7,794 research outputs found
Local pressure-induced metallization of a semiconducting carbon nanotube in a crossed junction
The electronic and vibrational density of states of a semiconducting carbon
nanotube in a crossed junction was investigated by elastic and inelastic
scanning tunneling spectroscopy. The strong radial compression of the nanotube
at the junction induces local metallization spatially confined to a few nm. The
local electronic modifications are correlated with the observed changes in the
radial breathing and G-band phonon modes, which react very sensitively to local
mechanical deformation. In addition, the experiments reveal the crucial
contribution of the image charges to the contact potential at nanotube-metal
interfaces
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Towards the spatial resolution of metalloprotein charge states by detailed modeling of XFEL crystallographic diffraction.
Oxidation states of individual metal atoms within a metalloprotein can be assigned by examining X-ray absorption edges, which shift to higher energy for progressively more positive valence numbers. Indeed, X-ray crystallography is well suited for such a measurement, owing to its ability to spatially resolve the scattering contributions of individual metal atoms that have distinct electronic environments contributing to protein function. However, as the magnitude of the shift is quite small, about +2 eV per valence state for iron, it has only been possible to measure the effect when performed with monochromated X-ray sources at synchrotron facilities with energy resolutions in the range 2-3 × 10-4 (ΔE/E). This paper tests whether X-ray free-electron laser (XFEL) pulses, which have a broader bandpass (ΔE/E = 3 × 10-3) when used without a monochromator, might also be useful for such studies. The program nanoBragg is used to simulate serial femtosecond crystallography (SFX) diffraction images with sufficient granularity to model the XFEL spectrum, the crystal mosaicity and the wavelength-dependent anomalous scattering factors contributed by two differently charged iron centers in the 110-amino-acid protein, ferredoxin. Bayesian methods are then used to deduce, from the simulated data, the most likely X-ray absorption curves for each metal atom in the protein, which agree well with the curves chosen for the simulation. The data analysis relies critically on the ability to measure the incident spectrum for each pulse, and also on the nanoBragg simulator to predict the size, shape and intensity profile of Bragg spots based on an underlying physical model that includes the absorption curves, which are then modified to produce the best agreement with the simulated data. This inference methodology potentially enables the use of SFX diffraction for the study of metalloenzyme mechanisms and, in general, offers a more detailed approach to Bragg spot data reduction
Kondo effect of Co adatoms on Ag monolayers on noble metal surfaces
The Kondo temperature of single Co adatoms on monolayers of Ag on Cu
and Au(111) is determined using Scanning Tunneling Spectroscopy. of Co on
a single monolayer of Ag on either substrate is essentially the same as that of
Co on a homogenous Ag(111) crystal. This gives strong evidence that the
interaction of surface Kondo impurities with the substrate is very local in
nature. By comparing found for Co on Cu, Ag, and Au (111)-surfaces we
show that the energy scale of the many-electron Kondo state is insensitive to
the properties of surface states and to the energetic position of the projected
bulk band edges.Comment: 4 pages, 3 figure
Quantum Coherence of Image-Potential States
The quantum dynamics of the two-dimensional image-potential states in front
of the Cu(100) surface is measured by scanning tunneling microscopy (STM) and
spectroscopy (STS). The dispersion relation and the momentum resolved
phase-relaxation time of the first image-potential state are determined from
the quantum interference patterns in the local density of states (LDOS) at step
edges. It is demonstrated that the tip-induced Stark shift does not affect the
motion of the electrons parallel to the surface.Comment: Submitted to Phys. Rev. Lett., 4 pages, 4 figures; corrected typos,
minor change
Role of pseudospin in quasiparticle interferences in epitaxial graphene probed by high-resolution scanning tunneling microscopy
Pseudospin, an additional degree of freedom related to the honeycomb
structure of graphene, is responsible of many of the outstanding electronic
properties found in this material. This article provides a clear understanding
of how such pseudospin impacts the quasiparticle interferences of monolayer
(ML) and bilayer (BL) graphene measured by low temperature scanning tunneling
microscopy and spectroscopy. We have used this technique to map, with very high
energy and space resolution, the spatial modulations of the local density of
states of ML and BL graphene epitaxialy grown on SiC(0001), in presence of
native disorder. We perform a Fourier transform analysis of such modulations
including wavevectors up to unit-vectors of the reciprocal lattice. Our data
demonstrate that the quasiparticle interferences associated to some particular
scattering processes are suppressed in ML graphene, but not in BL graphene.
Most importantly, interferences with 2qF wavevector associated to intravalley
backscattering are not measured in ML graphene, even on the images with highest
resolution. In order to clarify the role of the pseudospin on the quasiparticle
interferences, we use a simple model which nicely captures the main features
observed on our data. The model unambiguously shows that graphene's pseudospin
is responsible for such suppression of quasiparticle interferences features in
ML graphene, in particular for those with 2qF wavevector. It also confirms
scanning tunneling microscopy as a unique technique to probe the pseudospin in
graphene samples in real space with nanometer precision. Finally, we show that
such observations are robust with energy and obtain with great accuracy the
dispersion of the \pi-bands for both ML and BL graphene in the vicinity of the
Fermi level, extracting their main tight binding parameters
STABILITY OF POLYNOMIALS UNDER CORRELATED COEFFICIENT PERTURBATIONS.
The robust stability of polynomials with respect to real parameter variations is investigated. The coefficients of the polynomial are assumed to be linear functions of several real parameters. An algorithm to calculate the maximum allowable variations of the parameters so the roots still remain in prescribed regions of the complex plane is presented. Examples are given to illustrate the method
Ag-coverage-dependent symmetry of the electronic states of the Pt(111)-Ag-Bi interface: The ARPES view of a structural transition
We studied by angle-resolved photoelectron spectroscopy the strain-related
structural transition from a pseudomorphic monolayer (ML) to a striped
incommensurate phase in an Ag thin film grown on Pt(111). We exploited the
surfactant properties of Bi to grow ordered Pt(111)-xMLAg-Bi trilayers with 0 <
x < 5 ML, and monitored the dispersion of the Bi-derived interface states to
probe the structure of the underlying Ag film. We find that their symmetry
changes from threefold to sixfold and back to threefold in the Ag coverage
range studied. Together with previous scanning tunneling microscopy and
photoelectron diffraction data, these results provide a consistent microscopic
description of the coverage-dependent structural transition.Comment: 10 pages, 9 figure
Intercalation of graphene on SiC(0001) via ion-implantation
Electronic devices based on graphene technology are catching on rapidly and
the ability to engineer graphene properties at the nanoscale is becoming, more
than ever, indispensable. Here, we present a new procedure of graphene
functionalization on SiC(0001) that paves the way towards the fabrication of
complex graphene electronic chips. The procedure resides on the well-known
ion-implantation technique. The efficiency of the working principle is
demonstrated by the intercalation of the epitaxial graphene layer on SiC(0001)
with Bi atoms, which was not possible following standard procedures. Our
results put forward the ion-beam lithography to nanostructure and functionalize
desired graphene chips
Ultrafast photodoping and effective Fermi-Dirac distribution of the Dirac particles in Bi2Se3
We exploit time- and angle- resolved photoemission spectroscopy to determine
the evolution of the out-of-equilibrium electronic structure of the topological
insulator Bi2Se. The response of the Fermi-Dirac distribution to ultrashort IR
laser pulses has been studied by modelling the dynamics of the hot electrons
after optical excitation. We disentangle a large increase of the effective
temperature T* from a shift of the chemical potential mu*, which is consequence
of the ultrafast photodoping of the conduction band. The relaxation dynamics of
T* and mu* are k-independent and these two quantities uniquely define the
evolution of the excited charge population. We observe that the energy
dependence of the non-equilibrium charge population is solely determined by the
analytical form of the effective Fermi-Dirac distribution.Comment: 5 Pages, 3 Figure
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