Oxidation studies. I. Oxidation of primary alcohols by peroxydisulfate

Results on the oxidation of primary alcohols (methanol, ethanol, n-propanol, n-butanol and isobutanol) by peroxydisulfate in aqueous solution in the temperature range 50°-80°, under uncatalysed, Ag+ catalysed and deaerated conditions are presented. Oxygen was found to have a retarding effect on the rate of peroxydisulfate disappearance, -RS2O3−, and the inhibition period was a maximum in the case of ethanol and isobutanol. Both under uncatalysed and Ag+ catalysed conditions -RS2O3− varied with [S2O8-]3/2 for all the alcohols; -RS2O3− was independent of alcohol concentration for all the alcohols except for methanol and ethanol where a one-half order with respect to [alcohol] was observed. In the Ag+ catalysed oxidation -RS2O3− varied as [Ag+]½ with all the alcohols. The effect of [H+], ionic strength, temperature, initially added product of the reaction on the rate are discussed and the stoichiometries of the reactions determined. In the light of the observed results, reaction mechanisms are postulated with SO4•− as the reactive species formed by thermal decomposition of S2O8− under uncatalysed conditions and by the interaction of Ag+ and S2O8- under Ag+ catalysed conditions. The existence of Ag++ in catalysed reactions is postulated. The values of rate constants, frequency factors, energies of activation entropies of activation, etc., were evaluated

Vortex behavior near a spin vacancy in 2D XY-magnets

The dynamical behavior of anisotropic two dimensional Heisenberg models is still a matter of controversy. The existence of a central peak at all temperatures and a rich structure of magnon peaks are not yet understood. It seems that the central peaks are related, in some way, to structures like vortices. In order to contribute to the discussion of the dynamical behavior of the model we use Monte Carlo and spin dynamics simulations as well analytical calculations to study the behavior of vortices in the presence of nonmagnetic impurities. Our simulations show that vortices are attracted and trapped by the impurities. Using this result we show that if we suppose that vortices are not very much disturbed by the presence of the impurities, then they work as an attractive potential to the vortices explaining the observed behavior in our simulations.Comment: 4 pages, 6 figure

Monte Carlo study of the critical temperature for the planar rotator model with nonmagnetic impurities

We performed Monte Carlo simulations to calculate the Berezinskii-Kosterlitz-Thouless (BKT) temperature $T_{BKT}$ for the two-dimensional planar rotator model in the presence of nonmagnetic impurity concentration $(\rho)$. As expected, our calculation shows that the BKT temperature decreases as the spin vacancies increase. There is a critical dilution $\rho_c \approx 0.3$ at which $T_{BKT} =0$. The effective interaction between a vortex-antivortex pair and a static nonmagnetic impurity is studied analytically. A simple phenomenological argument based on the pair-impurity interaction is proposed to justify the simulations.Comment: 5 pages, 5 figures, Revetex fil

Marine fisheries of the south-west coast of India during 2008

The south-west region comprising the states of Kerala, Karnataka and Goa with a coastline of 994 km and 7.83 lakh fishermen population, had been the most productive and the largest contributor to the country’s total marine fish landings. Marine fish production in this region during the year 2008 has been estimated as 11.11 lakh t, contributing about 34.5% to the all India landing

Discommensurational and Inhomogeneous States Induced by a Strong Magnetic Field in Low-Dimensional Antiferromagnets

Anisotropic antiferromagnetic systems of dimensionality greater than one in an external field are shown to exhibit a complicated array of ground states depending on the spin structure of the surface. The simplest structure that exhibits these effects is the spin ladder with the surface being the ladder end, which can be either compensated or non-compensated spins. The structure with the compensated end has a surface spin flop phase, the non-compensated end has a discommensurational phase, and the transition to these phases can be either first or second order with a tricritical point.Comment: 10 page

Estimated marine fish landings (in tonnes)in India during 2002 and 2003

Estimated marine fishing landing in India during 2002 and 2003 is 2.59 and 2.58 millon tonnes respectively. Gear wise landing were also estimated during this period

Morphology of supported polymer electrolyte ultra-thin films: a numerical study

Morphology of polymer electrolytes membranes (PEM), e.g., Nafion, inside PEM fuel cell catalyst layers has significant impact on the electrochemical activity and transport phenomena that determine cell performance. In those regions, Nafion can be found as an ultra-thin film, coating the catalyst and the catalyst support surfaces. The impact of the hydrophilic/hydrophobic character of these surfaces on the structural formation of the films has not been sufficiently explored yet. Here, we report about Molecular Dynamics simulation investigation of the substrate effects on the ionomer ultra-thin film morphology at different hydration levels. We use a mean-field-like model we introduced in previous publications for the interaction of the hydrated Nafion ionomer with a substrate, characterized by a tunable degree of hydrophilicity. We show that the affinity of the substrate with water plays a crucial role in the molecular rearrangement of the ionomer film, resulting in completely different morphologies. Detailed structural description in different regions of the film shows evidences of strongly heterogeneous behavior. A qualitative discussion of the implications of our observations on the PEMFC catalyst layer performance is finally proposed

Overview of marine fisheries in India during 2007

Fisheries sector in India plays an important role in the country’s economy and it supports the livelihood of millions of people. India is having 8,129 km of coastal length with 2.02 million sq. km of Exclusive Economic Zone (upto 200 m depth) and 0.452 million sq. km of continental shelf area

Heavy Quark Solitons: Strangeness and Symmetry Breaking

We discuss the generalization of the Callan-Klebanov model to the case of heavy quark baryons. The light flavor group is considered to be $SU(3)$ and the limit of heavy spin symmetry is taken. The presence of the Wess-Zumino-Witten term permits the neat development of a picture , at the collective level, of a light diquark bound to a ``heavy" quark with decoupled spin degree of freedom. The consequences of $SU(3)$ symmetry breaking are discussed in detail. We point out that the $SU(3)$ mass splittings of the heavy baryons essentially measure the ``low energy" physics once more and that the comparison with experiment is satisfactory.Comment: 17 pages, RevTEX. Minor typos corrected and new references adde

Effective Hadron Dynamics: From Meson Masses to the Proton Spin Puzzle

We construct a three flavor chiral Lagrangian of pseudoscalars and vectors with special emphasis on the symmetry breaking terms. Comparing tree level two and three point functions with experiment allows us to first, fix the parameters of the model (including the light quark mass ratios) and second, to predict $m(K^{*+})-m(K^{*\circ}),\, \Gamma(K^*\rightarrow K\pi)$ and $\Gamma(\phi\rightarrow K {\overline K})$. The last mentioned quantities come out reasonably well, in contrast to an ``ordinary" $SU(3)$ treatment. For this purpose we need ``second order" symmetry breakers involving the vector fields analogous to those needed for the chiral perturbation theory program with only pseudoscalars. An improved description of the $\eta-\eta^\prime$ system is also given. We then use the soliton sector of this improved chiral Lagrangian to investigate some aspects of baryon physics which are especially sensitive to symmetry breaking. For this purpose a fairly elaborate ``cranking" techinque is employed in connection with the collective Hamiltonian. In addition to the ``strong" baryon mass spectrum a careful investigation is made of the non-electromagnetic part of the neutron-proton mass difference. This work is needed to improve our previous estimates concerning the two component approach to the ``proton spin" puzzle. We find that both the ``matter" and ``glue" contributions are small but they do tend to cancel each other.Comment: 33 pages, LaTe