Double Resonance in Dalitz Plot of M(pLambda)-M(KLambda) in DISTO Data on p+p rightarrow p+Lambda+K+ at 2.85 GeV

The X(2265) resonance was previously observed in DISTO data of p+p rightarrow p+Lambda+K+ at 2.85 GeV on an attempt of searching for the kaonic nuclear state K-pp rightarrow p + Lambda. In the present paper we report an additional finding, namely, a double resonance type phenomena, not only with a peak at M(pLambda) = 2265 MeV/c2 but also a broad bump at M(K+ Lambda) ~ 1700 MeV/c2. This "double-resonance" zone is expressed as XY(2265, 1700). The latter bump may result from nearby nucleon resonances, typically N*(1710), as well as by attractive K - Lambda final-state interaction. We point out that this double resonance XY(2265, 1700) as seen in DISTO at 2.85 GeV cannot be populated kinematically in a HADES experiment at 3.5 GeV.Comment: 4 pages, 3 figures, HYP2015 conferenc

Systematic Selection of Green Solvents and Process Optimization for the Hydroformylation of Long-Chain Olefines

Including ecologic and environmental aspects in chemical engineering requires new methods for process design and optimization. In this work, a hydroformylation process of long-chain olefines is investigated. A thermomorphic multiphase system is employed that is homogeneous at reaction conditions and biphasic at lower temperatures for catalyst recycling. In an attempt to replace the toxic polar solvent N,N-dimethylformamide (DMF), ecologically benign alternatives are selected using a screening approach. Economic process optimization is conducted for DMF and two candidate solvents. It is found that one of the green candidates performs similarly well as the standard benchmark solvent DMF, without being toxic. Therefore, the candidate has the potential to replace it

New Way to Produce Dense Double-Antikaonic Dibaryon System, \bar{K}\bar{K} NN, through Lambda(1405)-Doorway Sticking in p+p Collisions

A recent successful observation of a dense and deeply bound \bar{K} nuclear system, K^-pp, in the p + p \rightarrow K^+ + K^-pp reaction in a DISTO experiment indicates that the double-\bar{K} dibaryon, K^-K^-pp, which was predicted to be a dense nuclear system, can also be formed in p+p collisions. We find theoretically that the K^- -K^- repulsion plays no significant role in reducing the density and binding energy of K^-K^-pp and that, when two \Lambda(1405) resonances are produced simultaneously in a short-range p+p collision, they act as doorways to copious formation of K^-K^-pp, if and only if K^-K^-pp is a dense object, as predicted.Comment: 8 pages, 9 figures, Accepted Apr. 19, 201

Extended Huckel theory for bandstructure, chemistry, and transport. II. Silicon

In this second paper, we develop transferable semi-empirical parameters for the technologically important material, silicon, using Extended Huckel Theory (EHT) to calculate its electronic structure. The EHT-parameters areoptimized to experimental target values of the band dispersion of bulk-silicon. We obtain a very good quantitative match to the bandstructure characteristics such as bandedges and effective masses, which are competitive with the values obtained within an $sp^3 d^5 s^*$ orthogonal-tight binding model for silicon. The transferability of the parameters is investigated applying them to different physical and chemical environments by calculating the bandstructure of two reconstructed surfaces with different orientations: Si(100) (2x1) and Si(111) (2x1). The reproduced $\pi$- and $\pi^*$-surface bands agree in part quantitatively with DFT-GW calculations and PES/IPES experiments demonstrating their robustness to environmental changes. We further apply the silicon parameters to describe the 1D band dispersion of a unrelaxed rectangular silicon nanowire (SiNW) and demonstrate the EHT-approach of surface passivation using hydrogen. Our EHT-parameters thus provide a quantitative model of bulk-silicon and silicon-based materials such as contacts and surfaces, which are essential ingredients towards a quantitative quantum transport simulation through silicon-based heterostructures.Comment: 9 pages, 9 figure

Mistletoe treatment in cancer-related fatigue: a case report

Cancer-related fatigue (CRF) is a major and very common disabling condition in cancer patients. Treatment options do exist but have limited therapeutic effects. Mistletoe extracts are widely-used complementary cancer treatments whose possible impact on CRF has not been investigated in detail. A 36-year-old Swedish woman with a 10-year history of recurrent breast cancer, suffering from severe CRF, started complementary cancer treatment with mistletoe extracts. Over two and a half years a correspondence was observed between the intensity of mistletoe therapy and the fatigue. Mistletoe extracts seemed to have a beneficial, dose-dependent effect on CRF. Although such effect has also been noted in clinical studies, it has never been the subject of detailed investigation. More research should clarify these observations

First-principles modelling of molecular single-electron transistors

We present a first-principles method for calculating the charging energy of a molecular single-electron transistor operating in the Coulomb blockade regime. The properties of the molecule are modeled using density-functional theory, the environment is described by a continuum model, and the interaction between the molecule and the environment are included through the Poisson equation. The model is used to calculate the charge stability diagrams of a benzene and C$_{60}$ molecular single-electron transistor

Time-gated transillumination and reflection by biological tissues and tissuelike phantoms: simulation versus experiment

A numerical method is presented to solve exactly the time-dependent diffusion equation that describes light transport in turbid media. The simulation takes into account spatial variations of the scattering and absorption factors of the medium and the objects as well as random fluctuations of these quantities. The technique is employed to explore the possibility of locating millimeter-sized objects immersed in turbid media from time-gated measurements of the transmitted or reflected (near-infrared) light. The simulation results for tissue-like phantoms are compared with experimental transillumination data, and excellent agreement is found. Simulations of time-gated reflection experiments indicate that it may be possible to detect objects of 1-mm radius.

Multi‐Method Characterization of the High‐Entropy Spinel Oxide Mn0.2_{0.2}Co0.2_{0.2}Ni0.2_{0.2}Cu0.2_{0.2}Zn0.2_{0.2}Fe2_{2}O4_{4}: Entropy Evidence, Microstructure, and Magnetic Properties

The novel spinel Cu0.2Co0.2Mn0.2Ni0.2Zn0.2Fe2O4 comprising six transition metal cations was successfully prepared by a solution-combustion method followed by distinct thermal treatments. The entropic stabilization of this hexa-metallic material is demonstrated using in situ high temperature powder X-ray diffraction (PXRD) and directed removal of some of the constituting elements. Thorough evaluation of the PXRD data yields sizes of coherently scattering domains in the nanometre-range. Transmission electron microscopy based methods support this finding and indicate a homogeneous distribution of the elements in the samples. The combination of 57Fe Mössbauer spectroscopy with X-ray absorption near edge spectroscopy allowed determination of the cation occupancy on the tetrahedral and octahedral sites in the cubic spinel structure. Magnetic studies show long-range magnetic exchange interactions which are of ferri- or ferromagnetic nature with an exceptionally high saturation magnetization in the range of 92–108 emu g−1 at low temperature, but also an anomaly in the hysteresis of a sample calcined at 500 °C