Molten salt corrosion of SiC and Si3N4

Industrial systems such as heat engines and heat exchangers involve harsh environments. The structural materials are subjected to high temperatures as well as corrosive gases and condensed phases. Past experience with metal alloys has shown that these condensed phases can be particularly corrosive and are often the limiting factor in the operation of these systems. In a heat engine the most common condensed corrodent is Na2SO4 whereas in a heat exchanger an oxide slag may be present. The primary emphasis is on Na2SO4 induced corrosion, however, similarities and differences to oxide slag are also discussed. The extensive research on corrosion of metal alloys has led to understanding and controlling corrosion for these materials. Currently silicon based ceramics are prime candidates for the applications discussed. Therefore it is important to understand the effects of condensed phase deposits on this emerging class of high temperature materials. Both the thermodynamic and strength of the ceramic is also examined. Finally some control strategies for corrosion of silicon based ceramics are explored

Hot corrosion of ceramic engine materials

A number of commercially available SiC and Si3N4 materials were exposed to 1000 C in a high velocity, pressurized burner rig as a simulation of a turbine engine environment. Sodium impurities added to the burner flame resulted in molten Na2SO4 deposition, attack of the SiC and Si4N4 and formation of substantial Na2O-x(SiO2) corrosion product. Room temperature strength of the materials decreased. This was a result of the formation of corrosion pits in SiC, and grain boundary dissolution and pitting in Si3N4. Corrosion regimes for such Si-based ceramics have been predicted using thermodynamics and verified in rig tests of SiO2 coupons. Protective mullite coatings are being investigated as a solution to the corrosion problem for SiC and Si3N4. Limited corrosion occurred to cordierite (Mg2Al4Si5O18) but some cracking of the substrate occurred

Are geometric morphometric analyses replicable? Evaluating landmark measurement error and its impact on extant and fossil Microtus classification.

Geometric morphometric analyses are frequently employed to quantify biological shape and shape variation. Despite the popularity of this technique, quantification of measurement error in geometric morphometric datasets and its impact on statistical results is seldom assessed in the literature. Here, we evaluate error on 2D landmark coordinate configurations of the lower first molar of five North American Microtus (vole) species. We acquired data from the same specimens several times to quantify error from four data acquisition sources: specimen presentation, imaging devices, interobserver variation, and intraobserver variation. We then evaluated the impact of those errors on linear discriminant analysis-based classifications of the five species using recent specimens of known species affinity and fossil specimens of unknown species affinity. Results indicate that data acquisition error can be substantial, sometimes explaining >30% of the total variation among datasets. Comparisons of datasets digitized by different individuals exhibit the greatest discrepancies in landmark precision, and comparison of datasets photographed from different presentation angles yields the greatest discrepancies in species classification results. All error sources impact statistical classification to some extent. For example, no two landmark dataset replicates exhibit the same predicted group memberships of recent or fossil specimens. Our findings emphasize the need to mitigate error as much as possible during geometric morphometric data collection. Though the impact of measurement error on statistical fidelity is likely analysis-specific, we recommend that all geometric morphometric studies standardize specimen imaging equipment, specimen presentations (if analyses are 2D), and landmark digitizers to reduce error and subsequent analytical misinterpretations

A Search for N2+ in Spectra of Comet C/2002C1 (Ikeya-Zhang)

We report low- and high-resolution spectra of comet C/2002 C1 (Ikeya-Zhang) from McDonald Observatory. The comet had a well-developed ion tail including CO+, CO2+, CH+, and H2O+. We used our high-resolution spectra to search for N2+. None was detected and we placed upper limits on N2+/CO+ of 5.4 times 10^{-4}. N2+ was detected in the low-resolution spectra but we show that this emission was probably telluric in origin (if cometary, we derive N2+/CO+ = 5.5 times 10^{-3}, still very low). We discuss the implications for the conditions in the early solar nebula of the non-detection of N2+. These depend on whether the H2O ice was deposited in the amorphous or crystalline form. If H2O was deposited in its crystalline form, the detection of CO+ but not N2+ has implications for H2O/H2 in the early solar nebula.Comment: Accepted for publication in ApJ (Letters) - 10 Sept 200

Multi-filter transit observations of WASP-39b and WASP-43b with three San Pedro M\'artir telescopes

Three optical telescopes located at the San Pedro M\'artir National Observatory were used for the first time to obtain multi-filter defocused photometry of the transiting extrasolar planets WASP-39b and WASP-43b. We observed WASP-39b with the 2.12m telescope in the U filter for the first time, and additional observations were carried out in the R and I filters using the 0.84m telescope. WASP-43b was observed in VRI with the same instrument, and in the i filter with the robotic 1.50m telescope. We reduced the data using different pipelines and performed aperture photometry with the help of custom routines, in order to obtain the light curves. The fit of the light curves (1.5--2.5mmag rms), and of the period analysis, allowed a revision of the orbital and physical parameters, revealing for WASP-39b a period ($4.0552947 \pm 9.65 \times 10^{-7}$ days) which is $3.084 \pm 0.774$ seconds larger than previously reported. Moreover, we find for WASP-43b a planet/star radius ($0.1738 \pm 0.0033$) which is $0.01637 \pm 0.00371$ larger in the i filter with respect to previous works, and that should be confirmed with additional observations. Finally, we confirm no evidence of constant period variations in WASP-43b.Comment: 13 pages, 7 figures, accepted in PASP, scheduled for the February 1, 2015 issu

Genome-Wide Association to Body Mass Index and Waist Circumference: The Framingham Heart Study 100K Project

BACKGROUND: Obesity is related to multiple cardiovascular disease (CVD) risk factors as well as CVD and has a strong familial component. We tested for association between SNPs on the Affymetrix 100K SNP GeneChip and measures of adiposity in the Framingham Heart Study. METHODS: A total of 1341 Framingham Heart Study participants in 310 families genotyped with the Affymetrix 100K SNP GeneChip had adiposity traits measured over 30 years of follow up. Body mass index (BMI), waist circumference (WC), weight change, height, and radiographic measures of adiposity (subcutaneous adipose tissue, visceral adipose tissue, waist circumference, sagittal height) were measured at multiple examination cycles. Multivariable-adjusted residuals, adjusting for age, age-squared, sex, smoking, and menopausal status, were evaluated in association with the genotype data using additive Generalized Estimating Equations (GEE) and Family Based Association Test (FBAT) models. We prioritized mean BMI over offspring examinations (1–7) and cohort examinations (10, 16, 18, 20, 22, 24, 26) and mean WC over offspring examinations (4–7) for presentation. We evaluated associations with 70,987 SNPs on autosomes with minor allele frequencies of at least 0.10, Hardy-Weinberg equilibrium p ≥ 0.001, and call rates of at least 80%. RESULTS: The top SNPs to be associated with mean BMI and mean WC by GEE were rs110683 (p-value 1.22*10-7) and rs4471028 (p-values 1.96*10-7). Please see for the complete set of results. We were able to validate SNPs in known genes that have been related to BMI or other adiposity traits, including the ESR1 Xba1 SNP, PPARG, and ADIPOQ. CONCLUSION: Adiposity traits are associated with SNPs on the Affymetrix 100K SNP GeneChip. Replication of these initial findings is necessary. These data will serve as a resource for replication as more genes become identified with BMI and WC.National Heart, Lung, and Blood Institute's Framingham Heart Study (N01-HC-25195); Atwood (R01 DK066241); National Institutes of Health National Center for Research Resources Shared Instrumentation grant (1S10RR163736-01A1

VADA: A transformation-based system for variable dependence analysis

Variable dependence is an analysis problem in which the aim is to determine the set of input variables that can affect the values stored in a chosen set of intermediate program variables. This paper shows the relationship between the variable dependence analysis problem and slicing and describes VADA, a system that implements variable dependence analysis. In order to cover the full range of C constructs and features, a transformation to a core language is employed Thus, the full analysis is required only for the core language, which is relatively simple. This reduces the overall effort required for dependency analysis. The transformations used need preserve only the variable dependence relation, and therefore need not be meaning preserving in the traditional sense. The paper describes how this relaxed meaning further simplifies the transformation phase of the approach. Finally, the results of an empirical study into the performance of the system are presented