Mechanical properties of plasma sprayed layers of NiAl10 and NiAl40 on AZ91 alloy

In this work, plasma coatings of NiAl10 and NiAl40 on magnesium alloy AZ91 substrate were prepared by the hybrid plasma spraying system WSP®-H 500. The both plasma sprayed coatings of NiAl10 and NiAl40 have metallurgical bond. The thicknesses of microstructures in the cross-section of NiAl10 and NiAl40 plasma sprayed coatings prepared by 9 passes were 374 and 440 μm respectively. Adhesion test of plasma sprayed layers was performed using a modified ASTM C 633 standard. The tensile adhesion strength values are 24.7 MPa for NiAl10 coatings and 12.3 MPa for NiAl40 coatings. Abrasion resistance according to Slurry Abrasion Response (SAR) test of NiAl40 layers had similar values (0.12 g/cm2)in a comparison with the uncoated AZ91 (0.126 g/cm2). Layers NiAl10 had greater weight losses (0.175 g/cm2) than uncoated AZ91. Microhardness of plasma coating of NiAl40 is several times greater than microhardnesses of plasma coating of NiAl10 and uncoated substrate AZ9

Corrosion behavior of plasma coatings CuAl10 and CuAl50 on magnesium alloy AZ 91

The most common magnesium alloy AZ 91 is widely used as a structural material, but its use is limited at higher temperatures and high humidity. Plasma spraying is a technology that allows to prepare protective metallic and non-metallic coatings on a wide variety of substrates including magnesium and its alloys. In this study, CuAl10 and CuAl50 were plasma sprayed on magnesium alloy AZ 91 with the aim to study corrosion resistance of the plasma sprayed coatings. The corrosion resistance of layers was evaluated by the method of electrochemical potentiodynamic measurement as well as long-term corrosion tests in a condensation chamber with 0.5 mol\nNaCl at the temperature of 35 °C for 1344 hours. Layers with 1, 2, 5 passes and passes of CuAl10 with the thickness ranging from 75 to 716 mm and CuAl50 with the thickness ranging from 64 to 566 mm were prepared. The increased corrosion velocity was observed in the case of thin layers of 2 and 5 passes due to the development of a galvanic corrosion couple. The CuAl10 layer prepared with ten passes has an outstanding corrosion resistance

Mechanical and chemical properties of plasma sprayed bronze CuAl10 coating on magnesium and magnesium alloy AZ91

The most common magnesium alloy AZ91 is widely used as a structural material, but its use is limited at higher temperatures and high humidity. Plasma spraying is a technology that allows to prepare protective metallic and nonmetallic coatings on a wide variety of substrates including magnesium and its alloys. In this study, CuAl10 was plasma sprayed on magnesium and magnesium alloy AZ91 with the aim to study corrosion resistance of the magnesium substrates. The work focuses on optimization of the plasma spraying process, on chemical composition of the coatings, on interface between the coating and substrate, as well as on adhesive strength of the coatings. The coating were deposited after two passes of the spraying torch resulting in thickness of 150 micro m on magnesium substrate and 110 micro m on AZ91 substrate. Chemical microanalysis showed that deposition of CuAl10 alloy on magnesium results in formation of an intermetallic layer at the interface. The layer provides

The Structure and Mechanical Properties of High-Strength Bulk Ultrafine-Grained Cobalt Prepared Using High-Energy Ball Milling in Combination with Spark Plasma Sintering

In this study, bulk ultrafine-grained and micro-crystalline cobalt was prepared using a combination of high-energy ball milling and subsequent spark plasma sintering. The average grain sizes of the ultrafine-grained and micro-crystalline materials were 200 nm and 1 μm, respectively. Mechanical properties such as the compressive yield strength, the ultimate compressive strength, the maximum compressive deformation and the Vickers hardness were studied and compared with those of a coarse-grained as-cast cobalt reference sample. The bulk ultrafine-grained sample showed an ultra-high compressive yield strength that was greater than 1 GPa, which is discussed with respect to the preparation technique and a structural investigation

High-Strength Ultra-Fine-Grained Hypereutectic Al-Si-Fe-X (X = Cr, Mn) Alloys Prepared by Short-Term Mechanical Alloying and Spark Plasma Sintering

In this work, Al-20Si-10Fe-6Cr and Al-20Si-10Fe-6Mn (wt %) alloys were prepared by a combination of short-term mechanical alloying and spark plasma sintering. The microstructure was composed of homogeneously dispersed intermetallic particles forming composite-like structures. X-ray diffraction analysis and TEM + EDS analysis determined that the α-Al along with α-Al15(Fe,Cr)3Si2 or α-Al15(Fe,Mn)3Si2 phases were present, with dimensions below 130 nm. The highest hardness of 380 ± 7 HV5 was observed for the Al-20Si-10Fe-6Mn alloy, exceeding the hardness of the reference as-cast Al-12Si-1Cu-1 Mg-1Ni alloy (121 ± 2 HV5) by nearly a factor of three. Both of the prepared alloys showed exceptional thermal stability with the hardness remaining almost the same even after 100 h of annealing at 400 °C. Additionally, the compressive strengths of the Al-20Si-10Fe-6Cr and Al-20Si-10Fe-6Mn alloys reached 869 MPa and 887 MPa, respectively, and had virtually the same values of 870 MPa and 865 MPa, respectively, even after 100 h of annealing. More importantly, the alloys showed an increase in ductility at 400 °C, reaching several tens of percent. Thus, both of the investigated alloys showed better mechanical properties, including superior hardness, compressive strength and thermal stability, as compared to the reference Al-10Si-1Cu-1Mg-1Ni alloy, which softened remarkably, reducing its hardness by almost 50% to 63 ± 8 HV5