Split-beam echosounder observations of natural methane seep variability in the northern Gulf of Mexico

A method for positioning and characterizing plumes of bubbles from marine gas seeps using an 18 kHz scientific split-beam echo sounder (SBES) was developed and applied to acoustic observations of plumes of presumed methane gas bubbles originating at approximately 1400 m depth in the northern Gulf of Mexico. A total of 161 plume observations from 27 repeat surveys were grouped by proximity into 35 clusters of gas vent positions on the seafloor. Profiles of acoustic target strength per vertical meter of plume height were calculated with compensation for both the SBES beam pattern and the geometry of plume ensonification. These profiles were used as indicators of the relative fluxes and fates of gas bubbles acoustically observable at 18 kHz and showed significant variability between repeat observations at time intervals of 1 h–7.5 months. Active gas venting was observed during approximately one third of the survey passes at each cluster. While gas flux is not estimated directly in this study owing to lack of bubble size distribution data, repeat surveys at active seep sites showed variations in acoustic response that suggest relative changes in gas flux of up to 1 order of magnitude over time scales of hours. The minimum depths of acoustic plume observations at 18 kHz averaged 875 m and frequently coincided with increased amplitudes of acoustic returns in layers of biological scatterers, suggesting acoustic masking of the gas bubble plumes in these layers. Minimum plume depth estimates were limited by the SBES field of view in only five instances

Acoustic sensing of gas seeps in the deep ocean with split-beam echosounders

When in the form of free gas in the water column, methane seeps emanating from the seabed are strong acoustic targets that are often detectable from surface vessels using echo sounders.In addition to detecting that a seep is present at some location, it is also desirable to characterize the nature of the seep in terms of its morphology and flux rates. Here, we examine how much we can learn about seeps in the deep (\u3e 1000 m) northern Gulf of Mexico using narrow-band split-beam echo sounders operating at fixed frequencies (18 kHz and 38 kHz).Methane seeps in this region are deeper than the methane hydrate stability zone, implying that bubbles of free gas form hydrate rinds that allow them to rise further in the water column than they otherwise would. While this behavior may aid in the classification of gas types in the seep, it is possible that the presence of hydrate rinds may also change the acoustic response of the bubbles and thereby make flux rate estimates more challenging. These and other aspects of seep characterization will be discussed

Recovering full coherence in a qubit by measuring half of its environment

When quantum systems interact with the environment they lose their quantum properties, such as coherence. Quantum erasure makes it possible to restore coherence in a system by measuring its environment, but accessing the whole of it may be prohibitive: realistically one might have to concentrate only on an accessible subspace and neglect the rest. If that is the case, how good is quantum erasure? In this work we compute the largest coherence $\langle \mathcal C\rangle$ that we can expect to recover in a qubit, as a function of the dimension of the accessible and of the inaccessible subspaces of its environment. We then imagine the following game: we are given a uniformly random pure state of $n+1$ qubits and we are asked to compute the largest coherence that we can retrieve on one of them by optimally measuring a certain number $0\leq a\leq n$ of the others. We find a surprising effect around the value $a\approx n/2$: the recoverable coherence sharply transitions between 0 and 1, indicating that in order to restore full coherence on a qubit we need access to only half of its physical environment (or in terms of degrees of freedom to just the square root of them). Moreover, we find that the recoverable coherence becomes a typical property of the whole ensemble as $n$ grows.Comment: 4 pages, 5 figure

Corporate social responsibility:reviewed, rated, revised

Purpose: Critical literature review of CSR research in both general management and hospitality management literature. Discusses trends,commonalities, and inconsistencies to better understand the state of contemporary scholarship, and calls for a context-specific conceptual engagement with the phenomenon.Design/Methodology/Approach: Systematic literature review, noting and critiquing a general tendency towards measurement of financial and other internal benefit impacts.Findings: Hospitality management is well-positioned to evaluate the opportunities and challenges of CSR, yet research has uncritically adopted the instrumental emphasis on assessing processes, perceptions, and private profitability from the general management literature, without engaging on a contextually-specific and/or theoretical level.Research limitations: CSR research is abundant and therefore difficult to summarise in one article.The primarily Anglo-American and Asian contextual bias is reflected in this review.Practical implications: Consistently inconsistent results challenge the portability of financial impact studies.Studies are needed to re-evaluate the concept of CSR as it pertains to hospitality, and measure the effectiveness of CSR activities relative to context and resource availability.Social implications: Further research into the scope of CSR in hospitality management, with an emphasis on recuperating social value, would lead to widespread positive social implications.Originality/value: This critical review offers a new perspective on CSR in the hospitality literature and industry, calling for a reconsideration of the concept in context, and formulates a working definition

Controls on dissolved organic carbon quantity and chemical character in temperate rivers of North America

Understanding the processes controlling the transfer and chemical composition of dissolved organic carbon (DOC) in freshwater systems is crucial to understanding the carbon cycle and the effects of DOC on water quality. Previous studies have identified watershed‐scale controls on bulk DOC flux and concentration among small basins but fewer studies have explored controls among large basins or simultaneously considered the chemical composition of DOC. Because the chemical character of DOC drives riverine biogeochemical processes such as metabolism and photodegradation, accounting for chemical character in watershed‐scale studies will improve the way bulk DOC variability in rivers is interpreted. We analyzed DOC quantity and chemical character near the mouths of 17 large North American rivers, primarily between 2008 and 2010, and identified watershed characteristics that controlled variability. We quantified DOC chemical character using both specific ultraviolet absorbance at 254 nm (SUVA254) and XAD‐resin fractionation. Mean DOC concentration ranged from 2.1 to 47 mg C L−1 and mean SUVA254 ranged from 1.3 to 4.7 L mg C−1 m−1. We found a significant positive correlation between basin wetland cover and both bulk DOC concentration (R2 = 0.78; p \u3c 0.0001) and SUVA254 (R2 = 0.91; p \u3c 0.0001), while other land use characteristics were not correlated. The strong wetland relationship with bulk DOC concentration is similar to that found by others in small headwater catchments. However, two watersheds with extremely long surface water residence times, the Colorado and St. Lawrence, diverged from this wetland relationship. These results suggest that the role of riverine processes in altering the terrestrial DOC signal at the annual scale was minimal except in river systems with long surface water residence times. However, synoptic DOC sampling of both quantity and character throughout river networks will be needed to more rigorously test this finding. The inclusion of DOC chemical character will be vital to achieving a more complete understanding of bulk DOC dynamics in large river systems

Variability of Temperature and Salinity in the Middle Atlantic Bight and Gulf of Maine

Monitoring of the waters of the Middle Atlantic Bight and Gulf of Maine has been conducted by the MARMAP Ships of Opportunity Program since the early 1970's. Presented in this atlas are portrayals of the temporal and spatial patterns of surface and bottom temperature and surface salinity for these areas during the period 1978-1990. These patterns are shown in the form of time-space diagrams for single-year and multiyear (base period) time frames. Each base period figure shows thirteen-year (1978-1990) mean conditions, sample variance in the form of standard deviations of the measured values, and data locations. Each single-year figure displays annual conditions, sampling locations, and departures of annual conditions from the thirteen-year means, expressed as algebraic anomalies and standardized anomalies. (PDF file contains 112 pages.

Determination of rate constants for H-abstraction by 4-fluorophenyl radicals from fatty acid methyl esters by F-19 NMR

https://openriver.winona.edu/urc2018/1129/thumbnail.jp