who had undergone 3T MRI prior to surgery. The resulting group of women underwent comparison of the MR, surgical and histopathological findings for each individual including diagnosis of benign or malignant disease and International Federation of Gynecology and Obstetrics (FIGO) staging where appropriate. Main outcome measures: Comparisons were made between the staging accuracy of 3T MRI and surgical staging compared with histopathological findings and FIGO stage using weighted kappa. Sensitivity, specificity and accuracy were calculated for diagnosing malignant ovarian disease with 3T MRI. Results: A total of 191 women identified as having ovarian pathology underwent imaging with 3T MR and primary surgical intervention. In 19 of these women, the ovarian disease was an incidental finding. The group for which staging methods were compared consisted of 77 women of primary ovarian malignancy (20 of whom had borderline tumours). 3T MRI was able to detect ovarian malignancy with a sensitivity of 92% and a specificity of 76%. The overall accuracy in detecting malignancy with 3T MRI was 84%, with a positive predictive value of 80% and negative predictive value of 90%. Statistical analysis of the two methods of staging using weighted kappa, gave a K value of 0.926 (SE ±0.121) for surgical staging and 0.866 (SE ±0.119) for MR staging. A further analysis of the staging data for ovarian cancers alone, excluding borderline tumours resulted in a K value of 0.931 (SE ±0.136) for histopathological staging versus MR staging and 0.958 (±0.140) for histopathological stage versus surgical staging. Conclusion: Our study has shown that MRI can achieve staging of ovarian cancer comparable with the accuracy seen with surgical staging. No previous studies comparing different modalities have used the higher field strength 3T MRI. In addition, all other studies comparing radiological assessment of ovarian cancer have grouped the stages into I, II, III and IV rather than the more clinically appropriate a, b and c subgroups. © 2008 The Authors
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