229 research outputs found
Perfluoroether triazine elastomers
The synthesis of high performance elastomers with the high thermal stability and chemical, inertness of perfluoroalkylene triazine and a low glass transition temperature is discussed. Perfluorether triazine elastomers were proposed as potentially superior. It is concluded that the difficulties experienced in fluoroalkytriazine elastomer synthesis can be overcome by a four-step reaction process involving chain extension, triazine ring closure, crosslinking, and elastomer curing. Molecular weight can be controlled in the initial polymer formation so that elastomer modulus can be determined. The final product elastomers exhibit a useful elastomeric range of approximately 45 to 325 C with an oxidative stability superior to other broad range elastomers
Process for the preparation of fluorine containing crosslinked elastomeric polytriazine and product so produced
Crosslinking elastomeric polytriazines are prepared by a 4 step procedure which consists of (1) forming a poly(imidoylamidine) by the reaction, under reflux conditions, of anhydrous ammonia with certain perfluorinated alkyl or alkylether dinitriles; (2) forming a linear polytriazine by cyclizing the imidoylamidine linkages by reaction with certain perfluorinated alkyl or alkylether acid anhydrides or halides; (3) extending the linear polytriazine chain by further refluxing in anhydrous ammonia; and (4) heating to cyclize the new imidoylamidine and thereby crosslink the polymer
Perfluroether triazine elastomers
In order to obtain high performance elastomers with the high thermal stability and chemical inertness of perfluoroalkylene triazine and a low glass transition temperature, perfluoroether triazine elastomers were synthesized. The procedure for elastomer synthesis is described as well as general experimental methods. Results are presented and discussed. The screening of catalysts for the dehydration of perfluoroether diamide is also considered
Impact of bank stabilization structures on upstream and downstream bank mobilization at Cedar River, Nebraska
Streambed Flux Measurement Informed by Distributed Temperature Sensing Leads to a Significantly Different Characterization of Groundwater Discharge
Groundwater discharge though streambeds is often focused toward discrete zones, indicating that preliminary reconnaissance may be useful for capturing the full spectrum of groundwater discharge rates using point-scale quantitative methods. However, many direct-contact reconnaissance techniques can be time-consuming, and remote sensing (e.g., thermal infrared) typically does not penetrate the water column to locate submerged seepages. In this study, we tested whether dozens of groundwater discharge measurements made at “uninformed” (i.e., selected without knowledge on high-resolution temperature variations at the streambed) point locations along a reach would yield significantly dierent Darcy-based groundwater discharge rates when compared with “informed” measurements, focused at streambed thermal anomalies that were identified a priori using fiber-optic distributed temperature sensing (FO-DTS). A non-parametric U-test showed a significant difference between median discharge rates for uninformed (0.05 m day 1; n = 30) and informed (0.17 m day 1; n = 20) measurement locations. Mean values followed a similar pattern (0.12 versus 0.27 m day 1), and frequency distributions for uninformed and informed measurements were also significantly different based on a Kolmogorov–Smirnov test. Results suggest that even using a quick “snapshot-in-time” field analysis of FO-DTS data can be useful in streambeds with groundwater discharge rate
An Overview of Fluctuation and Correlation Results in Relativistic Heavy Ion Collisions
A great deal of recent data on event-by-event fluctuation and correlation
measurements has been released by several experiments at the SPS and RHIC.
Recent results on charge fluctuations, balance functions in pseudorapidity, and
average transverse momentum fluctuations will be reviewed. The results will be
compared to various model predictions after examining contributions to each
observable from known physics processes.Comment: 8 pages, 3 figures. Contribution to the Proceedings of the 17th
International Conference on Ultra Relativistic Nucleus-Nucleus Collisions
(Quark Matter 2004), Oakland, California, 11-17 Jan 2004. Submitted to
J.Phys.
Thermal fluctuations in the interacting pion gas
We derive the two-particle fluctuation correlator in a thermal gas of
pi-mesons to the lowest order in an interaction due to a resonance exchange. A
diagrammatic technique is used. We discuss how this result can be applied to
event-by-event fluctuations in heavy-ion collisions, in particular, to search
for the critical point of QCD. As a practical example, we determine the shape
of the rapidity correlator.Comment: 12 pages, 4 figures, RevTe
Observation of an Exotic S = -2, Q = -2 Baryon Resonance in Proton-Proton Collisions at the CERN SPS
Results of resonance searches in the Xi- pi-, Xi- pi+, antiXi+ pi- and
antiXi+ pi+ invariant mass spectra in proton-proton collisions at sqrt{s}=17.2
GeV are presented. Evidence is shown for the existence of a narrow Xi- pi-
baryon resonance with mass of 1.862+/-0.002 GeV/c^2 and width below the
detector resolution of about 0.018 GeV/c^2. The significance is estimated to be
4.0 sigma. This state is a candidate for the hypothetical exotic Xi_(3/2)^--
baryon with S = -2, I = 3/2 and a quark content of (d s d s ubar). At the same
mass a peak is observed in the Xi- pi+ spectrum which is a candidate for the
Xi_(3/2)^0 member of this isospin quartet with a quark content of (d s u s
dbar). The corresponding antibaryon spectra also show enhancements at the same
invariant mass.Comment: 5 pages, 3 figure
Rapidity and energy dependence of the electric charge correlations in A+A collisions at the SPS energies
Results from electric charge correlations studied with the Balance Function
method in A+A collisions from 20\emph{A} to 158\emph{A} GeV are presented in
two different rapidity intervals: In the mid-rapidity region we observe a
decrease of the width of the Balance Function distribution with increasing
centrality of the collision, whereas this effect vanishes in the forward
rapidity region.
Results from the energy dependence study in central Pb+Pb collisions show
that the narrowing of the Balance Function expressed by the normalised width
parameter \textit{W} increases with energy towards the highest SPS and RHIC
energies.
Finally we compare our experimental data points with predictions of several
models. The hadronic string models UrQMD and HIJING do not reproduce the
observed narrowing of the Balance Function. However, AMPT which contains a
quark-parton transport phase before hadronization can reproduce the narrowing
of the BF's width with centrality. This confirms the proposed sensitivity of
the Balance Function analysis to the time of hadronization.Comment: Submitted in Phys. Rev.
Transverse Momentum Fluctuations in Nuclear Collisions at 158 AGeV
Results are presented on event-by-event fluctuations in transverse momentum
of charged particles, produced at forward rapidities in p+p, C+C, Si+Si and
Pb+Pb collisions at 158 AGeV. Three different characteristics are discussed:
the average transverse momentum of the event, the Phi_pT fluctuation measure
and two-particle transverse momentum correlations. In the kinematic region
explored, the dynamical fluctuations are found to be small. However, a
significant system size dependence of Phi_pT is observed, with the largest
value measured in peripheral Pb+Pb interactions. The data are compared with
predictions of several models.Comment: will be submitted to Phys. Rev.
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