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Agricultural development prospects in Belize (NRI Bulletin 48)
This report is one ofthree documents completing the land resource assessment of Belize undertaken by the Natural Resources Institute (NRI)from 1986-90. The other documents are: (i) a revised national soil classification (Baillie et al., 1993) (ii) an update on 'Land in British Honduras' (Wright et al., 1959), which will present inter alia much of the NRI land resource assessment findings in a more easily readable format (Wright et al., 1993). The aim of this report is to assess the entire··agricultural resources of the country, present an assessment of how they can be used to best effect, both in the short(economically) and long terms (by protecting the environment), and present a 1:500 000 scale map indicating the preferred use for each part of the country (Map 1 ). Map 1 does not take into account current ownership, except in the case of Programme for Belize, where it is assumed that organization will continue to manage the Rio Bravo Conservation Management Area. This report also includes advice on how a Geographical Information System (GIS) can be used to update the NRI surveys and provide additional data so that the suitability of new crops and the effect of changed economic circumstances can be determined from the land resource assessment database
Effects of Strong Magnetic Fields in Strange Baryonic Matter
We investigate the effects of very strong magnetic fields upon the equation
of state of dense bayonic matter in which hyperons are present. In the presence
of a magnetic field, the equation of state above nuclear density is
significantly affected both by Landau quantization and magnetic moment
interactions, but only for field strengths G. The former
tends to soften the EOS and increase proton and lepton abundances, while the
latter produces an overall stiffening of the EOS. Each results in a supression
of hyperons relative to the field-free case. The structure of a neutron star
is, however, primarily determined by the magnetic field stress. We utilize
existing general relativistic magneto-hydrostatic calculations to demonstrate
that maximum average fields within a stable neutron are limited to values G. This is not large enough to significantly influence
particle compositions or the matter pressure, unless fluctuations dominate the
average field strengths in the interior or configurations with significantly
larger field gradients are considered.Comment: 12 pages, 3 figures. To be submitted to Phys. Lett.
Case report: Effectiveness of low-dose methotrexate monotherapy in post-essential thrombocythemia myelofibrosis
JAK/STAT pathway signalling is associated with both chronic inflammatory conditions such as psoriasis and haematological malignancies such as the myeloproliferative neoplasms (MPNs). Here we describe a 73yo female patient with a history of chronic plaque psoriasis, post-essential thrombocythemia myelofibrosis (MF) and a quality of life substantially impacted by both conditions. We report that 15 mg oral Methotrexate (MTX) weekly as a monotherapy is well tolerated, provides a substantial clinical improvement for both conditions and significantly improves quality of life. We suggest that the recently identified mechanism of action of MTX as a JAK inhibitor is likely to explain this efficacy and suggest that repurposing MTX for MPNs may represent a clinical- and cost-effective therapeutic option
Phase transitions in BaTiO from first principles
We develop a first-principles scheme to study ferroelectric phase transitions
for perovskite compounds. We obtain an effective Hamiltonian which is fully
specified by first-principles ultra-soft pseudopotential calculations. This
approach is applied to BaTiO, and the resulting Hamiltonian is studied
using Monte Carlo simulations. The calculated phase sequence, transition
temperatures, latent heats, and spontaneous polarizations are all in good
agreement with experiment. The order-disorder vs.\ displacive character of the
transitions and the roles played by different interactions are discussed.Comment: 13 page
Electron localization : band-by-band decomposition, and application to oxides
Using a plane wave pseudopotential approach to density functional theory we
investigate the electron localization length in various oxides. For this
purpose, we first set up a theory of the band-by-band decomposition of this
quantity, more complex than the decomposition of the spontaneous polarization
(a related concept), because of the interband coupling. We show its
interpretation in terms of Wannier functions and clarify the effect of the
pseudopotential approximation. We treat the case of different oxides: BaO,
-PbO, BaTiO and PbTiO. We also investigate the variation of the
localization tensor during the ferroelectric phase transitions of BaTiO as
well as its relationship with the Born effective charges
Controlling the structures of organic semiconductor–quantum dot nanocomposites through ligand shell chemistry
Nanocrystal quantum dots (QD) functionalised with active organic ligands hold significant promise as solar energy conversion materials, capable of multiexcitonic processes that could improve the efficiencies of single-junction photovoltaic devices. Small-angle X-ray and neutron scattering (SAXS and SANS) were used to characterize the structure of lead sulphide QDs post ligand-exchange with model acene-carboxylic acid ligands (benzoic acid, hydrocinnamic acid and naphthoic acid). Results demonstrate that hydrocinnamic acid and naphthoic acid ligated QDs form monolayer ligand shells, whilst benzoic acid ligated QDs possess ligand shells thicker than a monolayer. Further, the formation of a range of nanocomposite materials through the self-assembly of such acene-ligated QDs with an organic small-molecule semiconductor [5,12-bis((triisopropylsilyl)ethynyl)tetracene (TIPS-Tc)] is investigated. These materials are representative of a wider set of functional solar energy materials; here the focus is on structural studies, and their optoelectronic function is not investigated. As TIPS-Tc concentrations are increased, approaching the solubility limit, SANS data show that QD fractal-like features form, with structures possibly consistent with a diffusion limited aggregation mechanism. These, it is likely, act as heterogeneous nucleation agents for TIPS-Tc crystallization, generating agglomerates containing both QDs and TIPS-Tc. Within the TIPS-Tc crystals there seem to be three distinct QD morphologies: (i) at the crystallite centre (fractal-like QD aggregates acting as nucleating agents), (ii) trapped within the growing crystallite (giving rise to QD features ordered as sticky hard spheres), and (iii) a population of aggregate QDs at the periphery of the crystalline interface that were expelled from the growing TIPS-Tc crystal. Exposure of the QD:TIPS-Tc crystals to DMF vapour, a solvent known to be able to strip ligands from QDs, alters the spacing between PbS–hydrocinnamic acid and PbS–naphthoic acid ligated QD aggregate features. In contrast, for PbS–benzoic acid ligated QDs, DMF vapour exposure promotes the formation of ordered QD colloidal crystal type phases. This work thus demonstrates how different QD ligand chemistries control the interactions between QDs and an organic small molecule, leading to widely differing self-assembly processes. It highlights the unique capabilities of multiscale X-ray and neutron scattering in characterising such composite materials
Epitaxially strained [001]-(PbTiO)(PbZrO) superlattice and PbTiO from first principles
The effect of layer-by-layer heterostructuring and epitaxial strain on
lattice instabilities and related ferroelectric properties is investigated from
first principles for the [001]-(PbTiO)(PbZrO) superlattice and
pure PbTiO on a cubic substrate. The results for the superlattice show an
enhancement of the stability of the monoclinic r-phase with respect to pure
PbTiO. Analysis of the lattice instabilities of the relaxed centrosymmetric
reference structure computed within density functional perturbation theory
suggests that this results from the presence of two unstable zone-center modes,
one confined in the PbTiO layer and one in the PbZrO layer, which
produce in-plane and normal components of the polarization, respectively. The
zero-temperature dielectric response is computed and shown to be enhanced not
only near the phase boundaries, but throughout the r-phase. Analysis of the
analogous calculation for pure PbTiO is consistent with this
interpretation, and suggests useful approaches to engineering the dielectric
properties of artificially structured perovskite oxides.Comment: 8 pages, 5 figure
Cluster Masses Accounting for Structure along the Line of Sight
Weak gravitational lensing of background galaxies by foreground clusters
offers an excellent opportunity to measure cluster masses directly without
using gas as a probe. One source of noise which seems difficult to avoid is
large scale structure along the line of sight. Here I show that, by using
standard map-making techniques, one can minimize the deleterious effects of
this noise. The resulting uncertainties on cluster masses are significantly
smaller than when large scale structure is not properly accounted for, although
still larger than if it was absent altogether.Comment: 5 pages, 5 figure
A systematic review of physical activity promotion strategies
This article was first published in:British Journal of Sports Medicine:1996:30:84-89We have reviewed randomised controlled trials of physical activity promotion to provide recent and reliable information on the effectiveness of physical activity promotion. Computerised databases and references of references were searched. Experts were contacted and asked for information about existing work. Studies assessed were randomised controlled trials of healthy, free living, adult subjects, where exercise behaviour was the dependent variable. Eleven trials were identified. No United Kingdom based studies were found. Interventions that encourage walking and do not require attendance at a facility are most likely to lead to sustainable increases in overall physical activity. Brisk walking has the greatest potential for increasing overall activity levels of a sedentary population and meeting current public health recommendations. The small number of trials limits the strength of any conclusions and highlights the need for more research
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