Glaube und Wissenschaft beim Frankfurter Hegel

Wissenschaft und Glauben sind für den frühen Hegel\ud keine Gegensätze. Dies zeige ich in drei Schritten: Ich\ud stelle den ‚vernünftigen Glauben" des Frankfurter Hegel\ud dar, zeige den Bezug von Hegels Erkenntnisbegriff zu\ud Kants ‚ästhetischer Idee" und rekonstruiere Hegels Frankfurter\ud Urteilstheorie. Sie beruht auf der ursprünglichen\ud Beziehung von Glaube, Kunst und Denken

The Effect of Binder Loading on the Pore Size of 3D Printed PMMA

Binder jetting is known to produce porous objects by depositing the binder selectively layer by layer on a powder bed. In this study, the pore size of printed parts and the correlating mechanical properties are investigated on a commercially available PMMA powder binder system. Pore sizes are measured via capillary flow porometry and mechanical properties via tensile tests. Porometry indicates that the pore size stays at a constant level of 22 µm at 5 to 10 wt% binder loading before decreasing to 6 µm at loadings of 30 wt% or higher. The results were compared with the mechanical testing and related to the agglomerate strength model of Rumpf. The highlights of the article are the application of a binder jetted part as a filter and the identification of a close relationship between porosity and mechanical strength, similar to phenomena in agglomeration science

The Challenge of Die Filling in Rotary Presses: A Systematic Study of Material Properties and Process Parameters

For the efficient and safe production of pharmaceutical tablets, a deep process understanding is of high importance. An essential process step during tableting is the die filling, as it is responsible for a consistent tablet weight and drug content. Furthermore, it affects the results of subsequent process steps, compaction and ejection, and thus critical quality attributes. This study focuses on understanding the influences of process parameters and material properties on die filling on a rotary tablet press. By the systematic variation in process parameters as the turret and paddle speeds as well as the fill and dosing depths, five formulations with differing properties are processed. Analysis of the normalized tablet weight, called filling yield, revealed different limitation mechanisms of the filling process, i.e., incomplete filled dies for certain parameter settings. Kinetic limitations occur due to a short residence time under the feed frame (filling time) caused by high turret speeds, which additionally induce high tablet weight variation coefficients. Characteristic maximum turret speeds at certain paddle speeds can be found to still achieve complete filling. At low turret speeds, densification of the powder inside the dies takes place, induced by two mechanisms: either high paddle speeds or high overfill ratios, or a combination of both. The challenge to fill the dies completely as well as avoid densification is dependent on material properties as the flowability. The mass discharge rate from an orifice was found to be in a linear correlation to the filling results of different formulations below complete filling

Modeling of Carbon Black Fragmentation During High‐Intensity Dry Mixing Using the Population Balance Equation and the Discrete Element Method

A complex interaction between the process design and the properties of carbon black (CB) during dry mixing of cathode material influences the microstructure and thus the performance of the Li-ion battery. The description of these interactions by means of a coupling of the mixing process simulation and the fragmentation of CB is the focus of this work. The discrete element method provides information about the frequency and intensity of the stress. The change of the CB size distribution is done by the population balance equation. The material strength as well as the fracture behavior are represented with simple models. The calibration of the model parameters is performed using the Nelder–Mead algorithm. The calibrated models provide good agreement with the measurements of the size distributions from experimental investigations. Transfer of the calibrated parameters to other process settings is possible and provides good agreement in some cases. Recalibration of the fracture behavior improves the accuracy of the model so that it can be used as a predictive tool

Artificial Intelligence in Process Engineering

In recent years, the field of Artificial Intelligence (AI) is experiencing a boom, caused by recent breakthroughs in computing power, AI techniques, and software architectures. Among the many fields being impacted by this paradigm shift, process engineering has experienced the benefits caused by AI. However, the published methods and applications in process engineering are diverse, and there is still much unexploited potential. Herein, the goal of providing a systematic overview of the current state of AI and its applications in process engineering is discussed. Current applications are described and classified according to a broader systematic. Current techniques, types of AI as well as pre- and postprocessing will be examined similarly and assigned to the previously discussed applications. Given the importance of mechanistic models in process engineering as opposed to the pure black box nature of most of AI, reverse engineering strategies as well as hybrid modeling will be highlighted. Furthermore, a holistic strategy will be formulated for the application of the current state of AI in process engineering

Impact of Particle and Equipment Properties on Residence Time Distribution of Pharmaceutical Excipients in Rotary Tablet Presses

Paddle feeders are devices commonly used in rotary tablet presses to facilitate constant and efficient die filling. Adversely, the shear stress applied by the rotating paddles is known to affect the bulk properties of the processed powder dependent on the residence time. This study focuses on the residence time distribution (RTD) of two commonly applied excipients (microcrystalline cellulose, MCC; dicalcium phosphate, DCP), which exhibit different flow properties inside rotary tablet presses. To realistically depict the powder flow inside rotary tablet presses, custom-made tracer powder was developed. The applied method was proven to be appropriate as the tracer and bulk powder showed comparable properties. The RTDs of both materials were examined in two differently scaled rotary tablet presses and the influence of process parameters was determined. To analyze RTDs independent of the mass flow, the normalized variance was used to quantify intermixing. Substantial differences between both materials and tablet presses were found. Broader RTDs were measured for the poorer flowing MCC as well as for the production scale press. The obtained results can be used to improve the general understanding of powder flow inside rotary tablet presses and amplify scale-up and continuous production process development

Grinding Media Motion and Collisions in Different Zones of Stirred Media Mills

Product fineness during grinding in stirred media mills is mainly influenced by the specific energy input, the stress energy transferred by the colliding grinding media and the stress frequency. The stress energy from grinding media collisions is heterogeneously distributed in stirred media mills. Herein, in order to characterize the stress energy distribution and the local grinding media collision frequencies, the grinding media motion was calculated using discrete element method (DEM) simulations coupled with computational fluid dynamics (CFD). The local grinding media concentration, velocity profiles, grinding media collisions and stress energies were compared for varied total grinding media fillings and stirrer speeds. It was confirmed that the normalized grinding media velocity profile can be used to divide the grinding chamber into four types of zones that allow the modeling of the stress energy distribution. However, the collision frequency showed very different distributions for varied stirrer velocities and grinding media fillings

Challenges in Ecofriendly Battery Recycling and Closed Material Cycles: A Perspective on Future Lithium Battery Generations

The global use of lithium-ion batteries of all types has been increasing at a rapid pace for many years. In order to achieve the goal of an economical and sustainable battery industry, the recycling and recirculation of materials is a central element on this path. As the achievement of high 95% recovery rates demanded by the European Union for some metals from today’s lithium ion batteries is already very challenging, the question arises of how the process chains and safety of battery recycling as well as the achievement of closed material cycles are affected by the new lithium battery generations, which are supposed to enter the market in the next 5 to 10 years. Based on a survey of the potential development of battery technology in the next years, where a diversification between high-performance and cost-efficient batteries is expected, and today’s knowledge on recycling, the challenges and chances of the new battery generations regarding the development of recycling processes, hazards in battery dismantling and recycling, as well as establishing a circular economy are discussed. It becomes clear that the diversification and new developments demand a proper separation of battery types before recycling, for example by a transnational network of dismantling and sorting locations, and flexible and high sophisticated recycling processes with case-wise higher safety standards than today. Moreover, for the low-cost batteries, recycling of the batteries becomes economically unattractive, so legal stipulations become important. However, in general, it must be still secured that closing the material cycle for all battery types with suitable processes is achieved to secure the supply of raw materials and also to further advance new developments

China’s One-Belt-One-Road (OBOR) Policy Initiative: The Internationalization of the Renminbi

The last decade having witnessed China’s meteoric resurgence has created a paradigm shift that has resulted into not only a massive structural adjustment, but also caused a shift in attention of international relations discourse towards itself. It is partly in respect of the rise and the tailoring of the One-Belt-One-Road policy that this academic research is conducted. Using much of secondary data, the thrust of this study is to examine the impact of the policy and its potential, particularly, in relations to its contributory prowess to the monetary system of china and also, its immense spread effect in contributing to the internationalization of the renminbi. Using the Strength, Weaknesses, Opportunities and Threats (SWOT) model, holding the strengths and opportunities which are internal on one side and holding the weaknesses and threats which are extraneous on the other side, the model conclusively asserts that, capitalizing on the strengths and opportunities will help Beijing override the threats and the weaknesses to turbo-charge the Chinese Renminbi currency into internationalization heights whiles same time helping to rake in social, political and economic benefits including the ability to create the strategic position not only in Eurasia, but in other part of the world. Keywords: One-Belt-One-Road (OBOR), Belt and road initiative (BRI), Renminbi (RMB), Internationalization, Strengths, Weaknesses, Opportunities, Threats (SWOT)