A climo and litho soil-sequence on the Vico volcano (Italy)

A la suite d'une cartographie pédologique détaillée de la majeure partie de l'appareil volcanique de Vico (Italie), une séquence topoclimatique a été définie. Cing profils ont été choisis à des altitudes représentatives des principales zones climatiques. Les changements observés dans les sols correspondent bien aux effets de variations significatives des paramètres climatique

Reactive Metals as Energy Storage and Carrier Media: Use of Aluminum for Power Generation in Fuel Cell-Based Power Plants

In recent years, the energy production sector has experienced a growing interest in new energy vectors enabling energy storage and, at the same time, intersectoral energy applications among users. Hydrogen is one of the most promising energy storage and carrier media featuring a very high gravimetric energy density, but a rather low volumetric energy density. To this regard, this study focuses on the use of aluminum as energy storage and carrier medium, offering high volumetric energy density (23.5 kWh L$^{-1}$), ease to transport and stock (e.g., as ingots), and is neither toxic nor dangerous when stored. In addition, mature production and recycling technologies exist for aluminum. Herein, the performance of power systems driven by aluminum powder in terms of electrical efficiency (η$_{(I)}$) and round‐trip efficiency (RTE) is analyzed. Along with the additional advantages relating to high volumetric energy density, and safety and management aspects, the aluminum‐based technology appears to outperform the power‐to‐power systems based on hydrogen and liquid fuels

Experimental investigation of SO2 poisoning in a Molten Carbonate Fuel Cell operating in CCS configuration

[EN] One of the most interesting innovations in the CCS (Carbon Capture and Storage) field is the use of MCFCs as carbon dioxide concentrators, feeding their cathode side (or air side) with the exhaust gas of a traditional power plant. The feasibility of this kind of application depends on the resistance of the MCFC to air-side contaminants, with particular attention to SO2. The aim of this work is to investigate the effects of poisoning when sulphur dioxide is added to the cathodic stream in various concentrations and in different operating conditions. This study was carried out operating single cells (80 cm(2)) with a cathodic feeding composition simulating typical flue gas conditions, i.e. N-2, H2O, O-2 and CO2 in 73:9:12:6 mol ratio as reference mixture. On the anodic side a base composition was chosen with H-2, CO2 and H2O in 64:16:20 mol ratio. Starting from these reference mixtures, the effect of single species on cell poisoning was experimentally investigated considering, as main parameters chosen for the sensitivity analysis, SO2 (0-24 ppm) and CO2 (4-12%) content in the cathodic feeding mixture, H-2 (40-64%) content in the anodic stream as well as the operating temperature (620-680 degrees C). Results showed that degradation caused by SO2 poisoning is strongly affected by the operating conditions. Data gathered during this experimental campaign will be used in a future work to model the poisoning mechanisms through the definition of MCFC electrochemical kinetics which take into account the SO2 effects. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.The work was partly supported by H2FC European Infrastructure Project (Integrating European Infrastructure to support science and development of Hydrogen and Fuel Cell Technologies towards European Strategy for Sustain-able Competitive and Secure Energy) Theme [INFRA-2011-1.1.16.], Grant agreement 284522.Della Pietra, M.; Discepoli, G.; Bosio, B.; Mcphail, S.; Barelli, L.; Bidini, G.; Ribes-Greus, A. (2016). Experimental investigation of SO2 poisoning in a Molten Carbonate Fuel Cell operating in CCS configuration. International Journal of Hydrogen Energy. 41(41):18822-18836. https://doi.org/10.1016/j.ijhydene.2016.05.147S1882218836414

Repeated (4D) marine geophysical surveys as a tool for studying the coastal environment and ground-truthing remote-sensing observations and modeling

Sandy beaches and the nearshore environment are dynamic coastal systems characterized by sediment mobilization driven by alternating stormy and mild wave conditions. However, this natural behavior of beaches can be altered by coastal defense structures. Repeated surveys carried out with autonomous surface vehicles (ASVs) may represent an interesting tool for studying nearshore dynamics and testing the effects of mitigation strategies against erosion. We present a one-year experiment involving repeated stratigraphic and morpho-bathymetric surveys of a nearshore environment prone to coastal erosion along the Emilia-Romagna coast (NE Italy), the Lido di Dante beach, carried out between October 2020 and December 2021 using an ASV. Seafloor and subseafloor “snapshots” collected at different time intervals enabled us to delineate the seasonal variability and shed light on key controlling variables, which could be used to integrate and calibrate remote-sensing observations and modeling. The results demonstrated that repeated surveys could be successfully employed for monitoring coastal areas and represent a promising tool for studying coastal dynamics on a medium/short (years/months) timescale

Space and Time pattern of mid-velocity IMF emission in peripheral heavy-ion collisions at Fermi energies

The emission pattern in the V_perp - V_par plane of Intermediate Mass Fragments with Z=3-7 (IMF) has been studied in the collision 116Sn + 93Nb at 29.5 AMeV as a function of the Total Kinetic Energy Loss of the reaction. This pattern shows that for peripheral reactions most of IMF's are emitted at mid-velocity. Coulomb trajectory calculations demonstrate that these IMF's are produced in the early stages of the reaction and shed light on geometrical details of these emissions, suggesting that the IMF's originate both from the neck and the surface of the interacting nuclei.Comment: 4 pages, 3 figures, RevTex 3.1, submitted to Phys. Rev. Letter

Fiasco: a multidetector optimized for semiperipheral heavy ion collisions at Fermi energies

The Fiasco multidetector is a low-threshold apparatus, optimized for the investigation of peripheral to semi-central collisions in heavy ion reactions at Fermi energies. It consists of three types of detectors. The first detector layer is a shell of 24 position-sensitive Parallel Plate Avalanche Detectors (PPADs), covering about 70% of the forward hemisphere, which measure the velocity vectors of the heavy ðZ\10Þ reaction products. Below and around the grazing angle, behind the most forward PPADs, there are 96 DE–E silicon telescopes (with thickness of 200 and 500 mm; respectively); they are mainly used to measure the energy of the projectile-like fragment and to identify its charge and, via the time-of-flight of the PPADs, also its mass. Finally, behind most of the PPADs there are 158 (or 182, depending on the configuration) scintillation detectors, mostly of the phoswich type, which cover 25–30% of the forward hemisphere; they identify both light charged particles ðZ ¼ 1; 2Þ and intermediate mass fragments ð3pZt20Þ; measuring also their time-of-flight. r 2003 Elsevier B.V. All rights reserved

Study of the carbonation-calcination reaction applied to the hydrogen production from syngas

In the last years the interest in hydrogen as an energy carrier is significantly increased both for vehicle fuelling and stationary energy production by fuel cells. The benefits of a hydrogen energy policy are the reduction of the greenhouse effect and the centralization of the emission sources. Moreover, an improvement to the environmental benefits can be achieved if hydrogen is produced from renewable sources, as biomass. The present study relates the development of an innovative system for hydrogen production and CO(2) capture starting from syngas. The plant is based on the carbonation and calcination reactions for CO(2) absorption and desorption, respectively. In the carbonation reactor also steam methane reforming and CO-shift take place to enhance the hydrogen production. By means of a thermodynamic analysis, the system has been optimized in terms of the amount of the hydrogen produced and its purity. Different syngas compositions have been tested. The results confirm the effectiveness of the system proposed, which provides 99% H(2) purity and zero CO(2) emission in the case of the syngas derived from Battelle Columbus Laboratories gasifier