670 research outputs found
Mapping of operating windows for methane and ethane pyrolysis in the pulsed compression reactor by experiments and modelling
The effect of inert gases (Xe, Ar, Ne, He) on decomposition reactions of N<sub>2</sub>O, CH<sub>4</sub> and CO<sub>2</sub> at high pressures
In a pulsed compression reactor (PCR) experiments were done with N2O (4%mol), CH4 (1%mol) and CO2 (2%mol) diluted in the inert gases Xe, Ar, Ne and He. The mixtures were compressed up to 250 bar, reaching temperatures of up to 4000 K. At equal temperature, pressure and volume, significant differences (up to 20%) were measured in the conversion of the three species in different noble gases. The measurements with N2O decomposition showed that the reaction is the fastest in the most heavy noble gas tested. The conversion decreased as the molar mass of the noble gas decreased. Likewise, methane pyrolysis was measured to be the fastest in xenon and slowed down in accordance with the mass of the inert molecule. A reverse trend was measured for the decomposition of CO2 to CO and Oâ‹…, which is explained by the dominant role of the reverse reaction. As a result, the CO2 data is also explained by conversion rates that are higher in heavier gases. This paper provides a first attempt to understand the observed influence of the molar mass of the inert bathing gas on the reaction rate in the high pressure domain. A theory is proposed based on a Newtonian description of reactant activation by the inert bathing gas.</p
The data cyclotron query processing scheme
Distributed database systems exploit static workload characteristics to steer data fragmentation and data allocation schemes. However, the grand challenge of distributed query processing is to come up with a self-organizing architecture, which exploits all resources to manage the hot data set, minimize query response time, and maximize throughput without global co-ordination.
In this paper, we introduce the Data Cyclotron architecture which addresses the challenges using turbulent data movement through a storage ring built from distributed main memory capitalizing modern remote-DMA facilities. Queries assigned to individual nodes interact with the Data Cyclotron by picking up data fragments continuously flowing around, i.e., the hot set.
Each data fragment carries a level of interest (LOI) metric, which represents the cumulative query interest as the fragment passes around the ring multiple times. A fragment with a LOI below a given threshold, inversely proportional to the ring load, is pulled o
On the intrinsic reaction rate of polyethylene pyrolysis and its interplay with mass transfer
Microalgae wet extraction using N-ethyl butylamine for fatty acid production
AbstractMicroalgae are considered a promising feedstock for the production of food ingredients, cosmetics, pharmaceutical products and biofuels. The energy intensity of drying and cell breaking of algae and solvent recovery afterwards hindered the route of algae biorefinery. In this work the influences of freeze drying and cell breaking to the extraction efficiency of crude lipid yield and fatty acid yield were investigated. Results showed that drying and cell breaking are not necessary for N-ethyl butylamine extraction, because good yields were obtained without. Crude lipid yield and fatty acid yield using N-ethyl butylamine were comparable with Bligh & Dyer extraction, making N-ethyl butylamine a candidate for further development of an energy efficient lipid extraction technology for non-broken microalgae
Multistage wet lipid extraction from fresh water stressed Neochloris oleoabundans slurry – Experiments and modelling
Algae are considered an important renewable feedstock for lipid extraction to produce biofuels. Algae strain Neochloris oleoabundans used in this research can yield a high lipid content under stressed conditions. N-ethyl butylamine (EBA) as a switchable solvent has previously shown outstanding performance on energy efficient lipid extraction from non-broken wet algae slurry. In this work, a model was developed that describes the equilibrium state of lipid extraction from fresh water (FW)-stressed Neochloris oleoabundans algae slurry using EBA as solvent. When assuming that the cell interior is almost completely filled with the solvent phase during extraction, the model estimated extraction yields showed good agreement with those obtained in experiments. The developed model can predict the amount of crude lipid being recovered from any stage of a multistage extraction process
Furfural to Cyclopentanone – a Search for Putative Oligomeric By-products
We report here on the reductive rearrangement of biomass-derived furfural to cyclopentanone, a promising non-fossil feedstock for fuels and chemicals. An underreported aspect of this reaction is the inevitable formation of heavy byproducts. To mitigate its formation, process condition such as, solvent, catalyst, temperature, acidity, and feed concentration were varied to unravel the chemistry and improve the reaction performance. Water medium was confirmed to play a crucial role, as organic solvents were unable to deliver cyclopentanone or heavy by products. Copper-based catalyst showed the highest selectivity for ring-rearrangement, reaching 50 mol % under the conditions investigated. The main factor influencing the yields of cyclopentanone (CPO), and promote oligomer formation, are the feed concentration and the pH, as high feed concentrations and high acidity facilitate the self-polymerization of furfuryl alcohol (FALC). This was confirmed by dedicated experiments using FALC and the hydroxypentenone intermediate as feed. The concentration challenge could be mitigated by slowly dosing the feed, which increased the desired product yields by 4–12 mol %. Nevertheless, most oligomers appeared to fall in the range of common liquid fuels and could be converted to diesel by hydrodeoxygenation.</p
Pyrolysis of plastic waste: effect of feedstock pretreatment and fate of contaminants
Please click Additional Files below to see the full abstrac
Peak Performance – Remote Memory Revisited
Many database systems share a need for large amounts of
fast storage. However, economies of scale limit the utility
of extending a single machine with an arbitrary amount
of memory. The recent broad availability of the zero-copy
data transfer protocol RDMA over low-latency and high
throughput network connections such as InfiniBand prompts
us to revisit the long-proposed usage of memory provided
by remote machines. In this paper, we present a solution
to make use of remote memory without manipulation of the
operating system, and investigate the impact on database
performance
- …