4,608 research outputs found
Influence of the Synthesis Method on the Preparation Composites Derived from TiO2-LDH for Phenol Photodegradation
Three different TiO2 catalysts are prepared using different methods. MgAl-CO32â layered double hydroxides (LDH) were obtained by the sol-gel method. In the preparation of the composites, the three photocatalysts were combined with LDH following different methodologies. The composites were characterized using X-ray diffraction (XRD), specific surface area (SA), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). The influence of the synthesis method on the preparation of the composites was evaluated by analyzing their photocatalytic activity against phenol as a model organic pollutant under UV irradiation. The photocatalytic activity of the composites improves when the chemical interaction, determined by XPS, between the TiO2 and the LDH decreases. The same happens when the ratio of the anatase-rutile phases, determined by XRD, approaches optimum (80:20%). The effect of the composite concentration in the solution (0.5â2.0 g/L) was investigated, and the light-shielding phenomenon due to high composite concentration decreases the phenol photodegradation. The reduction of photocatalytic activity in reuse cycles is due to loss and partial deactivation of the material. The elimination of phenol is attributed primarily to the photocatalytic process due to the generation of âOH radicals and to a lesser extent the adsorption process also present in the samples
Temperature dependence of the anomalous effective action of fermions in two and four dimensions
The temperature dependence of the anomalous sector of the effective action of
fermions coupled to external gauge and pseudo-scalar fields is computed at
leading order in an expansion in the number of Lorentz indices in two and four
dimensions. The calculation preserves chiral symmetry and confirms that a
temperature dependence is compatible with axial anomaly saturation. The result
checks soft-pions theorems at zero temperature as well as recent results in the
literature for the pionic decay amplitude into static photons in the chirally
symmetric phase. The case of chiral fermions is also considered.Comment: RevTex, 19 pages, no figures. References adde
A simulation analysis of an influenza vaccine production plant in areas of high humanitarian flow. A preliminary study for the region of norte de santander (colombia)
The production of vaccines of biological origin presents a tremendous challenge for re-searchers. In this context, animal cell cultures are an excellent alternative for the isolation and production of biologicals against several viruses, since they have an affinity with viruses and a great capacity for their replicability. Different variables have been studied to know the systemâs ideal parameters, allowing it to obtain profitable and competitive products. Consequently, this work fo-cuses its efforts on evaluating an alternative for producing an antiâinfluenza biological from MDCK cells using SuperPro Designer v8.0 software. The process uses the DMEN culture medium supple-mented with nutrients as raw material for cell development; the MDCK cells were obtained from a potential scaleâup with a final working volume of 500 L, four days of residence time, inoculum volume of 10%, and continuous working mode with up to a total of 7400 h/Yr of work. The scheme has the necessary equipment for the vaccineâs production, infection, and manufacture with yields of up to 416,698 units/h. In addition, it was estimated to be economically viable to produce recom-binant vaccines with competitive prices of up to 0.31 USD/unit
Herschel/HIFI observations of molecular emission in protoplanetary nebulae and young planetary nebulae
We performed Herschel/HIFI observations of intermediate-excitation molecular
lines in the far-infrared/submillimeter range in a sample of ten protoplanetary
nebulae and young planetary nebulae. The high spectral resolution provided by
HIFI yields accurate measurements of the line profiles. The observation of
these high-energy transitions allows an accurate study of the excitation
conditions, particularly in the warm gas, which cannot be properly studied from
the low-energy lines.
We have detected FIR/sub-mm lines of several molecules, in particular of
12CO, 13CO, and H2O. Emission from other species, like NH3, OH, H2^{18}O, HCN,
SiO, etc, has been also detected. Wide profiles showing sometimes spectacular
line wings have been found. We have mainly studied the excitation properties of
the high-velocity emission, which is known to come from fast bipolar outflows.
From comparison with general theoretical predictions, we find that CRL 618
shows a particularly warm fast wind, with characteristic kinetic temperature Tk
>~ 200 K. In contrast, the fast winds in OH 231.8+4.2 and NGC 6302 are cold, Tk
~ 30 K. Other nebulae, like CRL 2688, show intermediate temperatures, with
characteristic values around 100 K. We also discuss how the complex structure
of the nebulae can affect our estimates, considering two-component models. We
argue that the differences in temperature in the different nebulae can be due
to cooling after the gas acceleration (that is probably due to shocks); for
instance, CRL 618 is a case of very recent acceleration, less than ~ 100 yr
ago, while the fast gas in OH 231.8+4.2 was accelerated ~ 1000 yr ago. We also
find indications that the densest gas tends to be cooler, which may be
explained by the expected increase of the radiative cooling efficiency with the
density.Comment: 24 pages, 31 figure
Electromagnetic Evidence that SSS17a is the Result of a Binary Neutron Star Merger
11 hours after the detection of gravitational wave source GW170817 by the
Laser Interferometer Gravitational-Wave Observatory and Virgo Interferometers,
an associated optical transient SSS17a was discovered in the galaxy NGC 4993.
While the gravitational wave data indicate GW170817 is consistent with the
merger of two compact objects, the electromagnetic observations provide
independent constraints of the nature of that system. Here we synthesize all
optical and near-infrared photometry and spectroscopy of SSS17a collected by
the One-Meter Two-Hemisphere collaboration. We find that SSS17a is unlike other
known transients. The source is best described by theoretical models of a
kilonova consisting of radioactive elements produced by rapid neutron capture
(the r-process). We find that SSS17a was the result of a binary neutron star
merger, reinforcing the gravitational wave result.Comment: 21 pages, 4 figures, accepted to Scienc
Urinary Excretion of Mimosine Metabolites by Hair Sheep Fed Foliage of \u3cem\u3eLeucaena leucocephala\u3c/em\u3e
Leucaena leucocephala is an adapted legume widely distributed in the tropical regions of Mexico. The high crude protein content of leucaena leaves renders it appropriate for ruminant feeding under commercial conditions. However, the foliage contains the non-protein amino acid mimosine, which, if consumed in high amounts, may induce toxicity in animals which have not previously consumed the legume or without microorganisms capable of degrading mimosine and its derivatives 2,3-DHP (dihydroxypyridine) and 3,4-DHP (Hammond 1995, Palmer et al. 2010, Dalzell et al. 2012). Barros-RodrĂguez et al. (2012) found that dry matter intake and weight gain were reduced when sheep grazed paddocks with 55,000 plants of leucaena per hectare. Early work in Australia led to the isolation of Synergistes jonesii, an anaerobic bacterium able to degrade 3,4-DHP and 2,3-DHP to non-toxic compounds (Allison et al. 1992). In Mexico, the presence of this microorganism in the rumen has not yet been confirmed. Inoculation of non-accustomed animals with rumen liquor of ruminants adapted to the consumption of leucaena can reduce the impact of mimosine and its metabolites on animal health (Ghosh et al. 2009; Palmer et al. 2010). The aim of the present work was to evaluate the effects of transferring rumen liquor of cows adapted to the consumption of L. leucocephala to sheep without experience of consumption, on urinary excretion of 3.4-DHP and 2.3-DHP by means of a colorimetric technique
Light Curves of the Neutron Star Merger GW170817/SSS17a: Implications for R-Process Nucleosynthesis
On 2017 August 17, gravitational waves were detected from a binary neutron
star merger, GW170817, along with a coincident short gamma-ray burst,
GRB170817A. An optical transient source, Swope Supernova Survey 17a (SSS17a),
was subsequently identified as the counterpart of this event. We present
ultraviolet, optical and infrared light curves of SSS17a extending from 10.9
hours to 18 days post-merger. We constrain the radioactively-powered transient
resulting from the ejection of neutron-rich material. The fast rise of the
light curves, subsequent decay, and rapid color evolution are consistent with
multiple ejecta components of differing lanthanide abundance. The late-time
light curve indicates that SSS17a produced at least ~0.05 solar masses of heavy
elements, demonstrating that neutron star mergers play a role in r-process
nucleosynthesis in the Universe.Comment: Accepted to Scienc
Managing ethnic conflict : the menu of institutional engineering
The debate on institutional engineering offers options to manage ethnic and other conflicts. This contribution systematically assesses the logic of these institutional designs and the empirical evidence on their functioning. Generally, institutions can work on ethnic conflict by either accommodating (âconsociationalistsâ) or denying (âintegrationistsâ) ethnicity in politics. Looking at individual and combined institutions (e.g. state structure, electoral system, forms of government), the literature review finds that most designs are theoretically ambivalent and that empirical evidence on their effectiveness is mostly inconclusive. The following questions remain open: a) Is politicized ethnicity really a conflict risk? b) What impact does the whole âmenuâ (not just single institutions) have? and c) How are effects conditioned by the exact nature of conflict risks
Structure of the Collision Zone Between the Nazca Ridge and the Peruvian Convergent Margin: Geodynamic and Seismotectonic Implications
We study the structure and tectonics of the collision zone between the Nazca Ridge (NR) and the Peruvian margin constrained by seismic, gravimetric, bathymetric, and natural seismological data. The NR was formed in an on-ridge setting, and it is characterized by a smooth and broad shallow seafloor (swell) with an estimated buoyancy flux of ~7 Mg/s. The seismic results show that the NR hosts an oceanic lower crust 10â14 km thick with velocities of 7.2â7.5 km/s suggesting intrusion of magmatic material from the hot spot plume to the oceanic plate. Our results show evidence for subduction erosion in the frontal part of the margin likely enhanced by the collision of the NR. The ridge-trench collision zone correlates with the presence of a prominent normal scarp, a narrow continental slope, and (uplifted) shelf. In contrast, adjacent of the collision zone, the slope does not present a topographic scarp and the continental slope and shelf become wider and deeper. Geophysical and geodetic evidence indicate that the collision zone is characterized by low seismic coupling at the plate interface. This is consistent with vigorous subduction erosion enhanced by the subducting NR causing abrasion and increase of fluid pore pressure at the interplate contact. Furthermore, the NR has behaved as a barrier for rupture propagation of megathrust earthquakes (e.g., 1746 Mw 8.6 and 1942 Mw 8.1 events). In contrast, for moderate earthquakes (e.g., 1996 Mw 7.7 and 2011 Mw 6.9 events), the NR has behaved as a seismic asperity nucleating at depths >20 km
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