Effects of lipids on the water sorption, glass transition and structural strength of carbohydrate-protein systems

peer-reviewedEncapsulant systems are gaining wide practical interest due to their functional and nutritional properties. This paper was focusing on understanding structural relaxations in that systems near glass transition temperature. Freeze-dried trehalose-whey protein isolate-sunflower oil systems with various ratios of the last were used as a carbohydrate-protein-lipid food model. The Guggenheim-Anderson-de Boer (GAB) water sorption relationship was used as a tool to model water sorption isotherms. The glass transition temperature was obtained by differential scanning calorimetry (DSC). Structural α-relaxation temperatures were measured by dynamical mechanical analyses (DMA), dielectric analysis (DEA) and combined to cover a broad range for strength assessment. The microstructure was characterized by optical light microscopy, confocal laser scanning microscopy and scanning electron microscopy. The C1 and C2 constants for Williams-Landel-Ferry (WLF) equation and structural strength parameter were calculated for each system. The effect of sunflower oil and water contents on strength of carbohydrate-protein system was analyzed. Strength shows decreasing with increasing of lipid concentration in the mixtures and more complex dependence on the water content in a system.This investigation was supported by the Food Institutional Research Measure (FIRM) project “Formulation and Design for Food Structure and Stability” funded by the Department of Agriculture, Food and Marine (11-F-001), coordinated by prof. Y.H. Roos, UCC, Ireland and by the Food Institutional Research Measure (FIRM) project “Developing the next generation of high protein spray dried dairy powders with enhanced hydration properties” (15-F-679) funded by the Department of Agriculture, Food and Marine, coordinated by Dr. Mark Auty, Teagasc Food Research Centre, Moorepark, Co. Cork, Ireland

Relativistic linear stability equations for the nonlinear Dirac equation in Bose-Einstein condensates

We present relativistic linear stability equations (RLSE) for quasi-relativistic cold atoms in a honeycomb optical lattice. These equations are derived from first principles and provide a method for computing stabilities of arbitrary localized solutions of the nonlinear Dirac equation (NLDE), a relativistic generalization of the nonlinear Schr\"odinger equation. We present a variety of such localized solutions: skyrmions, solitons, vortices, and half-quantum vortices, and study their stabilities via the RLSE. When applied to a uniform background, our calculations reveal an experimentally observable effect in the form of Cherenkov radiation. Remarkably, the Berry phase from the bipartite structure of the honeycomb lattice induces a boson-fermion transmutation in the quasi-particle operator statistics.Comment: 6 pages, 3 figure

Underlying modal data issues for detecting damage in truss structures

Independent of the modal identification techniques employed for damage detection, use of measured modal data limits the expectations for damage location. These limitations are examined using the distribution of modal strain energy and the sensitivity of the frequency and mode shapes to structural stiffness changes. For given measured modal information of specific accuracy, this examination reveals the following: (1) damage detection is feasible for members that contribute significantly to the strain energy of the measured modes, (2) the modes which are most effective in detecting damage to certain critical members can be identified, and (3) a relationship can be drawn between the accuracy of the measured modes and frequencies and damage detection feasibility

Tracking in a space variant active vision system

Without the ability to foveate on and maintain foveation, active vision for applications such as surveillance, object recognition and object tracking are difficult to build. Although foveation in cartesian coordinates is being actively pursued by many, multi-resolution high accuracy foveation in log polar space has not been given much attention. This paper addresses the use of foveation to track a single object as well as multiple objects for a simulated space variant active vision system. Complex logarithmic mapping is chosen firstly because it provides high resolution and wide angle viewing. Secondly, the spatially variant structure of log polar space leads to an object increasing in size as it moves towards the fovea. This is important as we know which object is closer to the fovea at any instant in time.<br /

Unexpected phase locking of magnetic fluctuations in the multi-k magnet USb

The spin waves in the multi-k antiferromagnet USb soften and become quasielastic well below the antiferromagnetic ordering temperature TN. This occurs without a magnetic or structural transition. It has been suggested that this change is in fact due to dephasing of the different multi-k components: a switch from 3-k to 1-k behavior. In this work, we use inelastic neutron scattering with tridirectional polarization analysis to probe the quasielastic magnetic excitations and reveal that the 3-k structure does not dephase. More surprisingly, the paramagnetic correlations also maintain the same clear phase correlations well above TN (up to at least 1.4TN)

Finite temperature Casimir pistons for electromagnetic field with mixed boundary conditions and its classical limit

In this paper, the finite temperature Casimir force acting on a two-dimensional Casimir piston due to electromagnetic field is computed. It was found that if mixed boundary conditions are assumed on the piston and its opposite wall, then the Casimir force always tends to restore the piston towards the equilibrium position, regardless of the boundary conditions assumed on the walls transverse to the piston. In contrary, if pure boundary conditions are assumed on the piston and the opposite wall, then the Casimir force always tend to pull the piston towards the closer wall and away from the equilibrium position. The nature of the force is not affected by temperature. However, in the high temperature regime, the magnitude of the Casimir force grows linearly with respect to temperature. This shows that the Casimir effect has a classical limit as has been observed in other literatures.Comment: 14 pages, 3 figures, accepted by Journal of Physics

Discovery of Radio Emission from the Tight M8 Binary: LP 349-25

We present radio observations of 8 ultracool dwarfs with a narrow spectral type range (M8-M9.5) using the Very Large Array at 8.5 GHz. Only the tight M8 binary LP 349-25 was detected. LP 349-25 is the tenth ultracool dwarf system detected in radio and its trigonometric parallax pi = 67.6 mas, recently measured by Gatewood et al., makes it the furthest ultracool system detected by the Very Large Array to date, and the most radio-luminous outside of obvious flaring activity or variability. With a separation of only 1.8 AU, masses of the components of LP 349-25 can be measured precisely without any theoretical assumptions (Forveille et al.), allowing us to clarify their fully-convective status and hence the kind of magnetic dynamo in these components which may play an important role to explain our detection of radio emission from these objects. This also makes LP 349-25 an excellent target for further studies with better constraints on the correlations between X-ray, radio emission and stellar parameters such as mass, age, temperature, and luminosity in ultracool dwarfs.Comment: accepted by ApJ, referee's comments included, typo in equation 1 correcte

Morphology controls the thermoelectric power factor of a doped semiconducting polymer.

The electrical performance of doped semiconducting polymers is strongly governed by processing methods and underlying thin-film microstructure. We report on the influence of different doping methods (solution versus vapor) on the thermoelectric power factor (PF) of PBTTT molecularly p-doped with F n TCNQ (n = 2 or 4). The vapor-doped films have more than two orders of magnitude higher electronic conductivity (σ) relative to solution-doped films. On the basis of resonant soft x-ray scattering, vapor-doped samples are shown to have a large orientational correlation length (OCL) (that is, length scale of aligned backbones) that correlates to a high apparent charge carrier mobility (μ). The Seebeck coefficient (α) is largely independent of OCL. This reveals that, unlike σ, leveraging strategies to improve μ have a smaller impact on α. Our best-performing sample with the largest OCL, vapor-doped PBTTT:F4TCNQ thin film, has a σ of 670 S/cm and an α of 42 μV/K, which translates to a large PF of 120 μW m-1 K-2. In addition, despite the unfavorable offset for charge transfer, doping by F2TCNQ also leads to a large PF of 70 μW m-1 K-2, which reveals the potential utility of weak molecular dopants. Overall, our work introduces important general processing guidelines for the continued development of doped semiconducting polymers for thermoelectrics