228 research outputs found

    Measurement and Correlation of Phase Diagram Data of Hydrophilic Alcohols (1-Propanol/2-Propanol) + Salts (Na2SO4/(NH4)2SO4/NH4NO3) + Water Systems

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    Binodal data and the ternary liquid–liquid equilibria (LLE) was experimentally determined at 298.15 K for hydrophilic alcohols (1-propanol or 2-propanol) + salts (Na2SO4, (NH4)2SO4 or NH4NO3) + water systems. The salting-out and the phase-forming abilities of the salts and alcohols for the investigated ATPSs were discussed. The salting-out abilities of the investigated salts follow the order Na2SO4 > (NH4)2SO4 > NH4NO3, which can be indicated by the location of the binodal curves plotted in mass fraction, the effective excluded volume (EEV), the salting-out coefficient (Ks), the size of the ions, and the Gibbs free energy of hydration of the ions. The phase-separation ability of the studied hydrophilic alcohols was discussed on the basis of the dielectric constant and boiling point of the alcohols. The results show that the phase-separation capability of the system consists of different hydrophilic alcohols in the order: 1-propanol>2-propanol. Furthermore, the binodal curves of the studied systems were satisfactorily correlated by a nonlinear equation with four parameters. The reliability of the calculation method and the corresponding LLE data was successfully proved by the Othmer-Tobias equation and the Bancroft equation

    Enhancement of 2,3-butanediol production by Klebsiella pneumoniae PTCC 1290: Application of Taguchi methodology for process optimization

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    2,3-Butanediol production parameter optimization using Klebsiella pneumoniae PTCC 1290 was performed using the design of experiments available in the form of an orthogonal array and a software for automatic design and analysis of the experiments, both based on Taguchi protocol. Optimal levels of physical parameters and key media components namely temperature, pH, inoculum size, agitation, acetic acid and succinic acid were determined. 2,3-Butanediol production obtained from the 18 sets offermentation experiments performed with the selected factors and levels were further processed with Qualitek-4 software at bigger is better as quality character. The optimized conditions showed an enhanced 2,3-butanediol production of 35.8% (from 11.856 to 18.459 g l-1). The optimal combinations of factors obtained from the proposed design of experiments methodology was further validated by conducting fermentation experiments and the obtained results revealed an enhanced 2,3-butanediol production of 25.8%. Taguchi approach of design of experiments resulted in evaluating the main and interaction effects of the factors individually and in combinatio

    Liquid-Liquid Equilibria of Aqueous Two-phase Systems Containing Polyethylene Glycol 4000 and Two Different Salts of Ammonium

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    Abstract: The aim of this study was to survey on phase diagrams and Liquid-Liquid Equilibrium (LLE) data of the aqueous PEG 4000 -(NH 4 ) 2 HPO 4 and PEG 4000 -(NH 4 ) 2 SO 4 systems experimentally at 298.15 K. The salting-out effect was also discussed on the basis of the Gibbs free energy of hydration of ions. The experimental binodal data were satisfactorily correlated with the Merchuk equation. Tie line compositions were correlated using the Othmer-Tobias and Bancroft equations, and the parameters have also reported. Good agreement was obtained with the experimental data with the model equations

    Performance Evaluation of Bulk Liquid Membrane Technique on p-Nitrophenol Removal from Aqueous Solution

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    The transport of p-nitrophenol (PNP) through a bulk liquid membrane (BLM) was investigated to evaluate the effect of different experimental conditions on PNP partitioning behavior. The influence of solvent type, different salts in feed phase, the feed phase pH and PNP concentration in feed phase on transport efficiency of PNP through the BLM were studied. The results indicated that the highest removal efficiency of PNP was observed for 80 % xylene + 20 % toluene as liquid membrane, Na2SO4 as salt in feed phase, in the acidic feed phase and in 150 min. The effect of initial concentration of PNP on the efficiency of the separation PNP showed that the increase in initial concentration up to 350 ppm had positive effect, and more than 350 ppm had negative effect on the PNP removal behavior. Also, pertraction in BLM systems were described by a kinetic model of two consecutive irreversible first order chemical reactions. This work is licensed under a Creative Commons Attribution 4.0 International License

    Submerged Yeast Fermentation of Cheese Whey for Protein Production and Nutritional Profile Analysis

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    Abstract: In this study, ten whey samples collected from dairy industries in Rasht (Iran). Five lactose fermentative yeasts strains (designated A1 to A5) were isolated. Beta-galactosidase activity in the yeast strains showed that strain of Kluyveromyces marxianus designated as A2 had highest enzyme activity (up to 9012 EU/mL) and the most SCP production from whey with the yield of 12.68 g/L. Ammonium sulfate as nitrogen source had an increasing effect on biomass yield up to 30%. Crude fiber, lipids, carbohydrates and ash content of isolate dry cells were found to be 4.9, 7.23, 33.19 and 14.05%, respectively. The true protein content based on nitrogen fractionation procedure was 29.25%. The yeast biomass recovering by ultrafiltration reduced the total COD to 96.26% of its initial value in the raw whey

    FashionBrain Project: A Vision for Understanding Europe's Fashion Data Universe

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    A core business in the fashion industry is the understanding and prediction of customer needs and trends. Search engines and social networks are at the same time a fundamental bridge and a costly middleman between the customer’s purchase intention and the retailer. To better exploit Europe’s distinctive characteristics e.g., multiple languages, fashion and cultural differences, it is pivotal to reduce retailers’ dependence to search engines. This goal can be achieved by harnessing various data channels (manufacturers and distribution networks, online shops, large retailers, social media, market observers, call centers, press/magazines etc.) that retailers can leverage in order to gain more insight about potential buyers, and on the industry trends as a whole. This can enable the creation of novel on-line shopping experiences, the detection of influencers, and the prediction of upcoming fashion trends. In this paper, we provide an overview of the main research challenges and an analysis of the most promising technological solutions that we are investigating in the FashionBrain project

    All-sky Search for High-Energy Neutrinos from Gravitational Wave Event GW170104 with the ANTARES Neutrino Telescope

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    Advanced LIGO detected a significant gravitational wave signal (GW170104) originating from the coalescence of two black holes during the second observation run on January 4th^{\textrm{th}}, 2017. An all-sky high-energy neutrino follow-up search has been made using data from the ANTARES neutrino telescope, including both upgoing and downgoing events in two separate analyses. No neutrino candidates were found within ±500\pm500 s around the GW event time nor any time clustering of events over an extended time window of ±3\pm3 months. The non-detection is used to constrain isotropic-equivalent high-energy neutrino emission from GW170104 to less than 4×1054\sim4\times 10^{54} erg for a E2E^{-2} spectrum

    The ANTARES Collaboration: Contributions to ICRC 2017 Part I: Neutrino astronomy (diffuse fluxes and point sources)

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    Papers on neutrino astronomy (diffuse fluxes and point sources, prepared for the 35th International Cosmic Ray Conference (ICRC 2017, Busan, South Korea) by the ANTARES Collaboratio

    The ANTARES Collaboration: Contributions to ICRC 2017 Part III: Searches for dark matter and exotics, neutrino oscillations and detector calibration

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    Papers on the searches for dark matter and exotics, neutrino oscillations and detector calibration, prepared for the 35th International Cosmic Ray Conference (ICRC 2017, Busan, South Korea) by the ANTARES Collaboratio

    The ANTARES Collaboration: Contributions to ICRC 2017 Part II: The multi-messenger program

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    Papers on the ANTARES multi-messenger program, prepared for the 35th International Cosmic Ray Conference (ICRC 2017, Busan, South Korea) by the ANTARES Collaboratio
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