126 research outputs found
Synthesis, Structure and Properties of Tetragonal Sr2M3As2O2 (M3 = Mn3, Mn2Cu and MnZn2) Compounds Containing Alternating CuO2-Type and FeAs-Type Layers
Polycrystalline samples of Sr2Mn2CuAs2O2, Sr2Mn3As2O2, and Sr2Zn2MnAs2O2 were
synthesized. Their temperature- and applied magnetic field-dependent
structural, transport, thermal, and magnetic properties were characterized by
means of x-ray and neutron diffraction, electrical resistivity rho, heat
capacity, magnetization and magnetic susceptibility measurements. These
compounds have a body-centered-tetragonal crystal structure (space group
I4/mmm) that consists of MO2 (M = Zn and/or Mn) oxide layers similar to the
CuO2 layers in high superconducting transition temperature Tc cuprate
superconductors, and intermetallic MAs (M = Cu and/or Mn) layers similar to the
FeAs layers in high-Tc pnictides. These two types of layers alternate along the
crystallographic c-axis and are separated by Sr atoms. The site occupancies of
Mn, Cu and Zn were studied using Rietveld refinements of x-ray and neutron
powder diffraction data. The temperature dependences of rho suggest metallic
character for Sr2Mn2CuAs2O2 and semiconducting character for Sr2Mn3As2O2 and
Sr2Zn2MnAs2O2. Sr2Mn2CuAs2O2 is inferred to be a ferrimagnet with a Curie
temperature TC = 95(1) K. Remarkably, we find that the magnetic ground state
structure changes from a G-type antiferromagnetic structure in Sr2Mn3As2O2 to
an A-type ferrimagnetic structure in Sr2Mn2CuAs2O2 in which the Mn ions in each
layer are ferromagnetically aligned, but are antiferromagnetically aligned
between layers.Comment: 18 pages, 16 figures, 6 tables; submitted to Phys. Rev.
Comprehensive airborne characterization of aerosol from a major bovine source
We report an extensive airborne characterization of aerosol downwind of a massive bovine source in the San Joaquin Valley (California) on two flights during July 2007. The Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS) Twin Otter probed chemical composition, particle size distribution, mixing state, sub- and supersaturated water uptake behavior, light scattering properties, and the interrelationship between these parameters and meteorology. Total PM_(1.0) levels and concentrations of organics. nitrate. and ammonium were enhanced in the plume from the source as compared to the background aerosol. Organics dominated the plume aerosol mass (~56-64%), followed either by sulfate or nitrate. and then ammonium. Particulate amines were detected in the plume aerosol by a particle-into-liquid sampler (PILS) and via mass spectral inarkers in the Aerodvne C-ToF-AMS. Amines were found to be a significant atmospheric base even in the presence of arnmonia; particulate amine concentrations are estimated as at least 14-23% of that of ammonium in the plume. Enhanced sub- and supersaturated water uptake and reduced refractive indices were coincident with lower organic mass fractions, higher nitrate mass fractions, and the detection of amines. The likelihood of suppressed droplet growth owing to kinetic limitations from hydrophobic organic material is explored. After removing effects associated with size distribution and mixing state, the normalized activated fraction of cloud condensation nuclei (CCN) increased as a function of the subsaturated hygroscopic growth factor, with the highest activated fractions being consistent with relatively lower organic mass fractions and higher nitrate mass fractions. Subsaturated hygroscopic growth factors for the organic fraction of the aerosol are estimated based on employing the Zdanovskii-Stokes Robinson (ZSR) mixing rule. Representative values for a parameterization treating particle water uptake in both the sub- and supersaturated regimes are reported for incorporation into atmospheric models
Characterisation and airborne deployment of a new counterflow virtual impactor inlet
A new counterflow virtual impactor (CVI) inlet is introduced with details of its design, laboratory characterisation tests and deployment on an aircraft during the 2011 Eastern Pacific Emitted Aerosol Cloud Experiment (E-PEACE). The CVI inlet addresses three key issues in previous designs; in particular, the inlet operates with: (i) negligible organic contamination; (ii) a significant sample flow rate to downstream instruments (∼15 l min^(−1)) that reduces the need for dilution; and (iii) a high level of accessibility to the probe interior for cleaning. Wind tunnel experiments characterised the cut size of sampled droplets and the particle size-dependent transmission efficiency in various parts of the probe. For a range of counter-flow rates and air velocities, the measured cut size was between 8.7–13.1 μm. The mean percentage error between cut size measurements and predictions from aerodynamic drag theory is 1.7%. The CVI was deployed on the Center for Interdisciplinary Remotely Piloted Aircraft Studies (CIRPAS) Twin Otter for thirty flights during E-PEACE to study aerosol-cloud-radiation interactions off the central coast of California in July and August 2011. Results are reported to assess the performance of the inlet including comparisons of particle number concentration downstream of the CVI and cloud drop number concentration measured by two independent aircraft probes. Measurements downstream of the CVI are also examined from one representative case flight coordinated with shipboard-emitted smoke that was intercepted in cloud by the Twin Otter
Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds
A series of experiments has been conducted in the Caltech indoor smog chamber facility to investigate the water uptake properties of aerosol formed by oxidation of various organic precursors. Secondary organic aerosol (SOA) from simple and substituted cycloalkenes (C5-C8) is produced in dark ozonolysis experiments in a dry chamber (RH~5%). Biogenic SOA from monoterpenes, sesquiterpenes, and oxygenated terpenes is formed by photooxidation in a humid chamber (~50% RH). Using the hygroscopicity tandem differential mobility analyzer (HTDMA), we measure the diameter-based hygroscopic growth factor (GF) of the SOA as a function of time and relative humidity. All SOA studied is found to be slightly hygroscopic, with smaller water uptake than that of typical inorganic aerosol substances. The aerosol water uptake increases with time early in the experiments for the cycloalkene SOA, but decreases with time for the biogenic SOA. This behavior could indicate competing effects between the formation of more highly oxidized polar compounds (more hygroscopic), and formation of longer-chained oligomers (less hygroscopic). All SOA also exhibit a smooth water uptake with RH with no deliquescence or efflorescence. The water uptake curves are found to be fitted well with an empirical three-parameter functional form. The measured pure organic GF values at 85% RH are between 1.09–1.16 for SOA from ozonolysis of cycloalkenes, 1.01–1.04 for sesquiterpene photooxidation SOA, and 1.06–1.11 for the monoterpene and oxygenated terpene SOA. The GF of pure SOA (GForg) in experiments in which inorganic seed aerosol is used is determined by assuming volume-weighted water uptake (Zdanovskii-Stokes-Robinson or ''ZSR'' approach) and using the size-resolved organic mass fraction measured by the Aerodyne Aerosol Mass Spectrometer. Knowing the water content associated with the inorganic fraction yields GForg values. However, for each precursor, the GForg values computed from different HTDMA-classified diameters agree with each other to varying degrees. Lack of complete agreement may be a result of the non-idealities of the solutions that are not captured by the ZSR method. Comparing growth factors from different precursors, we find that GForg is inversely proportional to the precursor molecular weight and SOA yield, which is likely a result of the fact that higher-molecular weight precursors tend to produce larger and less hygroscopic oxidation products
Chemistry of layered d-metal pnictide oxides and their potential as candidates for new superconductors
Layered d-metal pnictide oxides are a unique class of compounds which
consists of characteristic d-metal pnictide layers and metal oxide layers. More
than 100 of these layered compounds, including the recently discovered Fe-based
superconducting pnictide oxides, can be classified into 9 structure types.
These structure types and the chemical and physical properties of the
characteristic d-metal pnictide layers and metal oxide layers of the layered
d-metal pnictide oxides are reviewed and discussed. Furthermore, possible
approaches to design new superconductors based on these layered d-metal
pnictide oxides are proposed.Comment: 29 pages including 6 tables and 2 figure
Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds
A series of experiments has been conducted in the Caltech indoor smog chamber facility to investigate the water uptake properties of aerosol formed by oxidation of various organic precursors. Secondary organic aerosol (SOA) from simple and substituted cycloalkenes (C<sub>5</sub>-C<sub>8</sub>) is produced in dark ozonolysis experiments in a dry chamber (<i>RH</i>~5%). Biogenic SOA from monoterpenes, sesquiterpenes, and oxygenated terpenes is formed by photooxidation in a humid chamber (~50% <i>RH</i>). Using the hygroscopicity tandem differential mobility analyzer (HTDMA), we measure the diameter-based hygroscopic growth factor (<i>GF</i>) of the SOA as a function of time and relative humidity. All SOA studied is found to be slightly hygroscopic, with smaller water uptake than that of typical inorganic aerosol substances. The aerosol water uptake increases with time early in the experiments for the cycloalkene SOA, but decreases with time for the sesquiterpene SOA. This behavior could indicate competing effects between the formation of more highly oxidized polar compounds (more hygroscopic), and formation of longer-chained oligomers (less hygroscopic). All SOA also exhibit a smooth water uptake with <i>RH</i> with no deliquescence or efflorescence. The water uptake curves are found to be fitted well with an empirical three-parameter functional form. The measured pure organic <i>GF</i> values at 85% <i>RH</i> are between 1.09–1.16 for SOA from ozonolysis of cycloalkenes, 1.01–1.04 for sesquiterpene photooxidation SOA, and 1.06–1.10 for the monoterpene and oxygenated terpene SOA. The <i>GF</i> of pure SOA (<i>GF</i><sub>org</sub>) in experiments in which inorganic seed aerosol is used is determined by assuming volume-weighted water uptake (Zdanovskii-Stokes-Robinson or 'ZSR' approach) and using the size-resolved organic mass fraction measured by the Aerodyne Aerosol Mass Spectrometer. Knowing the water content associated with the inorganic fraction yields <i>GF</i><sub>org</sub> values. However, for each precursor, the <i>GF</i><sub>org</sub> values computed from different HTDMA-classified diameters agree with each other to varying degrees. Comparing growth factors from different precursors, we find that <i>GF</i><sub>org</sub> is inversely proportional to the precursor molecular weight and SOA yield, which is likely a result of the fact that higher-molecular weight precursors tend to produce larger and less hygroscopic oxidation products
Possible high temperature superconductivity in Ti-doped A-Sc-Fe-As-O (A= Ca, Sr) system
We report a systematic study on the effect of partial substitution of
Sc by Ti in SrScFeAsO, CaScFeAsO and
SrScFeAsO on their electrical properties. High
level of doping results in an increased carrier concentration and leads to the
appearance of superconductivity with the onset of T up to 45 K.Comment: 8 pages, 4 figures, 2 new figure
Frequency of exercise-induced ST-T-segment deviations and cardiac arrhythmias in recreational endurance athletes during a marathon race: results of the prospective observational Berlin Beat of Running study
OBJECTIVES: While regular physical exercise has many health benefits, strenuous physical exercise may have a negative impact on cardiac function. The 'Berlin Beat of Running' study focused on feasibility and diagnostic value of continuous ECG monitoring in recreational endurance athletes during a marathon race. We hypothesised that cardiac arrhythmias and especially atrial fibrillation are frequently found in a cohort of recreational endurance athletes. The main secondary hypothesis was that pathological laboratory findings in these athletes are (in part) associated with cardiac arrhythmias. DESIGN: Prospective observational cohort study including healthy volunteers. SETTING AND PARTICIPANTS: One hundred and nine experienced marathon runners wore a portable ECG recorder during a marathon race in Berlin, Germany. Athletes underwent blood tests 2-3 days prior, directly after and 1-2 days after the race. RESULTS: Overall, 108 athletes (median 48 years (IQR 45-53), 24% women) completed the marathon in 249±43 min. Blinded ECG analysis revealed abnormal findings during the marathon in 18 (16.8%) athletes. Ten (9.3%) athletes had at least one episode of non-sustained ventricular tachycardia, one of whom had atrial fibrillation; eight (7.5%) individuals showed transient ST-T-segment deviations. Abnormal ECG findings were associated with advanced age (OR 1.11 per year, 95% CI 1.01 to 1.23), while sex and cardiovascular risk profile had no impact. Directly after the race, high-sensitive troponin T was elevated in 18 (16.7%) athletes and associated with ST-T-segment deviation (OR 9.9, 95% CI 1.9 to 51.5), while age, sex and cardiovascular risk profile had no impact. CONCLUSIONS: ECG monitoring during a marathon is feasible. Abnormal ECG findings were present in every sixth athlete. Exercise-induced transient ST-T-segment deviations were associated with elevated high-sensitive troponin T (hsTnT) values. TRIAL REGISTRATION: ClinicalTrials.gov NCT01428778; Results
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Chemical Evolution of a Power-Plant Plume
Measurements made from the DOE G-1 aircraft were used to calculate the rate and efficiency of O{sub 3} production downwind of an isolated, coal-fired power plant. The plume was transected 12 times at distances ranging to 65 km from its source (corresponding to an age of {approx}4 h assuming constant wind velocity). For NO{sub x}, a loss rate of 0.5 h{sup -1} was calculated. If reaction with OH was the sole loss mechanism, then an [OH] = 1.6 x 10{sup 7}molec/cm{sup 3} is inferred, which is {approx}2-3X values calculated using a box model constrained by observations. Possible explanations for this discrepancy are discussed. O{sub 3} production per molecule of NO{sub x} approached 6-8 after the plume had aged >3h. Peak O{sub 3} concentrations were 15 ppbv above background. Dilution appears to limit the peak O{sub 3} concentration despite the high production efficiency. Hydrocarbon samples indicate high levels of VOC reactivity ({approx}8 s{sup -1}) in the plume. The number concentration of accumulation mode particles increases significantly with plume age indicating a rapid formation of aerosol mass
On the link between ocean biota emissions, aerosol, and maritime clouds: Airborne, ground, and satellite measurements off the coast of California
Surface, airborne, and satellite measurements over the eastern Pacific Ocean off the coast of California during the period between 2005 and 2007 are used to explore the relationship between ocean chlorophyll a, aerosol, and marine clouds. Periods of enhanced chlorophyll a and wind speed are coincident with increases in particulate diethylamine and methanesulfonate concentrations. The measurements indicate that amines are a source of secondary organic aerosol in the marine atmosphere. Subsaturated aerosol hygroscopic growth measurements indicate that the organic component during periods of high chlorophyll a and wind speed exhibit considerable water uptake ability. Increased average cloud condensation nucleus (CCN) activity during periods of increased chlorophyll a levels likely results from both size distribution and aerosol composition changes. The available data over the period of measurements indicate that the cloud microphysical response, as represented by either cloud droplet number concentration or cloud droplet effective radius, is likely influenced by a combination of atmospheric dynamics and aerosol perturbations during periods of high chlorophyll a concentrations
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