Salinity gradient energy: Assessment of pressure retarded osmosis and osmotic heat engines for energy generation from low-grade heat sources

Development of clean energy technologies that maximize efficiency and minimize resource consumption is a necessary component for a clean and secure energy future. The osmotic heat engine (OHE) is a closed-loop, membrane based process that utilizes low-grade heat and salinity-gradient energy between two streams for electrical energy generation. The OHE couples pressure retarded osmosis (PRO), an osmotically driven membrane process, with membrane distillation (MD), a thermally driven membrane process. In PRO, water permeates via osmosis through a semi-permeable membrane from a low concentration feed stream into a higher concentration brine (draw solution). The permeate stream becomes pressurized on the high concentration side of the membrane and a mechanical device (e.g., turbine generator set) is used to convert the hydraulic pressure to electrical energy. The MD process utilizes low-grade heat to reconcentrate the diluted brine from the PRO process and to produce a deionized water stream; these streams are then resupplied to the PRO process in the OHE. High power-density (power generated per unit area of membrane) of the PRO membrane is essential to maximize the efficiency and minimize the capital and operating costs of the OHE. Likewise, high separation efficiency is needed in the MD process to effectively reconcentrate the diluted draw solution. Thus, robust PRO membranes that can support high pressure, have high water flux, low reverse salt flux, low structural parameter, and a good membrane support structure are essential. The MD process must also be able to withstand high operating temperatures (\u3e 60 ºC) and feed water concentrations, and have low pore wetting propensity. Additionally, the use of highly soluble ionic organic and inorganic draw solutions can increase PRO power densities while achieving high MD water fluxes, thus increasing efficiencies and decreasing costs of OHE. Please click Additional Files below to see the full abstract

Rank-Ordering Statistics of Extreme Events: Application to the Distribution of Large Earthquakes

Rank-ordering statistics provides a perspective on the rare, largest elements of a population, whereas the statistics of cumulative distributions are dominated by the more numerous small events. The exponent of a power law distribution can be determined with good accuracy by rank-ordering statistics from the observation of only a few tens of the largest events. Using analytical results and synthetic tests, we quantify the systematic and the random errors. We also study the case of a distribution defined by two branches, each having a power law distribution, one defined for the largest events and the other for smaller events, with application to the World-Wide (Harvard) and Southern California earthquake catalogs. In the case of the Harvard moment catalog, we make more precise earlier claims of the existence of a transition of the earthquake magnitude distribution between small and large earthquakes; the $b$-values are $b_2 = 2.3 \pm 0.3$ for large shallow earthquakes and $b_1 = 1.00 \pm 0.02$ for smaller shallow earthquakes. However, the cross-over magnitude between the two distributions is ill-defined. The data available at present do not provide a strong constraint on the cross-over which has a $50\%$ probability of being between magnitudes $7.1$ and $7.6$ for shallow earthquakes; this interval may be too conservatively estimated. Thus, any influence of a universal geometry of rupture on the distribution of earthquakes world-wide is ill-defined at best. We caution that there is no direct evidence to confirm the hypothesis that the large-moment branch is indeed a power law. In fact, a gamma distribution fits the entire suite of earthquake moments from the smallest to the largest satisfactorily. There is no evidence that the earthquakes of the Southern California catalog have a distribution with tw

Modes of random lasers

In conventional lasers, the optical cavity that confines the photons also determines essential characteristics of the lasing modes such as wavelength, emission pattern, directivity, and polarization. In random lasers, which do not have mirrors or a well-defined cavity, light is confined within the gain medium by means of multiple scattering. The sharp peaks in the emission spectra of semiconductor powders, first observed in 1999, has therefore lead to an intense debate about the nature of the lasing modes in these so-called lasers with resonant feedback. We review numerical and theoretical studies aimed at clarifying the nature of the lasing modes in disordered scattering systems with gain. The past decade has witnessed the emergence of the idea that even the low-Q resonances of such open systems could play a role similar to the cavity modes of a conventional laser and produce sharp lasing peaks. We focus here on the nearthreshold single-mode lasing regime where nonlinear effects associated with gain saturation and mode competition can be neglected.We discuss in particular the link between random laser modes near threshold and the resonances or quasi-bound (QB) states of the passive system without gain. For random lasers in the localized (strong scattering) regime, QB states and threshold lasing modes were found to be nearly identical within the scattering medium. These studies were later extended to the case of more lossy systems such as random systems in the diffusive regime, where it was observed that increasing the openness of such systems eventually resulted in measurable and increasing differences between quasi-bound states and lasing modes. Very recently, a theory able to treat lasers with arbitrarily complex and open cavities such as random lasers established that the threshold lasing modes are in fact distinct from QB states of the passive system and are better described in terms of a new class of states, the so-called constant-flux states. The correspondence between QB states and lasing modes is found to improve in the strong scattering limit, confirming the validity of initial work in the strong scattering limit. © 2010 Optical Society of America

Draft genome sequence of the commercial biocontrol strain Pantoea agglomerans P10c

We report here the draft genome sequence of the biocontrol strain Pantoea agglomerans P10c, composed of a draft chromosome and two plasmids: the 559-kb large Pantoea plasmid 1 (pPag3) and a 182-kb plasmid (pPag1). A genomic island containing pantocin A biosynthesis genes was identified

Emission of photon echoes in a strongly scattering medium

We observe the two- and three-pulse photon echo emission from a scattering powder, obtained by grinding a Pr$^{3+}$:Y$_2$SiO$_5$ rare earth doped single crystal. We show that the collective emission is coherently constructed over several grains. A well defined atomic coherence can therefore be created between randomly placed particles. Observation of photon echo on powders as opposed to bulk materials opens the way to faster material development. More generally, time-domain resonant four-wave mixing offers an attractive approach to investigate coherent propagation in scattering media

Strong Interactions in Multimode Random Lasers

Unlike conventional lasers, diffusive random lasers (DRLs) have no resonator to trap light and no high-Q resonances to support lasing. Due to this lack of sharp resonances the DRL has presented a challenge to conventional laser theory. We present a theory able to treat the DRL rigorously, and provide results on the lasing spectra, internal fields and output intensities of DRLs. Typically DRLs are highly multimode lasers, emitting light at a number of wavelengths. We show that the modal interactions through the gain medium in such lasers are extremely strong and lead to a uniformly spaced frequency spectrum, in agreement with recent experimental observations.Comment: 13 pages, 4 figures. Supplementary information available at arXiv:0805.449

N-Acyl Homoserine Lactones and Lux Solos Regulate Social Behaviour and Virulence of Pseudomonas syringae pv. actinidiae

The phyllosphere is a complex environment where microbes communicate through signalling molecules in a system, generally known as quorum sensing (QS). One of the most common QS systems in Gram-negative proteobacteria is based on the production of N-acyl homoserine lactones (AHLs) by a LuxI synthase and their perception by a LuxR sensor. Pseudomonas syringae pv. actinidiae (Psa), the aetiological agent of the bacterial canker of kiwifruit, colonises plant phyllosphere before penetrating via wounds and natural openings. Since Psa genome encodes three LuxR solos without a cognate LuxI, this bacterium may perceive diffusible signals, but it cannot produce AHLs, displaying a non-canonical QS system. The elucidation of the mechanisms underlying the perception of environmental cues in the phyllosphere by this pathogen and their influence on the onset of pathogenesis are of crucial importance for a long-lasting and sustainable management of the bacterial canker of kiwifruit. Here, we report the ability of Psa to sense its own population density and the presence of surrounding bacteria. Moreover, we show that Psa can perceive AHLs, indicating that AHL-producing neighbouring bacteria may regulate Psa virulence in the host. Our results suggest that the ecological environment is important in determining Psa fitness and pathogenic potential. This opens new perspectives in the use of more advanced biochemical and microbiological tools for the control of bacterial canker of kiwifruit

Vortical and Wave Modes in 3D Rotating Stratified Flows: Random Large Scale Forcing

Utilizing an eigenfunction decomposition, we study the growth and spectra of energy in the vortical and wave modes of a 3D rotating stratified fluid as a function of $\epsilon = f/N$. Working in regimes characterized by moderate Burger numbers, i.e. $Bu = 1/\epsilon^2 < 1$ or $Bu \ge 1$, our results indicate profound change in the character of vortical and wave mode interactions with respect to $Bu = 1$. As with the reference state of $\epsilon=1$, for $\epsilon < 1$ the wave mode energy saturates quite quickly and the ensuing forward cascade continues to act as an efficient means of dissipating ageostrophic energy. Further, these saturated spectra steepen as $\epsilon$ decreases: we see a shift from $k^{-1}$ to $k^{-5/3}$ scaling for $k_f < k < k_d$ (where $k_f$ and $k_d$ are the forcing and dissipation scales, respectively). On the other hand, when $\epsilon > 1$ the wave mode energy never saturates and comes to dominate the total energy in the system. In fact, in a sense the wave modes behave in an asymmetric manner about $\epsilon = 1$. With regard to the vortical modes, for $\epsilon \le 1$, the signatures of 3D quasigeostrophy are clearly evident. Specifically, we see a $k^{-3}$ scaling for $k_f < k < k_d$ and, in accord with an inverse transfer of energy, the vortical mode energy never saturates but rather increases for all $k < k_f$. In contrast, for $\epsilon > 1$ and increasing, the vortical modes contain a progressively smaller fraction of the total energy indicating that the 3D quasigeostrophic subsystem plays an energetically smaller role in the overall dynamics.Comment: 18 pages, 6 figs. (abbreviated abstract