The future of bioethanol

Yeasts have been domesticated by mankind before horses. After the mastering of alcoholic fermentation for centuries, yeasts have become the protagonist of one of the most important biotechnological industries worldwide: the production of bioethanol. This chapter will initially present some important challenges to be overcome in this industry, both in first and second generation biofuel production. Then, it will briefly revisit some advances obtained in recent years. Finally, it will present and discuss some opportunities, in the scope of metabolic engineering and synthetic biology, that will likely be present in the future of bioethanol

Non universality of entanglement convertibility

Recently, it has been suggested that operational properties connected to quantum computation can be alternative indicators of quantum phase transitions. In this work we systematically study these operational properties in 1D systems that present phase transitions of different orders. For this purpose, we evaluate the local convertibility between bipartite ground states. Our results suggest that the operational properties, related to non-analyticities of the entanglement spectrum, are good detectors of explicit symmetries of the model, but not necessarily of phase transitions. We also show that thermodynamically equivalent phases, such as Luttinger liquids, may display different convertibility properties depending on the underlying microscopic model.Comment: 5 pages + references, 4 figures - improved versio

Charmed hadron signals of partonic medium

We present a short review of our results on the collectivity and the suppression pattern of charmed mesons in heavy-ion collisions based on the microscopic Hadron-String Dynamics (HSD) transport approach for different scenarios of charm interactions with the surrounding matter - the 'comover' dissociation by mesons with further recreation by D+Dbar channels and 'pre-hadronic' interaction scenarios. While at SPS energies the hadronic 'comover' absorption scenario is found to be compatible with the experimental data, the dynamics of c and cbar quarks at RHIC are dominated by partonic or 'pre-hadronic' interactions in the strongly coupled quark-gluon plasma stage and cannot be modeled by pure hadronic interactions. We find that the collective flow of charm in the purely hadronic scenario appears compatible with the data at SPS energies but underestimates the data at top RHIC energies. Thus, the large elliptic flow v2 of D mesons and the low R_AA(pT) of J/Psi seen experimentally at RHIC have to be attributed to early interactions of non-hadronic degrees of freedom. Simultaneously, we observe that non-hadronic interactions are mandatory in order to describe the narrowing of the J/Psi rapidity distribution from p+p to central Au+Au collisions at the top RHIC energy. We demonstrate additionally that the strong quenching of high-pT J/Psi's in central Au+Au collisions indicates that a fraction of final J/Psi mesons is created by a coalescence mechanism close to the phase boundary.Comment: Talk given at International Conference on Strangeness in Quark Matter (SQM 2008), Beijing, China, 6-10 Oct 200

Oxidation reactions of derivatives of cis-octalins promoted by thallium trinitrate (TTN)

The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF).FAPESPCNPqCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES

Contribution of biomass fires to black carbon supply in a tropical river basin assessed using a Lagrangian atmospheric transport model and MODIS burned area product

Black carbon (BC) is known to be a potential sink of carbon for the global carbon cycle, particularly if long-term ocean stores are reached. Fluvial transport to the oceans can occur through the dissolution of BC in river water. Evidence from the Paraiba do Sul river basin, Brazil suggests that river DBC concentration is related to charcoal formed during the deforestation of the Brazilian Atlantic Forest. However, we highlight several key potential sources of BC to the basin that are yet to be considered. We hypothesize that external biomass fires are a source of BC to the basin on the basis that BC released from them can be transported over large distances before being deposited. This hypothesis is tested by quantifying the number of biomass fires intercepted by trajectories en route to the basin using the HYSPLIT model and a MODIS burned area dataset. We then create a Black Carbon Fallout Index (BCFI) which is rationalized by our assumption that atmospheric BC delivery to the basin is proportional to the number of interceptions of air masses en route to the basin. Our results suggest that the BC fallout from air masses reaching the basin in the dry season can explain 50% of the variance in DBC measured in the PSR channel during a subsequent collection campaign (p<.001). Spatial and temporal variations in the supply of BC to the basin throughout the dry season may in part be linked to the fires associated with the cultivation of sugarcane in southeast Brazil

COMPARISON BETWEEN ANALYTICAL PYROLYSIS AND NITROBENZENE OXIDATION FOR DETERMINATION OF SYRINGYL/GUAIACYL RATIO IN Eucalyptus spp. LIGNIN

Pyrolysis-gas chromatography/mass spectrometry (Py-GC-MS) was applied to measure the lignin syringyl/guaiacyl (S/G) ratio in E. dunni, E. grandis, E. nitens, E. urograndis, and E. urophylla woods. A total of 41 compounds were identified, of which 11 were derived from carbo-hydrates and 30 from lignins. The S/G ratio was calculated on the basis of the areas of peaks recorded in the pyrograms and compared with the results obtained by alkaline nitrobenzene oxidation. The values of S/G found by pyrolysis were similar for all the species using the compounds guaiacol, 4-methylguaiacol, 4-vinylguaiacol, vanillin, 4-ethylsyringol, 4-vinylsyringol, homosyringaldehyde, acetosyringone, and syringylacetone, as lignin markers. The selected markers were efficient for the deter-mination of S/G ratio in eucalyptus wood by Py-GC-MS. The Py-GC-MS technique produced results that are comparable to the nitrobenzene oxidation method, with the advantage of requiring small wood samples and a short analysis time