764 research outputs found
C and S induces changes in the electronic and geometric structure of Pd(533) and Pd(320)
We have performed ab initio electronic structure calculations of C and S
adsorption on two vicinal surfaces of Pd with different terrace geometry and
width. We find both adsorbates to induce a significant perturbation of the
surface electronic and geometric structure of Pd(533) and Pd(320). In
particular C adsorbed at the bridge site at the edge of a Pd chain in Pd(320)
is found to penetrate the surface to form a sub-surface structure. The
adsorption energies show almost linear dependence on the number of
adsorbate-metal bonds, and lie in the ranges of 5.31eV to 8.58eV for C and
2.89eV to 5.40eV for S. A strong hybridization between adsorbate and surface
electronic states causes a large splitting of the bands leading to a drastic
decrease in the local densities of electronic states at the Fermi-level for Pd
surface atoms neighboring the adsorbate which may poison catalytic activity of
the surface. Comparison of the results for Pd(533) with those obtained earlier
for Pd(211) suggests the local character of the impact of the adsorbate on the
geometric and electronic structures of Pd surfaces.Comment: 14 pages 9 figs, Accepted J. Phys: Conden
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Novel concept of multi-channel fiber optic surface plasmon resonance sensor
A novel multi-channel fiber optic surface plasmon resonance (SPR) sensor is reported. The sensing structure consists of a single-mode optical fiber, covered with a thin gold layer, which supports a surface plasmon (SP), and a Bragg grating. The Bragg grating induces coupling between the forward-propagating fundamental core mode and the back-propagating SP-cladding mode. As the SP-cladding modes are highly sensitive to changes in the refractive index of the surrounding medium, the changes can be accurately measured by spectroscopy of these hybrid modes. Multichannel capability is achieved by employing a sequence of Bragg gratings of different periods and their reading via the wavelength division multiplexing. Theoretical analysis and optimization based on the coupled-mode theory (CMT) is carried out and performance characteristics of the sensor are determined
The effect of Coulomb interaction at ferromagnetic-paramagnetic metallic perovskite junctions
We study the effect of Coulomb interactions in transition metal oxides
junctions. In this paper we analyze charge transfer at the interface of a three
layer ferromagnetic-paramagnetic-ferromagnetic metallic oxide system. We choose
a charge model considering a few atomic planes within each layer and obtain
results for the magnetic coupling between the ferromagnetic layers. For large
number of planes in the paramagnetic spacer we find that the coupling
oscillates with the same period as in RKKY but the amplitude is sensitive to
the Coulomb energy. At small spacer thickness however, large differences may
appear as function of : the number of electrons per atom in the ferromagnetics
and paramagnetics materials, the dielectric constant at each component, and the
charge defects at the interface plane emphasizing the effects of charge
transfer.Comment: tex file and 7 figure
Cancellation of probe effects in measurements of spin polarized momentum density by electron positron annihilation
Measurements of the two dimensional angular correlation of the
electron-positron annihilation radiation have been done in the past to detect
the momentum spin density and the Fermi surface. We point out that the momentum
spin density and the Fermi Surface of ferromagnetic metals can be revealed
within great detail owing to the large cancellation of the electron-positron
matrix elements which in paramagnetic multiatomic systems plague the
interpretation of the experiments. We prove our conjecture by calculating the
momentum spin density and the Fermi surface of the half metal CrO2, who has
received large attention due to its possible applications as spintronics
material
Topological insulators in the quaternary chalcogenide compounds and ternary famatinite compounds
We present first-principles calculations to predict several three dimensional
(3D) topological insulators in quaternary chalcogenide compounds which are made
of I-II-IV-VI compositions and in ternary compositions of
I-V-VI famatinite compounds. Among the large members of these two
families, we give examples of naturally occurring compounds which are mainly
Cu-based chalcogenides. We show that these materials are candidates of 3D
topological insulators or can be tuned to obtain topological phase transition
by manipulating the atomic number of the other cation and anion elements. A
band inversion can occur at a single point with considerably large
inversion strength, in addition to the opening of a bulk band gap throughout
the Brillouin zone. We also demonstrate that both of these families are related
to each other by cross-substitutions of cations in the underlying tetragonal
structure and that one can suitably tune their topological properties in a
desired manner.Comment: 7 pages, 4 figure
European consensus on grading bone marrow fibrosis and assessment of cellularity
Quantification of characteristic bone marrow biopsy features includes basic parameters such as cellularity and fiber content. These are important to assess the dynamics of disease processes with a significant impact on risk stratification, survival patterns and, especially, therapy-related changes. A panel of experienced European pathologists and a foreign expert evaluated, at a multi-headed microscope, a large number of representative slides of trephine biopsies from patients with myelofibrosis in an attempt to reach a consensus on how to grade cellularity and fibrosis. This included a critical evaluation of previously described scoring systems. During the microscopic analysis and subsequent discussion and voting, the importance of age-dependent decrease in cellularity was recognized. Grading of myelofibrosis was simplified by using four easily reproducible categories including differentiation between reticulin and collagen. A consensus was reached that the density of fibers must be assessed in relation to the hematopoietic tissue. This feature is especially important in order to avoid a false impression of a reduced fiber content in fatty and/or edematous bone marrow samples after treatment. The consensus for measuring myelofibrosis by clear and reproducible guidelines achieved by our group should allow for precise grading during the disease process and after therapy
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