463 research outputs found
Photoionization and Photoelectric Loading of Barium Ion Traps
Simple and effective techniques for loading barium ions into linear Paul
traps are demonstrated. Two-step photoionization of neutral barium is achieved
using a weak intercombination line (6s2 1S0 6s6p 3P1, 791 nm) followed by
excitation above the ionization threshold using a nitrogen gas laser (337 nm).
Isotopic selectivity is achieved by using a near Doppler-free geometry for
excitation of the triplet 6s6p 3P1 state. Additionally, we report a
particularly simple and efficient trap loading technique that employs an
in-expensive UV epoxy curing lamp to generate photoelectrons.Comment: 5 pages, Accepted to PRA 3/20/2007 -fixed typo -clarified figure 3
caption -added reference [15
Identification of OSSO as a near-UV absorber in the Venusian atmosphere
The planet Venus exhibits atmospheric absorption in the 320–400 nm wavelength range produced by unknown chemistry. We investigate electronic transitions in molecules that may exist in the atmosphere of Venus. We identify two different S_2O_2 isomers, cis-OSSO and trans-OSSO, which are formed in significant amounts and are removed predominantly by near-UV photolysis. We estimate the rate of photolysis of cis- and trans-OSSO in the Venusian atmosphere and find that they are good candidates to explain the enigmatic 320–400 nm near-UV absorption. Between 58 and 70 km, the calculated OSSO concentrations are similar to those of sulfur monoxide (SO), generally thought to be the second most abundant sulfur oxide on Venus
Bright Source of Cold Ions for Surface-Electrode Traps
We produce large numbers of low-energy ions by photoionization of
laser-cooled atoms inside a surface-electrode-based Paul trap. The
isotope-selective trap loading rate of Yb ions/s exceeds
that attained by photoionization (electron impact ionization) of an atomic beam
by four (six) orders of magnitude. Traps as shallow as 0.13 eV are easily
loaded with this technique. The ions are confined in the same spatial region as
the laser-cooled atoms, which will allow the experimental investigation of
interactions between cold ions and cold atoms or Bose-Einstein condensates.Comment: Paper submitted to PRL for review on 2/1/0
About the dynamics and thermodynamics of trapped ions
This tutorial introduces the dynamics of charged particles in a
radiofrequency trap in a very general manner to point out the differences
between the dynamics in a quadrupole and in a multipole trap. When dense
samples are trapped, the dynamics is modified by the Coulomb repulsion between
ions. To take into account this repulsion, we propose to use a method,
originally developed for particles in Penning trap, that model the ion cloud as
a cold fluid. This method can not reproduce the organisation of cold clouds as
crystals but it allows one to scale the size of large samples with the trapping
parameters and the number of ions trapped, for different linear geometries of
trap.Comment: accepted for publication in the "Modern Applications of Trapped Ions"
special issu
Non-Destructive Identification of Cold and Extremely Localized Single Molecular Ions
A simple and non-destructive method for identification of a single molecular
ion sympathetically cooled by a single laser cooled atomic ion in a linear Paul
trap is demonstrated. The technique is based on a precise determination of the
molecular ion mass through a measurement of the eigenfrequency of a common
motional mode of the two ions. The demonstrated mass resolution is sufficiently
high that a particular molecular ion species can be distinguished from other
equally charged atomic or molecular ions having the same total number of
nucleons
Mesoscopic atomic entanglement for precision measurements beyond the standard quantum limit
Squeezing of quantum fluctuations by means of entanglement is a well
recognized goal in the field of quantum information science and precision
measurements. In particular, squeezing the fluctuations via entanglement
between two-level atoms can improve the precision of sensing, clocks,
metrology, and spectroscopy. Here, we demonstrate 3.4 dB of metrologically
relevant squeezing and entanglement for ~ 10^5 cold cesium atoms via a quantum
nondemolition (QND) measurement on the atom clock levels. We show that there is
an optimal degree of decoherence induced by the quantum measurement which
maximizes the generated entanglement. A two-color QND scheme used in this paper
is shown to have a number of advantages for entanglement generation as compared
to a single color QND measurement.Comment: 6 pages+suppl, PNAS forma
Identification of OSSO as a near-UV absorber in the Venusian atmosphere
The planet Venus exhibits atmospheric absorption in the 320–400 nm wavelength range produced by unknown chemistry. We investigate electronic transitions in molecules that may exist in the atmosphere of Venus. We identify two different S_2O_2 isomers, cis-OSSO and trans-OSSO, which are formed in significant amounts and are removed predominantly by near-UV photolysis. We estimate the rate of photolysis of cis- and trans-OSSO in the Venusian atmosphere and find that they are good candidates to explain the enigmatic 320–400 nm near-UV absorption. Between 58 and 70 km, the calculated OSSO concentrations are similar to those of sulfur monoxide (SO), generally thought to be the second most abundant sulfur oxide on Venus
Peroxy radical chemistry and OH radical production during the NO_3-initiated oxidation of isoprene
Peroxy radical reactions (RO_2 + RO_2) from the NO3-initiated oxidation of isoprene are studied with both gas chromatography and a chemical ionization mass spectrometry technique that allows for more specific speciation of products than in previous studies of this system. We find high nitrate yields (~ 80%), consistent with other studies. We further see evidence of significant hydroxyl radical (OH) formation in this system, which we propose comes from RO_2 + HO_2 reactions with a yield of ~38–58%. An additional OH source is the second generation oxidation of the nitrooxyhydroperoxide, which produces OH and a dinitrooxyepoxide with a yield of ~35%. The branching ratio of the radical propagating, carbonyl- and alcohol-forming, and organic peroxide-forming channels of the RO_2 + RO_2 reaction are found to be ~18–38%, ~59–77%, and ~3–4%, respectively. HO_2 formation in this system is lower than has been previously assumed. Addition of RO_2 to isoprene is suggested as a possible route to the formation of several isoprene C_(10)-organic peroxide compounds (ROOR). The nitrooxy, allylic, and C_5 peroxy radicals present in this system exhibit different behavior than the limited suite of peroxy radicals that have been studied to date
Formation of Highly Oxidized Molecules from NO3 Radical Initiated Oxidation of Delta-3-Carene : A Mechanistic Study
NO3 radical oxidation of most monoterpenes is a significant source of secondary organic aerosol (SOA) in many regions influenced by both biogenic and anthropogenic emissions, but there are very few published mechanistic studies of NO3 chemistry beyond simple first generation products. Here, we present a computationally derived mechanism detailing the unimolecular pathways available to the second generation of peroxy radicals following NO3 oxidation of Delta-3-carene, defining generations based on the sequence of peroxy radicals formed rather than number of oxidant attacks. We assess five different types of unimolecular reactions, including peroxy and alkoxy radical (RO2 and RO) hydrogen shifts, RO2 and RO ring closing (e.g., endoperoxide formation), and RO decomposition. Rate constants calculated using quantum chemical methods indicate that this chemical system has significant contribution from both bimolecular and unimolecular pathways. The dominant unimolecular reactions are endoperoxide formation, RO H-shifts, and RO decomposition. However, the complexity of the overall reaction is tempered as only 1 or 2 radical propagation pathways dominate the fate of each radical intermediate. Chemical ionization mass spectrometry (CIMS) measurements using the NO3- reagent ion during Delta-3-carene + NO3 chamber experiments show products consistent with each of the three types of unimolecular reactions predicted to be important from the computational mechanism. Moreover, the SIMPOL group contribution method for predicting vapor pressures suggests that a majority of the closed-shell products inferred from these unimolecular reactions are likely to have low enough vapor pressure to be able to contribute to SOA formation.Peer reviewe
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