Ground-state structure of the hydrogen double vacancy on Pd(111)

We determine the ground-state structure of a double vacancy in a hydrogen monolayer on the Pd(111) surface. We represent the double vacancy as a triple vacancy containing one additional hydrogen atom. The potential-energy surface for a hydrogen atom moving in the triple vacancy is obtained by density-functional theory, and the wave function of the fully quantum hydrogen atom is obtained by solving the Schr\"odinger equation. We find that an H atom in a divacancy defect experiences significant quantum effects, and that the ground-state wave function is centered at the hcp site rather than the fcc site normally occupied by H atoms on Pd(111). Our results agree well with scanning tunneling microscopy images.Comment: 5 pages, 3 figure

Structure of AlSb(001) and GaSb(001) Surfaces Under Extreme Sb-rich Conditions

We use density-functional theory to study the structure of AlSb(001) and GaSb(001) surfaces. Based on a variety of reconstruction models, we construct surface stability diagrams for AlSb and GaSb under different growth conditions. For AlSb(001), the predictions are in excellent agreement with experimentally observed reconstructions. For GaSb(001), we show that previously proposed model accounts for the experimentally observed reconstructions under Ga-rich growth conditions, but fails to explain the experimental observations under Sb-rich conditions. We propose a new model that has a substantially lower surface energy than all (nx5)-like reconstructions proposed previously and that, in addition, leads to a simulated STM image in better agreement with experiment than existing models. However, this new model has higher surface energy than some of (4x3)-like reconstructions, models with periodicity that has not been observed. Hence we conclude that the experimentally observed (1x5) and (2x5) structures on GaSb(001) are kinetically limited rather than at the ground state.Comment: 6 pages, 6 figure

Keepin’ it Real: From the Bronx to Cape Town, an Analysis of Hip-Hop in South Africa

Honors (Bachelor's)HistoryUniversity of Michiganhttp://deepblue.lib.umich.edu/bitstream/2027.42/98923/1/erwinkim.pd

Two-Dimensional Magnetohydrodynamic Simulations of Barred Galaxies

Barred galaxies are known to possess magnetic fields that may affect the properties of bar substructures such as dust lanes and nuclear rings. We use two-dimensional high-resolution magnetohydrodynamic (MHD) simulations to investigate the effects of magnetic fields on the formation and evolution of such substructures as well as on the mass inflow rates to the galaxy center. The gaseous medium is assumed to be infinitesimally-thin, isothermal, non-self-gravitating, and threaded by initially uniform, azimuthal magnetic fields. We find that there exists an outermost x1-orbit relative to which gaseous responses to an imposed stellar bar potential are completely different between inside and outside. Inside this orbit, gas is shocked into dust lanes and infalls to form a nuclear ring. Magnetic fields are compressed in dust lanes, reducing their peak density. Magnetic stress removes further angular momentum of the gas at the shocks, temporarily causing the dust lanes to bend into an 'L' shape and eventually leading to a smaller and more centrally distributed ring than in unmagnetized models. The mass inflow rates in magnetized models correspondingly become larger, by more than two orders of magnitude when the initial fields have an equipartition value with thermal energy, than in the unmagnetized counterparts. Outside the outermost x1-orbit, on the other hand, an MHD dynamo due to the combined action of the bar potential and background shear operates near the corotation and bar-end regions, efficiently amplifying magnetic fields. The amplified fields shape into trailing magnetic arms with strong fields and low density. The base of the magnetic arms has a thin layer in which magnetic fields with opposite polarity reconnect via a tearing-mode instability. This produces numerous magnetic islands with large density which propagate along the arms to turn the outer disk into a highly chaotic state.Comment: 22 pages, 19 figures, 3 tables; Accepted for publication in the ApJ; Version with full-resolution figures available at http://mirzam.snu.ac.kr/~wkim/Bar/mhdbar.pd

Cloudbus Toolkit for Market-Oriented Cloud Computing

This keynote paper: (1) presents the 21st century vision of computing and identifies various IT paradigms promising to deliver computing as a utility; (2) defines the architecture for creating market-oriented Clouds and computing atmosphere by leveraging technologies such as virtual machines; (3) provides thoughts on market-based resource management strategies that encompass both customer-driven service management and computational risk management to sustain SLA-oriented resource allocation; (4) presents the work carried out as part of our new Cloud Computing initiative, called Cloudbus: (i) Aneka, a Platform as a Service software system containing SDK (Software Development Kit) for construction of Cloud applications and deployment on private or public Clouds, in addition to supporting market-oriented resource management; (ii) internetworking of Clouds for dynamic creation of federated computing environments for scaling of elastic applications; (iii) creation of 3rd party Cloud brokering services for building content delivery networks and e-Science applications and their deployment on capabilities of IaaS providers such as Amazon along with Grid mashups; (iv) CloudSim supporting modelling and simulation of Clouds for performance studies; (v) Energy Efficient Resource Allocation Mechanisms and Techniques for creation and management of Green Clouds; and (vi) pathways for future research.Comment: 21 pages, 6 figures, 2 tables, Conference pape

The Black Hole Mass-Bulge Luminosity Relationship for Active Galactic Nuclei from Reverberation Mapping and Hubble Space Telescope Imaging

We investigate the relationship between black hole mass and bulge luminosity for AGNs with reverberation-based black hole mass measurements and bulge luminosities from two-dimensional decompositions of Hubble Space Telescope host galaxy images. We find that the slope of the relationship for AGNs is 0.76-0.85 with an uncertainty of ~0.1, somewhat shallower than the M_BH \propto L^{1.0+/-0.1} relationship that has been fit to nearby quiescent galaxies with dynamical black hole mass measurements. This is somewhat perplexing, as the AGN black hole masses include an overall scaling factor that brings the AGN M_BH-sigma relationship into agreement with that of quiescent galaxies. We discuss biases that may be inherent to the AGN and quiescent galaxy samples and could cause the apparent inconsistency in the forms of their M_BH-L_bulge relationships.Comment: 5 pages, 3 figures and 2 tables, submitted to ApJ Letter

Polarization tomography of metallic nanohole arrays

We report polarization tomography experiments on metallic nanohole arrays with square and hexagonal symmetry. As a main result, we find that a fully polarized input beam is partly depolarized after transmission through a nanohole array. This loss of polarization coherence is found to be anisotropic, i.e. it depends on the polarization state of the input beam. The depolarization is ascribed to a combination of two factors: i) the nonlocal response of the array due to surface plasmon propagation, ii) the non-plane wave nature of a practical input beam.Comment: 4 pages, 3 figures, 1 table, submitted to PR

Understanding visual map formation through vortex dynamics of spin Hamiltonian models

The pattern formation in orientation and ocular dominance columns is one of the most investigated problems in the brain. From a known cortical structure, we build spin-like Hamiltonian models with long-range interactions of the Mexican hat type. These Hamiltonian models allow a coherent interpretation of the diverse phenomena in the visual map formation with the help of relaxation dynamics of spin systems. In particular, we explain various phenomena of self-organization in orientation and ocular dominance map formation including the pinwheel annihilation and its dependency on the columnar wave vector and boundary conditions.Comment: 4 pages, 15 figure

In vitro antimicrobial and in vivo antioomycete activities of the novel antibiotic thiobutacin

BACKGROUND: A number of synthetic fungicides are not effective when confronted by oomycete pathogens because many fungicide targets are absent from oomycetes. Moreover, resistance to fungicides has already arisen in oomycete species, and thus development of new, effective and safe compounds for use in oomycete disease control is necessary. RESULTS: Zoospore lysis began at 10 µg mL −1 of thiobutacin, and most of the zoospores were collapsed at 50 µg mL −1 . Thiobutacin also revealed inhibitory activity against the cyst germination and hyphal growth of Phytophthora capsici at 50 µg mL −1 . Treatment with thiobutacin exhibited protective activity against development of Phytophthora disease on pepper plants. CONCLUSION: The authors verified in vitro antioomycete activity of thiobutacin against P. capsici and its control efficacy against Phytophthora blight in vivo . This is the first report to demonstrate in vivo antioomycete activity of the novel antibiotic thiobutacin against P. capsici infection. Copyright © 2007 Society of Chemical IndustryPeer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/57925/1/1494_ftp.pd