79 research outputs found
Theoretical and experimental study of high-pressure synthesized B20-type compounds Mn(Co,Rh)Ge
The search and exploration of new materials not found in nature is one of
modern trends in pure and applied chemistry. In the present work, we report on
experimental and \textit{ab initio} density-functional study of the
high-pressure-synthesized series of compounds Mn(Co,Rh)Ge. These
high-pressure phases remain metastable at normal conditions, therewith they
preserve their inherent noncentrosymmetric B20-type structure and chiral
magnetism. Of particular interest in these two isovalent systems is the
comparative analysis of the effect of (Co) and (Rh) substitution for
Mn, since the orbitals are characterized by higher localization and
electron interaction than the orbitals. The behavior of
Mn(Co,Rh)Ge systems is traced as the concentration changes in the
range . We applied a sensitive experimental and theoretical
technique which allowed to refine the shape of the temperature dependencies of
magnetic susceptibility and thereby provide a new and detailed
magnetic phase diagram of MnCoGe. It is shown that both systems
exhibit a helical magnetic ordering that very strongly depends on the
composition . However, the phase diagram of MnCoGe differs from
that of MnRhGe in that it is characterized by coexistence of two
helices in particular regions of concentrations and temperatures.Comment: 12 pages, 11 figure
Electrochemical Generation of Solvated Electrons and Hydrogen Evolution in Hexamethylphosphortriamide
Electrolysis experiments with rotating disc electrodes of copper,
amalgamated copper, and platinum in anhydrous hexamethylphosphortriamide are described. It is shown that the generation
of solvated electrons is a primary process. In the same
solutions (0.2 M LiCl + 0.09 to 0.20 M HCl) hydrogen evolution
occurs as a direct proton discharge step and not through a reaction
with the solvated electron(s)
Translation error detection as rationale extraction
Recent Quality Estimation (QE) models based on multilingual pre-trained representations have achieved very competitive results when predicting the overall quality of translated sentences. Predicting translation errors, i.e. detecting specifically which words are incorrect, is a more challenging task, especially with limited amounts of training data. We hypothesize that, not unlike humans, successful QE models rely on translation errors to predict overall sentence quality. By exploring a set of feature attribution methods that assign relevance scores to the inputs to explain model predictions, we study the behaviour of state-of-the-art sentence-level QE models and show that explanations (i.e. rationales) extracted from these models can indeed be used to detect translation errors. We therefore (i) introduce a novel semi-supervised method for word-level QE and (ii) propose to use the QE task as a new benchmark for evaluating the plausibility of feature attribution, i.e. how interpretable model explanations are to humans
Magnetic ground state and spin fluctuations in MnGe chiral magnet as studied by Muon Spin Rotation
We have studied by muon spin resonance ({\mu}SR) the helical ground state and
fluctuating chiral phase recently observed in the MnGe chiral magnet. At low
temperature, the muon polarization shows double period oscillations at short
time scales. Their analysis, akin to that recently developed for MnSi [A. Amato
et al., Phys. Rev. B 89, 184425 (2014)], provides an estimation of the field
distribution induced by the Mn helical order at the muon site. The refined muon
position agrees nicely with ab initio calculations. With increasing
temperature, an inhomogeneous fluctuating chiral phase sets in, characterized
by two well separated frequency ranges which coexist in the sample. Rapid and
slow fluctuations, respectively associated with short range and long range
ordered helices, coexist in a large temperature range below T = 170 K. We
discuss the results with respect to MnSi, taking the short helical period,
metastable quenched state and peculiar band structure of MnGe into account.Comment: 13 pages, 11 figure
Electrochemical Generation of Solvated Electrons and Hydrogen Evolution in Hexamethylphosphortriamide
Electrolysis experiments with rotating disc electrodes of copper,
amalgamated copper, and platinum in anhydrous hexamethylphosphortriamide are described. It is shown that the generation
of solvated electrons is a primary process. In the same
solutions (0.2 M LiCl + 0.09 to 0.20 M HCl) hydrogen evolution
occurs as a direct proton discharge step and not through a reaction
with the solvated electron(s)
Unsupervised quality estimation for neural machine translation
Quality Estimation (QE) is an important component in making Machine Translation (MT) useful in real-world applications, as it is aimed to inform the user on the quality of the MT output at test time. Existing approaches require large amounts of expert annotated data, computation and time for training. As an alternative, we devise an unsupervised approach to QE where no training or access to additional resources besides the MT system itself is required. Different from most of the current work that treats the MT system as a black box, we explore useful information that can be extracted from the MT system as a by-product of translation. By employing methods for uncertainty quantification, we achieve very good correlation with human judgments of quality, rivalling state-of-the-art supervised QE models. To evaluate our approach we collect the first dataset that enables work on both black-box and glass-box approaches to QE
- …