Innovative Selective Laser Sintering Rapid Manufacturing using Nanotechnology

The objective of this research is to develop an improved nylon 11 (polyamide 11) polymer with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into nylon 11 via twin screw extrusion to provide improved material properties of the polymer blends. Atofina (now known as Arkema) RILSAN® nylon 11 injection molding polymer pellets was used with three types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, nanosilica, and carbon nanofibers (CNF) to create nylon 11 nanocomposites. Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) were used to determine the degree of dispersion. Fifteen nylon 11 nanocomposites and control nylon 11 were fabricated by injection molding. Flammability properties (using a cone calorimeter with a radiant flux of 50 kW/m2 ) and mechanical properties such as tensile strength and modulus, flexural modulus, elongation at break were determined for the nylon 11 nanocomposites and compared with the baseline nylon 11. Based on flammability and mechanical material performance, five polymers including four nylon 11 nanocomposites and a control nylon 11 were cryogenically ground into fine powders for SLS RM. SLS specimens were fabricated for flammability, mechanical, and thermal properties characterization. Nylon 11-CNF nanocomposites exhibited the best overall properties for this study.Mechanical Engineerin

OH (1720 MHz) Masers: A Multiwavelength Study of the Interaction between the W51C Supernova Remnant and the W51B Star Forming Region

We present a comprehensive view of the W51B HII region complex and the W51C supernova remnant (SNR) using new radio observations from the VLA, VLBA, MERLIN, JCMT, and CSO along with archival data from Spitzer, ROSAT, ASCA, and Chandra. Our VLA data include the first 400 cm (74 MHz) continuum image of W51 at high resolution (88 arcsec). The 400 cm image shows non-thermal emission surrounding the G49.2-0.3 HII region, and a compact source of non-thermal emission (W51B_NT) coincident with the previously-identified OH (1720 MHz) maser spots, non-thermal 21 and 90 cm emission, and a hard X-ray source. W51B_NT falls within the region of high likelihood for the position of TeV gamma-ray emission. Using the VLBA three OH (1720 MHz) maser spots are detected in the vicinity of W51B_NT with sizes of 60 to 300 AU and Zeeman effect magnetic field strengths of 1.5 to 2.2 mG. The multiwavelength data demonstrate that the northern end of the W51B HII region complex has been partly enveloped by the advancing W51C SNR and this interaction explains the presence of W51B_NT and the OH masers. This interaction also appears in the thermal molecular gas which partially encircles W51B_NT and exhibits narrow pre-shock (DeltaV 5 km/s) and broad post-shock (DeltaV 20 km/s) velocity components. RADEX radiative transfer modeling of these two components yield physical conditions consistent with the passage of a non-dissociative C-type shock. Confirmation of the W51B/W51C interaction provides additional evidence in favor of this region being one of the best candidates for hadronic particle acceleration known thus far.Comment: Accepted to Ap

Polyamide 11-Carbon Nanotubes Nanocomposites: Preliminary Investigation

The objective of this research is to develop an improved polyamide 11 (PA11) polymer with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing. In the present study, a nanophase was introduced into polyamide 11 via twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used with 1, 3, 5, and 7 wt% loadings of Arkema’s GraphistrengthTM multi-wall carbon nanotubes (MWNTs) to create a family of PA11-MWNT nanocomposites. Transmission electron microscopy and scanning electron microscopy were used to determine the degree and uniformity of dispersion. Injection molded test specimens were fabricated for physical, thermal, mechanical properties, and flammability measurements. Thermal stability of these polyamide 11-MWNT nanocomposites was examined by TGA. Mechanical properties such as ultimate tensile strength, rupture tensile strength, and elongation at rupture were measured. Flammability properties were also obtained using the UL 94 test method. All these different methods and subsequent polymer characteristics are discussed in this paper.Mechanical Engineerin

Adiabatic Domain Wall Motion and Landau-Lifshitz Damping

Recent theory and measurements of the velocity of current-driven domain walls in magnetic nanowires have re-opened the unresolved question of whether Landau-Lifshitz damping or Gilbert damping provides the more natural description of dissipative magnetization dynamics. In this paper, we argue that (as in the past) experiment cannot distinguish the two, but that Landau-Lifshitz damping nevertheless provides the most physically sensible interpretation of the equation of motion. From this perspective, (i) adiabatic spin-transfer torque dominates the dynamics with small corrections from non-adiabatic effects; (ii) the damping always decreases the magnetic free energy, and (iii) microscopic calculations of damping become consistent with general statistical and thermodynamic considerations

Mid-infrared Identification of 6 cm Radio Source Counterparts in the Extended Groth Strip

A new 6-cm survey of almost 0.6 square degrees to a limit of 0.55-mJy/beam (10-sigma) finds 37 isolated radio sources and 7 radio source pairs (not necessarily physical companions). IRAC counterparts are identified for at least 92% of the radio sources within the area of deep IRAC coverage, which includes 31 isolated sources and 6 pairs. This contrasts with an identification rate of <74% to R<23.95 in visible light. Eight of the IRAC galaxies have power law spectral energy distributions, implying that the mid-infrared emission comes from a powerful AGN. The remaining 26 IRAC galaxies show stellar emission in the mid-infrared, probably in most of these galaxies because the stellar emission is bright enough to outshine an underlying AGN. The infrared colors suggest that the majority of these galaxies are bulge-dominated and have redshifts between approximately 0.5 and 1.0. Visible spectra from the DEEP2 redshift survey, available for 11 galaxies, are consistent with this suggestion. The IRAC galaxies fall into two distinct groups in a color-magnitude diagram, one group (the "stripe") includes all the AGN. The other group (the "blue clump") has blue 3.6 to 8 micron colors and a small range of 8 micron magnitudes. This separation should be useful in classifying galaxies found in other radio surveys.Comment: Accepted by A

Discovery of a Quadruple Lens in CANDELS with a Record Lens Redshift z=1.53

Using spectroscopy from the Large Binocular Telescope and imaging from the Hubble Space Telescope we discovered the first strong galaxy lens at z(lens)>1. The lens has a secure photometric redshift of z=1.53+/-0.09 and the source is spectroscopically confirmed at z=3.417. The Einstein radius (0.35"; 3.0 kpc) encloses 7.6 x 10^10 Msol, with an upper limit on the dark matter fraction of 60%. The highly magnified (40x) source galaxy has a very small stellar mass (~10^8 Msol) and shows an extremely strong [OIII]_5007A emission line (EW_0 ~ 1000A) bolstering the evidence that intense starbursts among very low-mass galaxies are common at high redshift.Comment: accepted for publication in ApJ Letter

Localization-delocalization transition of a reaction-diffusion front near a semipermeable wall

The A+B --> C reaction-diffusion process is studied in a system where the reagents are separated by a semipermeable wall. We use reaction-diffusion equations to describe the process and to derive a scaling description for the long-time behavior of the reaction front. Furthermore, we show that a critical localization-delocalization transition takes place as a control parameter which depends on the initial densities and on the diffusion constants is varied. The transition is between a reaction front of finite width that is localized at the wall and a front which is detached and moves away from the wall. At the critical point, the reaction front remains at the wall but its width diverges with time [as t^(1/6) in mean-field approximation].Comment: 7 pages, PS fil

Variational perturbation approach to the Coulomb electron gas

The efficiency of the variational perturbation theory [Phys. Rev. C {\bf 62}, 045503 (2000)] formulated recently for many-particle systems is examined by calculating the ground state correlation energy of the 3D electron gas with the Coulomb interaction. The perturbation beyond a variational result can be carried out systematically by the modified Wick's theorem which defines a contraction rule about the renormalized perturbation. Utilizing the theorem, variational ring diagrams of the electron gas are summed up. As a result, the correlation energy is found to be much closer to the result of the Green's function Monte Carlo calculation than that of the conventional ring approximation is.Comment: 4 pages, 3 figure

Magnetic-field-induced collapse of charge-ordered nanoclusters and the Colossal Magnetoresistance effect in Nd(0.3)Sr(0.3)MnO(3)

We report synchrotron x-ray scattering studies of charge/orbitally ordered (COO) nanoclusters in Nd$_{0.7}$Sr$_{0.3}$MnO$_3$. We find that the COO nanoclusters are strongly suppressed in an applied magnetic field, and that their decreasing concentration follows the field-induced decrease of the sample electrical resistivity. The COO nanoclusters, however, do not completely disappear in the conducting state, suggesting that this state is inhomogeneous and contains an admixture of an insulating phase. Similar results were also obtained for the zero-field insulator-metal transition that occurs as temperature is reduced. These observations suggest that these correlated lattice distortions play a key role in the Colossal Magnetoresistance effect in this prototypical manganite.Comment: 5 pages, 3 embedded eps figures; to appear in PRB Rapid Commumication

The definability criterions for convex projective polyhedral reflection groups

Following Vinberg, we find the criterions for a subgroup generated by reflections \Gamma \subset \SL^{\pm}(n+1,\mathbb{R}) and its finite-index subgroups to be definable over $\mathbb{A}$ where $\mathbb{A}$ is an integrally closed Noetherian ring in the field $\mathbb{R}$. We apply the criterions for groups generated by reflections that act cocompactly on irreducible properly convex open subdomains of the $n$-dimensional projective sphere. This gives a method for constructing injective group homomorphisms from such Coxeter groups to \SL^{\pm}(n+1,\mathbb{Z}). Finally we provide some examples of \SL^{\pm}(n+1,\mathbb{Z})-representations of such Coxeter groups. In particular, we consider simplicial reflection groups that are isomorphic to hyperbolic simplicial groups and classify all the conjugacy classes of the reflection subgroups in \SL^{\pm}(n+1,\mathbb{R}) that are definable over $\mathbb{Z}$. These were known by Goldman, Benoist, and so on previously.Comment: 31 pages, 8 figure