646 research outputs found
The lithospheric mantle and lower crust-mantle relationships under Scotland: a xenolithic perspective
In the British Isles the majority of volcanic rocks containing upper mantle and lower crustal xenoliths occur in Scotland. Most of the occurrences are of Carboniferous–Permian age. This paper presents new data on the mineral chemistry of spinel lherzolite xenoliths from the five principal Scottish tectonic terranes. Compositional variations among the minerals emphasize the broad lateral heterogeneity of the subcontinental lithospheric mantle across the region. The remarkable range of Al2O3 v. CaO exhibited by the clinopyroxenes compared with data from other ‘xenolith provinces' emphasizes the extremely complex tectonomagmatic history of the Scottish lithosphere. The generalized age increase from southern and central Scotland to the Northern Highland and Hebridean terranes of the north and NW, with concomitant complexity of geological history, is reflected also by trace element and isotopic studies. Reaction relationships in lherzolites from the Hebridean Terrane, owing to pervasive metasomatism, involve secondary growth of sodic feldspar. This, and light REE enrichment of clinopyroxenes, points to involvement of a natro-carbonatitic melt. Most pyroxenitic xenoliths are inferred to form a basal crustal layer with a generally sharp discontinuity above the underlying (dominantly lherzolitic) mantle. A second discontinuity is inferred to separate these ultramafic cumulates from overlying, broadly cognate metagabbroic cumulates
Study of geometries of active magnetic regenerators for room temperature magnetocaloric refrigeration
Nanostructured solid-state hybrid photovoltaic cells fabricated by electrostatic layer-by-layer deposition
We report on the fabrication of hybrid organic/inorganic photovoltaic cells utilizing layer-by-layer deposition of water-soluble polyions and nanocrystals. A bulk heterojunction structure was created consisting of alternating layers of the p-conductive polythiophene derivative poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] and n-conductive TiO2nanoparticles. We fabricated working devices with the heterostructure sandwiched between suitable charge carrier blocking layers and conducting oxide and metal electrodes, respectively. We analyzed the influence of the thickness and nanostructure of the active layer on the cell performance and characterized the devices in terms of static and transient current response with respect to illumination and voltage conditions. We observed reproducible and stable photovoltaic behavior with photovoltages of up to 0.9 V
Inhomogeneous nuclear spin polarization induced by helicity-modulated optical excitation of fluorine-bound electron spins in ZnSe
Optically-induced nuclear spin polarization in a fluorine-doped ZnSe epilayer
is studied by time-resolved Kerr rotation using resonant excitation of
donor-bound excitons. Excitation with helicity-modulated laser pulses results
in a transverse nuclear spin polarization, which is detected as a change of the
Larmor precession frequency of the donor-bound electron spins. The frequency
shift in dependence on the transverse magnetic field exhibits a pronounced
dispersion-like shape with resonances at the fields of nuclear magnetic
resonance of the constituent zinc and selenium isotopes. It is studied as a
function of external parameters, particularly of constant and radio frequency
external magnetic fields. The width of the resonance and its shape indicate a
strong spatial inhomogeneity of the nuclear spin polarization in the vicinity
of a fluorine donor. A mechanism of optically-induced nuclear spin polarization
is suggested based on the concept of resonant nuclear spin cooling driven by
the inhomogeneous Knight field of the donor-bound electron.Comment: 12 pages, 11 figure
Influence of Complex Exciton-Phonon Coupling on Optical Absorption and Energy Transfer of Quantum Aggregates
We present a theory that efficiently describes the quantum dynamics of an
electronic excitation that is coupled to a continuous, highly structured phonon
environment. Based on a stochastic approach to non-Markovian open quantum
systems, we develop a dynamical framework that allows us to handle realistic
systems where a fully quantum treatment is desired yet the usual approximation
schemes fail. The capability of the method is demonstrated by calculating
spectra and energy transfer dynamics of mesoscopic molecular aggregates,
elucidating the transition from fully coherent to incoherent transfer
Modelling and comparison studies of packed screen regenerators for active magnetocaloric refrigeration
Optimization of Multi-layer Active Magnetic Regenerator towards Compact and Efficient Refrigeration
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