Optically-controlled long-term storage and release of thermal energy in phase-change materials

Thermal energy storage offers enormous potential for a wide range of energy technologies. Phase-change materials offer state-of-the-art thermal storage due to high latent heat. However, spontaneous heat loss from thermally charged phase-change materials to cooler surroundings occurs due to the absence of a significant energy barrier for the liquid-solid transition. This prevents control over the thermal storage, and developing effective methods to address this problem has remained an elusive goal. Herein, we report a combination of photo-switching dopants and organic phase-change materials as a way to introduce an activation energy barrier for phase-change materials solidification and to conserve thermal energy in the materials, allowing them to be triggered optically to release their stored latent heat. This approach enables the retention of thermal energy (about 200 J g⁻¹) in the materials for at least 10 h at temperatures lower than the original crystallization point, unlocking opportunities for portable thermal energy storage systems

Two-dimensional covalent triazine framework as an ultrathin-film nanoporous membrane for desalination

We computationally demonstrate that two-dimensional covalent triazine frameworks (CTFs) provide opportunities in water desalination. By varying the chemical building blocks, the pore structure, chemistry, and membrane performance can be designed, leading to two orders of magnitude higher water permeability than polyamide membranes while maintaining excellent ability to reject salts.Netherlands Organization for Scientific ResearchUnited States. Dept. of Energy (Contract No. DE-AC02-05CH11231)Deshpande Center for Technological Innovatio

Multilayer Nanoporous Graphene Membranes for Water Desalination

While single-layer nanoporous graphene (NPG) has shown promise as a reverse osmosis (RO) desalination membrane, multilayer graphene membranes can be synthesized more economically than the single-layer material. In this work, we build upon the knowledge gained to date toward single-layer graphene to explore how multilayer NPG might serve as a RO membrane in water desalination using classical molecular dynamic simulations. We show that, while multilayer NPG exhibits similarly promising desalination properties to single-layer membranes, their separation performance can be designed by manipulating various configurational variables in the multilayer case. This work establishes an atomic-level understanding of the effects of additional NPG layers, layer separation, and pore alignment on desalination performance, providing useful guidelines for the design of multilayer NPG membranes.National Science Foundation (U.S.) (grant number ACI-1053575)Netherlands Organization for Scientific Research (NWO

Measurement of sin2beta in tree-dominated B0-decays and ambiguity removal

The most recent results from the B-factories on the time-dependent CP asymmetries measured in B0-decays mediated by b --> c c(bar) s quark-transitions are reviewed. The Standard Model interpretation of the results in terms of the parameter sin2beta leads to a four-fold ambiguity on the unitarity triangle beta which can be reduced to a two-fold ambiguity by measuring the sign of the parameter cos2beta. The results on cos2beta obtained so far are reviewed.Comment: 6 pages, 3 postscript figues, contributed to the Proceedings of Beauty200

Giving to Government: Voluntary Taxation in the Lab

In the United States, there is widespread antipathy toward taxation, yet at the same time there are substantial voluntary donations to nonprofit organizations with missions that are parallel to those of many government agencies. In this paper we compare giving in the form of voluntary taxes paid to government agencies with giving in the form of voluntary donations to nonprofit organizations that have similar missions. In a laboratory experimental setting, subjects are given an endowment, and are given the opportunity to donate any part of the endowment to a government agency or to a nonprofit organization. We compare levels of giving to private and government organizations for four different causes (cancer research, disaster relief, education, and parks and wildlife) at three levels of government (federal, state and local). Within a session, subjects make 12 decisions: they complete all six separate decisions for each of two causes, selected randomly from the four listed above. We find that people are not averse to giving to government. On average, they give 22 percent of their budget to government when anonymity is ensured and giving is completely voluntary. However, they do show a preference for nonprofit charities by giving higher amounts for most causes and levels of government. The willingness to give is influenced by the cause and level of the organization, as well as perceptions of the organization

Heavy particle electroweak loop effects in extra-dimensional models with bulk neutrinos

One way to detect the presence of new particles in theories beyond the standard model is through their contribution to electroweak loop effects. We comment on the importance of a consistent inclusion of their mixing angles to ensure that the physical requirement of heavy particle decoupling is fulfilled. We illustrate our points by a detailed discussion of the lepton flavor changing effect mu-e-gamma, investigated recently by Kitano, in the Randall-Sundrum model. Our remarks are equally applicable to models with large compactified dimensions where bulk neutrinos are introduced to account for the observed neutrino oscillations.Comment: 13 pages; new citations added in Ref [3] and [11

Trapping Penguins with Entangled B Mesons

The first direct observation of time-reversal (T) violation in the $B\bar{B}$ system has been reported by the BaBar collaboration, employing the method of Ba$\tilde {\rm n}\!$uls and Bernab\'eu. Given this, we generalize their analysis of the time-dependent T-violating asymmetry ($A_{T}$) to consider different choices of CP tags for which the dominant amplitudes have the same weak phase. As one application, we find that it is possible to measure departures from the universality of $\sin(2\beta)$ directly. If $\sin(2\beta)$ is universal, as in the Standard Model, the method permits the direct determination of penguin effects in these channels. Our method, although no longer a strict test of T, can yield tests of the $\sin(2\beta)$ universality, or, alternatively, of penguin effects, of much improved precision even with existing data sets.Comment: 11 pages, 2 figures; refs. added; reframed with expanded discussions; version to appear in PLB; Metadata abstract updated onl

Exclusive B-> M \nu \bar{\nu} (M= \pi, K, \rho, K^*) Decays and Leptophobic Z^\prime Model

We consider the exclusive flavor changing neutral current processes B -> M \nu \bar{\nu} (M= \pi, K, \rho, K^*) in the leptophobic Z^\prime model, in which the charged leptons do not couple to the extra Z^\prime boson. We find that these exclusive modes are very effective to constrain the leptophobic Z^\prime model. In the leptophobic Z^\prime model, additional right-handed neutrinos are introduced and they can contribute to the missing energy signal in B -> M + E_missing decays. Through the explicit calculations, we obtain quite stringent bounds on the model parameters, |U_{sb}^{Z^\prime}| \leq 0.29 and |U_{db}^{Z^\prime}| \leq 0.61, from the already existing experimental data. We also briefly discuss an interesting subject of massive right-handed neutrinos, which might be connected with the dark matter problem.Comment: 17 pages, 3 figures, minor corrections, version to appear in PL

Possible evidence for the breakdown of the CKM-paradigm of CP-violation

Using primarily experimental inputs for S(B -> psi Ks), Delta M_Bs, Delta M_Bd, BR(B -> tau nu) and epsilon_K along with necessary inputs from the lattice, we find that the measured value of sin(2 beta) is smaller than expectations of the Standard Model by as much as 3.3 sigma, and also that the measured value of the BR(B -> tau nu) seems to be less than the predicted value by about 2.8 sigma. However, through a critical study we show that most likely the dominant source of these deviations is in B_d(s) mixings and in sin(2 beta) and less so in B -> tau nu, and also that the bulk of the problem persists even if input from epsilon_K is not used. The fact that kaon mixing and epsilon_K are not the dominant source of the deviation from the Standard Model has the very important consequence that model independent considerations imply that the scale of the relevant new CP-violating physics is below O(2 TeV), thus suggesting that direct signals of the new particle(s) may well be accessible in collider experiments at the LHC and perhaps even at the Tevatron.Comment: 6 pages, 8 figures. Added another fit and some more discussion showing that BR(B->tau nu) comes out in good agreement with predictions of the SM if the measured value of sin2beta is not used as an input. References adde

Weak phases from topological-amplitude parametrization

We propose a parametrization for two-body nonleptonic $B$ meson decays, in which the various topologies of amplitudes are counted in terms of powers of the Wolfenstein parameter $\lambda\sim 0.22$. The weak phases and the amplitudes are determined by comparing this parametrization with available measurements. It is possible to obtain the phase $\phi_3$ from the $B\to K\pi$ data up to theoretical uncertainty of $O(\lambda^3)\sim 1$. The recently measured $B_d^0\to\pi^0\pi^0$ branching ratio implies a large color-suppressed or penguin amplitude, and that the extraction of the phase $\phi_2$ from the $B\to\pi\pi$ data may suffer theoretical uncertainty more than the expected one of $O(\lambda^2)\sim 5$.Comment: 11 pages, 4 figure