527 research outputs found
Magnetization Process of Nanoscale Iron Cluster
Low-temperature magnetization process of the nanoscale iron cluster in
linearly sweeped fields is investigated by a numerical analysis of
time-dependent Schrdinger equation and the quantum master
equation. We introduce an effective basis method extracting important states,
by which we can obtain the magnetization process effectively. We investigate
the structure of the field derivative of the magnetization. We find out that
the antisymmetric interaction determined from the lattice structure reproduces
well the experimental results of the iron magnets and that this interaction
plays an important role in the iron cluster. Deviations from the adiabatic
process are also studied. In the fast sweeping case, our calculations indicate
that the nonadiabatic transition dominantly occurs at the level crossing for
the lowest field. In slow sweeping case, due to the influence of the thermal
environment to the spin system, the field derivative of the magnetization shows
an asymmetric behavior, the magnetic Fhn effect, which explains
the substructure of the experimental results in the pulsed field.Comment: 5 pages of text and 2 pages of 6 figures. To appear in J. Phys. Soc.
Jp
Patterning molecular scale paramagnets at Au Surface: A root to Magneto-Molecular-Electronics
Few examples of the exploitation of molecular magnetic properties in
molecular electronics are known to date. Here we propose the realization of
Self assembled monolayers (SAM) of a particular stable organic radical. This
radical is meant to be used as a standard molecule on which to prove the
validity of a single spin reading procedure known as ESR-STM. We also discuss a
range of possible applications, further than ESR-STM, of magnetic monolayers of
simple purely organic magnetic molecule.Comment: This preprint is currently partially under revisio
Model Exact Low-Lying States and Spin Dynamics in Ferric Wheels; Fe to Fe
Using an efficient numerical scheme that exploits spatial symmetries and
spin-parity, we have obtained the exact low-lying eigenstates of exchange
Hamiltonians for ferric wheels up to Fe. The largest calculation
involves the Fe ring which spans a Hilbert space dimension of about 145
million for M=0 subspace. Our calculated gaps from the singlet ground state
to the excited triplet state agrees well with the experimentally measured
values. Study of the static structure factor shows that the ground state is
spontaneously dimerized for ferric wheels. Spin states of ferric wheels can be
viewed as quantized states of a rigid rotor with the gap between the ground and
the first excited state defining the inverse of moment of inertia. We have
studied the quantum dynamics of Fe as a representative of ferric wheels.
We use the low-lying states of Fe to solve exactly the time-dependent
Schr\"odinger equation and find the magnetization of the molecule in the
presence of an alternating magnetic field at zero temperature. We observe a
nontrivial oscillation of magnetization which is dependent on the amplitude of
the {\it ac} field. We have also studied the torque response of Fe as a
function of magnetic field, which clearly shows spin-state crossover.Comment: Revtex, 24 pages, 8 eps figure
Finite-size effects on the dynamic susceptibility of CoPhOMe single-chain molecular magnets in presence of a static magnetic field
The static and dynamic properties of the single-chain molecular magnet
[Co(hfac)NITPhOMe] are investigated in the framework of the Ising model
with Glauber dynamics, in order to take into account both the effect of an
applied magnetic field and a finite size of the chains. For static fields of
moderate intensity and short chain lengths, the approximation of a
mono-exponential decay of the magnetization fluctuations is found to be valid
at low temperatures; for strong fields and long chains, a multi-exponential
decay should rather be assumed. The effect of an oscillating magnetic field,
with intensity much smaller than that of the static one, is included in the
theory in order to obtain the dynamic susceptibility . We find
that, for an open chain with spins, can be written as a
weighted sum of frequency contributions, with a sum rule relating the
frequency weights to the static susceptibility of the chain. Very good
agreement is found between the theoretical dynamic susceptibility and the ac
susceptibility measured in moderate static fields ( kOe),
where the approximation of a single dominating frequency turns out to be valid.
For static fields in this range, new data for the relaxation time,
versus , of the magnetization of CoPhOMe at low temperature are
also well reproduced by theory, provided that finite-size effects are included.Comment: 16 pages, 9 figure
Chiral Quantization of the WZW Model
We quantize the Wess-Zumino-Witten model in terms of left and right
chiral variables choosing an appropriate gauge and we compare our results with
the results that have been previously obtained in the algebraic treatment of
the problem. The algebra of the chiral vertex operators in the fundamental
representation is verified by solving appropriate Knizhnik-Zamolodchikov
equations.Comment: 35 pages, latex, no figures, corrections in the chiral decomposition
of the vertex operators in the WZW model are introduce
Proton nuclear magnetic resonance as a probe of the dynamics of Zn(II)-doped CoPhOMe molecular chains
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