3,5-Dinitro­benzyl methane­sulfonate

The title compound, C8H8N2O7S, an inter­mediate in the synthesis of N,N-bis­(2-hydroxy­ethyl)-3,5-dinitro­aniline, exists as a discrete mol­ecule; the nitro groups are twisted with respect to the aromatic system [dihedral angles = 17.0 (1) and 26.3 (1)°]

Phonological encoding in Tongan: An experimental investigation

This study is the first to report chronometric evidence on Tongan language production. It has been speculated that the mora plays an important role during Tongan phonological encoding. A mora follows the (C)V form, so /a/ and /ka/ (but not /k/) denote a mora in Tongan. Using a picture-word naming paradigm, Tongan native speakers named pictures containing superimposed non-word distractors. This task has been used before in Japanese, Korean, and Vietnamese to investigate the initially selected unit during phonological encoding (IPU). Compared to control distractors, both onset and mora overlapping distractors resulted in faster naming latencies. Several alternative explanations for the pattern of results - proficiency in English, knowledge of Latin script, and downstream effects - are discussed. However, we conclude that Tongan phonological encoding likely natively uses the phoneme, and not the mora, as the IPU.

On the Formation of Copper Linear Atomic Suspended Chains

We report high resolution transmission electron microscopy and classical molecular dynamics simulation results of mechanically stretching copper nanowires conducting to linear atomic suspended chains (LACs) formation. In contrast with some previous experimental and theoretical work in literature that stated that the formation of LACs for copper should not exist our results showed the existence of LAC for the [111], [110], and [100] crystallographic directions, being thus the sequence of most probable occurence.Comment: 4 pages, 3 figure

An update on THORPEX-related research in data assimilation and observing strategies

International audienceThe international programme "THORPEX: a World Weather Research Programme" provides a framework in which to tackle the challenge of improving the forecast skill of high-impact weather through international collaboration between academic institutions, operational forecast centres, and users of forecast products. The objectives of the THORPEX Data Assimilation and Observation Strategy Working Group (DAOS-WG) are two-fold. The primary goal is to assess the impact of observations and various targeting methods to provide guidance for observation campaigns and for the configuration of the Global Observing System. The secondary goal is to setup an optimal framework for data assimilation, including aspects such as targeted observations, satellite data, background error covariances and quality control. The Atlantic THORPEX Regional campaign, ATReC, in 2003, has been very successful technically and has provided valuable datasets to test targeting issues. Various data impact experiments have been performed, showing a small but very slightly positive impact of targeted observations. Projects of the DAOS-WG include working on the AMMA field experiment, in the context of IPY and to prepare the future THORPEX-PARC field campaign in the Pacific by comparing sensitivity of the forecasts to observations between several groups

Multiple addition theorem for discrete and continuous nonlinear problems

The addition relation for the Riemann theta functions and for its limits, which lead to the appearance of exponential functions in soliton type equations is discussed. The presented form of addition property resolves itself to the factorization of N-tuple product of the shifted functions and it seems to be useful for analysis of soliton type continuous and discrete processes in the N+1 space-time. A close relation with the natural generalization of bi- and tri-linear operators into multiple linear operators concludes the paper.Comment: 9 page

Doping dependence of the exchange energies in bilayer manganites: Role of orbital degrees of freedom

Recently, an intriguing doping dependence of the exchange energies in the bilayer manganites $La_{2-2x}Sr_{1+2x}Mn_2O_7$ has been observed in the neutron scattering experiments. The intra-layer exchange only weakly changed with doping while the inter-layer one drastically decreased. Here we propose a theory which accounts for these experimental findings. We argue, that the observed striking doping dependence of the exchange energies can be attributed to the evaluation of the orbital level splitting with doping. The latter is handled by the interplay between Jahn-Teller effect (supporting an axial orbital) and the orbital anisotropy of the electronic band in the bilayer structure (promoting an in-plane orbital), which is monitored by the Coulomb repulsion. The presented theory, while being a mean-field type, describes well the experimental data and also gives the estimates of the several interesting energy scales involved in the problem.Comment: Added references, corrected typos. To appear in Phys. Rev.

Absolute photoionization cross section measurements of the Kr I-isoelectronic sequence

Photoionization spectra have been recorded in the 4s, 4p and 3d resonance regions for the Kr Iisoelectronic sequence using both the dual laser produced plasma technique (at DCU) to produce photoabsorption spectra, and the merged ion beam and synchrotron radiation technique (at ASTRID) to measure absolute photoionization cross sections. Profile parameters are compared for the 4s − np resonances of Rb+ and Sr2+. Many new 4p " ns, md transitions are identified with the aid of Hartree-Fock calculations, and consistent quantum defects are observed for the various ns and md Rydberg series. Absolute single and double photoionization cross sections recorded in the 3d region for Rb+ and Sr2+ ions show preferential decay via double photoionization. This is only the second report where both the DLP technique and the merged beam technique have been used simultaneously to record photoionization spectra, and the advantages of both techniques (i.e. better resolution in the case of DLP and values for absolute photoionization cross sections in the case of the merged beam technique) are highlighted