Numerical Simulations of Torsional Alfv\'en Waves in Axisymmetric Solar Magnetic Flux Tubes

We investigate numerically Alfv\'en waves propagating along an axisymmetric and non-isothermal solar flux tube embedded in the solar atmosphere. The tube magnetic field is current-free and diverges with height, and the waves are excited by a periodic driver along the tube magnetic field lines. The main results are that the two wave variables, the velocity and magnetic field perturbations in the azimuthal direction, behave differently as a result of gradients of physical parameters along the tube. To explain these differences in the wave behavior, the time evolution of the wave variables and the resulting cutoff period for each wave variable are calculated, and used to determine regions in the solar chromosphere where strong wave reflection may occur.Comment: Submitted to Solar Physics (accepted

On Thermal-Pulse-Driven Plasma Flows in Coronal Funnels as Observed by Hinode/EUV Imaging Spectrometer (EIS)

Using one-arcsecond-slit scan observations from the Hinode/EUV Imaging Spectrometer (EIS) on 05 February 2007, we find the plasma outflows in the open and expanding coronal funnels at the eastern boundary of AR 10940. The Doppler velocity map of Fe XII 195.120 A shows that the diffuse close-loop system to be mostly red-shifted. The open arches (funnels) at the eastern boundary of AR exhibit blue-shifts with a maximum speed of about 10-15 km/s. This implies outflowing plasma through these magnetic structures. In support of these observations, we perform a 2D numerical simulation of the expanding coronal funnels by solving the set of ideal MHD equations in appropriate VAL-III C initial temperature conditions using the FLASH code. We implement a rarefied and hotter region at the footpoint of the model funnel, which results in the evolution of slow plasma perturbations propagating outward in the form of plasma flows. We conclude that the heating, which may result from magnetic reconnection, can trigger the observed plasma outflows in such coronal funnels. This can transport mass into the higher corona, giving rise to the formation of the nascent solar wind.Comment: 17 Pages; 7 Figure

Numerical simulations of torsional Alfvén waves in axisymmetric solar magnetic flux tubes

We numerically investigate Alfvén waves propagating along an axisymmetric and non-isothermal solar flux tube embedded in the solar atmosphere. The tube magnetic field is current-free and diverges with height, and the waves are excited by a periodic driver along the tube magnetic field lines. The main results are that the two wave variables, the velocity and magnetic field perturbations in the azimuthal direction, behave differently as a result of gradients of the physical parameters along the tube. To explain these differences in the wave behavior, the time evolution of the wave variables and the resulting cutoff period for each wave variable are calculated and used to determine regions in the solar chromosphere where strong wave reflection may occur

Velocity Response of the Observed Explosive Events in the Lower Solar Atmosphere: I. Formation of the Flowing Cool Loop System

We observe plasma flows in cool loops using the Slit-Jaw Imager (SJI) onboard the Interface Region Imaging Spectrometer (IRIS). Huang et al. (2015) observed unusually broadened Si IV 1403 angstrom line profiles at the footpoints of such loops that were attributed to signatures of explosive events (EEs). We have chosen one such uni-directional flowing cool loop system observed by IRIS where one of the footpoints is associated with significantly broadened Si IV line profiles. The line profile broadening indirectly indicates the occurrence of numerous EEs below the transition region (TR), while it directly infers a large velocity enhancement /perturbation further causing the plasma flows in the observed loop system. The observed features are implemented in a model atmosphere in which a low-lying bi-polar magnetic field system is perturbed in the chromosphere by a velocity pulse with a maximum amplitude of 200 km/s. The data-driven 2-D numerical simulation shows that the plasma motions evolve in a similar manner as observed by IRIS in the form of flowing plasma filling the skeleton of a cool loop system. We compare the spatio-temporal evolution of the cool loop system in the framework of our model with the observations, and conclude that their formation is mostly associated with the velocity response of the transient energy release above their footpoints in the chromosphere/TR. Our observations and modeling results suggest that the velocity responses most likely associated to the EEs could be one of the main candidates for the dynamics and energetics of the flowing cool loop systems in the lower solar atmosphere.Comment: In Press; The Astrophysical Journal; 14 Pages; 9 Figure

Numerical Simulations of Magnetoacoustic-Gravity Waves in the Solar Atmosphere

We investigate the excitation of magnetoacoustic-gravity waves generated from localized pulses in the gas pressure as well as in vertical component of velocity. These pulses are initially launched at the top of the solar photosphere that is permeated by a weak magnetic field. We investigate three different configurations of the background magnetic field lines: horizontal, vertical and oblique to the gravitational force. We numerically model magnetoacoustic-gravity waves by implementing a realistic (VAL-C) model of solar temperature. We solve two-dimensional ideal magnetohydrodynamic equations numerically with the use of the FLASH code to simulate the dynamics of the lower solar atmosphere. The initial pulses result in shocks at higher altitudes. Our numerical simulations reveal that a small-amplitude initial pulse can produce magnetoacoustic-gravity waves, which are later reflected from the transition region due to the large temperature gradient. The atmospheric cavities in the lower solar atmosphere are found to be the ideal places that may act as a resonator for various oscillations, including their trapping and leakage into the higher atmosphere. Our numerical simulations successfully model the excitation of such wave modes, their reflection and trapping, as well as the associated plasma dynamics

Atropselective syntheses of (-) and (+) rugulotrosin A utilizing point-to-axial chirality transfer

Chiral, dimeric natural products containing complex structures and interesting biological properties have inspired chemists and biologists for decades. A seven-step total synthesis of the axially chiral, dimeric tetrahydroxanthone natural product rugulotrosin A is described. The synthesis employs a one-pot Suzuki coupling/dimerization to generate the requisite 2,2'-biaryl linkage. Highly selective point-to-axial chirality transfer was achieved using palladium catalysis with achiral phosphine ligands. Single X-ray crystal diffraction data were obtained to confirm both the atropisomeric configuration and absolute stereochemistry of rugulotrosin A. Computational studies are described to rationalize the atropselectivity observed in the key dimerization step. Comparison of the crude fungal extract with synthetic rugulotrosin A and its atropisomer verified that nature generates a single atropisomer of the natural product.P50 GM067041 - NIGMS NIH HHS; R01 GM099920 - NIGMS NIH HHS; GM-067041 - NIGMS NIH HHS; GM-099920 - NIGMS NIH HH

Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates

NOTICE: This is the peer reviewed version of the following book chapter: Varela J. A., González-Rodríguez C., Saá C. (2014). Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates. In: Dixneuf P., Bruneau C. (eds) Ruthenium in Catalysis. Topics in Organometallic Chemistry, vol 48, pp. 237-287. Springer, Cham. [doi: 10.1007/3418_2014_81]. This article may be used for non-commercial purposes in accordance with Springer Verlag Terms and Conditions for self-archiving.Vinylidenes are high-energy tautomers of terminal alkynes and they can be stabilized by coordination with transition metals. The resulting metal-vinylidene species have interesting chemical properties that make their reactivity different to that of the free and metal π-coordinated alkynes: the carbon α to the metal is electrophilic whereas the β carbon is nucleophilic. Ruthenium is one of the most commonly used transition metals to stabilize vinylidenes and the resulting species can undergo a range of useful transformations. The most remarkable transformations are the regioselective anti-Markovnikov addition of different nucleophiles to catalytic ruthenium vinylidenes and the participation of the π system of catalytic ruthenium vinylidenes in pericyclic reactions. Ruthenium vinylidenes have also been employed as precatalysts in ring closing metathesis (RCM) or ring opening metathesis polymerization (ROMP). Allenylidenes could be considered as divalent radicals derived from allenes. In a similar way to vinylidenes, allenylidenes can be stabilized by coordination with transition metals and again ruthenium is one of the most widely used metals. Metalallenylidene complexes can be easily obtained from terminal propargylic alcohols by dehydration of the initially formed metal-hydroxyvinylidenes, in which the reactivity of these metal complexes is based on the electrophilic nature of Cα and Cγ, while Cβ is nucleophilic. Catalytic processes based on nucleophilic additions and pericyclic reactions involving the π system of ruthenium allenylidenes afford interesting new structures with high selectivity and atom economy