Argo data 1999-2019: two million temperature-salinity profiles and subsurface velocity observations from a global array of profiling floats.

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wong, A. P. S., Wijffels, S. E., Riser, S. C., Pouliquen, S., Hosoda, S., Roemmich, D., Gilson, J., Johnson, G. C., Martini, K., Murphy, D. J., Scanderbeg, M., Bhaskar, T. V. S. U., Buck, J. J. H., Merceur, F., Carval, T., Maze, G., Cabanes, C., Andre, X., Poffa, N., Yashayaev, I., Barker, P. M., Guinehut, S., Belbeoch, M., Ignaszewski, M., Baringer, M. O., Schmid, C., Lyman, J. M., McTaggart, K. E., Purkey, S. G., Zilberman, N., Alkire, M. B., Swift, D., Owens, W. B., Jayne, S. R., Hersh, C., Robbins, P., West-Mack, D., Bahr, F., Yoshida, S., Sutton, P. J. H., Cancouet, R., Coatanoan, C., Dobbler, D., Juan, A. G., Gourrion, J., Kolodziejczyk, N., Bernard, V., Bourles, B., Claustre, H., D'Ortenzio, F., Le Reste, S., Le Traon, P., Rannou, J., Saout-Grit, C., Speich, S., Thierry, V., Verbrugge, N., Angel-Benavides, I. M., Klein, B., Notarstefano, G., Poulain, P., Velez-Belchi, P., Suga, T., Ando, K., Iwasaska, N., Kobayashi, T., Masuda, S., Oka, E., Sato, K., Nakamura, T., Sato, K., Takatsuki, Y., Yoshida, T., Cowley, R., Lovell, J. L., Oke, P. R., van Wijk, E. M., Carse, F., Donnelly, M., Gould, W. J., Gowers, K., King, B. A., Loch, S. G., Mowat, M., Turton, J., Rama Rao, E. P., Ravichandran, M., Freeland, H. J., Gaboury, I., Gilbert, D., Greenan, B. J. W., Ouellet, M., Ross, T., Tran, A., Dong, M., Liu, Z., Xu, J., Kang, K., Jo, H., Kim, S., & Park, H. Argo data 1999-2019: two million temperature-salinity profiles and subsurface velocity observations from a global array of profiling floats. Frontiers in Marine Science, 7, (2020): 700, doi:10.3389/fmars.2020.00700.In the past two decades, the Argo Program has collected, processed, and distributed over two million vertical profiles of temperature and salinity from the upper two kilometers of the global ocean. A similar number of subsurface velocity observations near 1,000 dbar have also been collected. This paper recounts the history of the global Argo Program, from its aspiration arising out of the World Ocean Circulation Experiment, to the development and implementation of its instrumentation and telecommunication systems, and the various technical problems encountered. We describe the Argo data system and its quality control procedures, and the gradual changes in the vertical resolution and spatial coverage of Argo data from 1999 to 2019. The accuracies of the float data have been assessed by comparison with high-quality shipboard measurements, and are concluded to be 0.002°C for temperature, 2.4 dbar for pressure, and 0.01 PSS-78 for salinity, after delayed-mode adjustments. Finally, the challenges faced by the vision of an expanding Argo Program beyond 2020 are discussed.AW, SR, and other scientists at the University of Washington (UW) were supported by the US Argo Program through the NOAA Grant NA15OAR4320063 to the Joint Institute for the Study of the Atmosphere and Ocean (JISAO) at the UW. SW and other scientists at the Woods Hole Oceanographic Institution (WHOI) were supported by the US Argo Program through the NOAA Grant NA19OAR4320074 (CINAR/WHOI Argo). The Scripps Institution of Oceanography's role in Argo was supported by the US Argo Program through the NOAA Grant NA15OAR4320071 (CIMEC). Euro-Argo scientists were supported by the Monitoring the Oceans and Climate Change with Argo (MOCCA) project, under the Grant Agreement EASME/EMFF/2015/1.2.1.1/SI2.709624 for the European Commission

Reactivity of molecular oxygen with aluminum clusters: Density functional and Ab Initio molecular dynamics simulation study

Dissociative adsorption of molecular oxygen (O-2) on aluminum (Al) clusters has attracted much interest in the field of surface science and catalysis, but theoretical predictions of the reactivity of this reaction in terms of barrier height is still challenging. In this regard, we systematically investigate the reactivity of O-2 with Al clusters using density functional theory (DFT) and atom-centered density matrix propagation (ADMP) simulations. We also calculate potential energy surfaces (PESs) of the reaction between O-2 and Al clusters to estimate the barrier energy of this reaction. The M06-2X functional gives the barrier energy in agreement with the one calculated by coupled cluster singles and doubles with perturbed triples (CCSD(T)) while the TPSSh functional significantly underestimates the barrier height. The ADMP simulation using the M06-2X functional predicts the reactivity of O-2 with the Al cluster in agreement with the experimental findings, that is, singlet O-2 readily reacts with Al clusters but triplet O-2 is less reactive. We found that the ability of a DFT functional to describe the charge transfer appropriately is critical for calculating the barrier energy and the reactivity of the reaction of O-2 with Al clusters. The M06-2X functional is relevant for investigating chemical reactions involving Al and O-2. (c) 2016 Wiley Periodicals, Inc.11Nsciescopu

Phase-leg power equalization method of modular multilevel converter with APOD strategy under unbalanced fault condition

An active power oscillation damping (APOD) control is one of the representative unbalanced fault compensa-tion strategies. Recently, various studies have been performed on the effect of the APOD with the internal power dynamic analysis of a Modular Multilevel Converter (MMC); however, most of the papers have considered only the active power component for analyzing the internal dynamics of the MMC. During the APOD operation, while reactive power is supplied to the grid for the voltage compensation, phase-leg power imbalance can be aggravated. To enhance stability and reliability, the phase-leg power imbalance phenomenon should be sufficiently considered at the development stage of the controller. This research discovers that the phase-leg power imbalance rate could be determined by the magnitude and phase of the negative sequence component of the grid voltage and the amount of reactive power. In addition, the unbalanced power component can be accurately calculated only based on the grid voltage information and the reactive power reference. Also, this paper proposes a phase-leg power equalization method (PPEM) using unbalanced power component estimation. Furthermore, an improved control structure is also proposed to achieve more accurate phase -leg power equalization using the internal leg-energy dynamics analysis. The effectiveness of the proposed methods is verified through high-fidelity PSCAD/EMTDC time-domain simulations using Point-to-Point (PTP) MMC-HVDC system and Hardware-in-the-Loop Simulation (HILS) with the MMC-MVDC system

A Study on the Determination of Korea Affecting Tropical Cyclone Center for Best Tracking

The establishment of an independent tropical cyclone (TC) position is suggested for the purpose of constructing TC best track data of the Korea Meteorological Administration. The best track process was designed with five basic stages: database, potential interval (PI), optimization, smoothing, and metadata. The PI was newly devised as a tool for expressing the uncertainty in the location of the center of the TC. This PI determined the minimum range at which the center of the TC can be adjusted and based on the analysis manual for each dataset used in the TC best tracking. Furthermore, the PI can be optimized by the differential application of the range depending on the reliability of the data. By smoothing all TC centers within the optimized PI, a best track can be produced more stably. Therefore, the analysis can be less subjective even when the determination of the TC center is difficult. For three typhoon cases that had affected Korea in 2013 (LEEPI, KONG-REY, and DANAS), best tracks were obtained based on the suggested analysis stages and verified. The results showed that the PI was relatively large in the early development and weakening stage of the TC or when the estimation of the TC center was difficult because of interactions with the land. And the best tracking was performed well with reasonable applicability

Density Functional Theory Assessment of Molecular Structures and Energies of Neutral and Anionic Al_<i>n</i> (<i>n</i> = 2–10) Clusters

We report the results of a benchmarking study on hybrid, hybrid-meta, long-range-corrected, meta-generalized gradient approximation (meta-GGA), and GGA density functional theory (DFT) methods for aluminum (Al) clusters. A range of DFT functionals, such as B3LYP, B1B95, PBE0, mPW1PW91, M06, M06-2X, ωB97X, ωB97XD, TPSSh, BLYP, PBE, mPWPW91, M06-L, and TPSS, have been used to optimize the molecular structures and calculate the vibrational frequencies and four energetic parameters for neutral and anionic Al_<i>n</i> (<i>n</i> = 2–10) clusters. The performances of these functionals are assessed systematically by calculating the vertical ionization energy for neutral Al clusters and the vertical electron detachment energy for anionic Al clusters, along with the cohesive energy and dissociation energy. The results are compared with the available experimental and high-level ab initio calculated results. The calculated results showed that the PBE0 and mPW1PW91 functionals generally provide better results than the other functionals studied. TPSS can be a good choice for the calculations of very large Al clusters. On the other hand, the B3LYP, BLYP, and M06-L functionals are in poor agreement with the available experimental and theoretical results. The calculated results suggest that the hybrid DFT functionals like B3LYP do not always provide better performance than GGA functionals

Verification of Forecast Performance of a Rapid Refresh Wave Model Based on Wind–Wave Interaction Effect

In this study, we constructed a rapid refresh wave forecast model using sea winds from the Korea Local Analysis and Prediction System as input forcing data. The model evaluated the changes in forecast performance considering the influence of input wind–wave interaction, which is an important factor that determines forecast performance. The forecast performance was evaluated by comparing the forecast results of the wave model with the significant wave height, wave period, and wave direction provided by moored buoy observations. During the typhoon season, the model tended to underestimate the conditions, and the root mean square error (RMSE) was reduced by increasing the wind and wave interaction parameter. The best value of the interaction parameter that minimizes the RMSE was determined based on the results of the numerical experiments performed during the typhoon season. The forecast error in the typhoon season was higher than that observed in the analysis results of the non-typhoon season. This can be attributed to the variations of the wave energy caused by the relatively strong typhoon wind field considered in the wave model

Tracking reaction dynamics in solution by pump–probe X-ray absorption spectroscopy and X-ray liquidography (solution scattering)

Characterization of transient molecular structures formed during chemical and biological processes is essential for understanding their mechanisms and functions. Over the last decade, time-resolved X-ray liquidography (TRXL) and time-resolved X-ray absorption spectroscopy (TRXAS) have emerged as powerful techniques for molecular and electronic structural analysis of photoinduced reactions in the solution phase. Both techniques make use of a pump–probe scheme that consists of (1) an optical pump pulse to initiate a photoinduced process and (2) an X-ray probe pulse to monitor changes in the molecular structure as a function of time delay between pump and probe pulses. TRXL is sensitive to changes in the global molecular structure and therefore can be used to elucidate structural changes of reacting solute molecules as well as the collective response of solvent molecules. On the other hand, TRXAS can be used to probe changes in both local geometrical and electronic structures of specific X-ray-absorbing atoms due to the element-specific nature of core-level transitions. These techniques are complementary to each other and a combination of the two methods will enhance the capability of accurately obtaining structural changes induced by photoexcitation. Here we review the principles of TRXL and TRXAS and present recent application examples of the two methods for studying chemical and biological processes in solution. Furthermore, we briefly discuss the prospect of using X-ray free electron lasers for the two techniques, which will allow us to keep track of structural dynamics on femtosecond time scales in various solution-phase molecular reactions

Tracking reaction dynamics in solution by pump–probe X-ray absorption spectroscopy and X-ray liquidography (solution scattering)

Characterization of transient molecular structures formed during chemical and biological processes is essential for understanding their mechanisms and functions. Over the last decade, time-resolved X-ray liquidography (TRXL) and time-resolved X-ray absorption spectroscopy (TRXAS) have emerged as powerful techniques for molecular and electronic structural analysis of photoinduced reactions in the solution phase. Both techniques make use of a pump-probe scheme that consists of (1) an optical pump pulse to initiate a photoinduced process and (2) an X-ray probe pulse to monitor changes in the molecular structure as a function of time delay between pump and probe pulses. TRXL is sensitive to changes in the global molecular structure and therefore can be used to elucidate structural changes of reacting solute molecules as well as the collective response of solvent molecules. On the other hand, TRXAS can be used to probe changes in both local geometrical and electronic structures of specific X-ray-absorbing atoms due to the element-specific nature of core-level transitions. These techniques are complementary to each other and a combination of the two methods will enhance the capability of accurately obtaining structural changes induced by photoexcitation. Here we review the principles of TRXL and TRXAS and present recent application examples of the two methods for studying chemical and biological processes in solution. Furthermore, we briefly discuss the prospect of using X-ray free electron lasers for the two techniques, which will allow us to keep track of structural dynamics on femtosecond time scales in various solution-phase molecular reactions.1110sciescopu