3,497 research outputs found
Dynamics from diffraction
A model-independent approach for the extraction of detailed
lattice dynamical information from neutron powder diffraction data is described. The technique is based on a statistical analysis of atomistic configurations generated using reverse Monte Carlo structural refinement.
Phonon dispersion curves extracted in this way are shown to
reproduce many of the important features found in those determined independently using neutron triple-axis spectroscopy. The extent to which diffraction data are sensitive to lattice dynamics is explored in a
range of materials. The prospect that such detailed dynamical information might be accessible using comparatively facile experiments such as neutron
powder diffraction is incredibly valuable when studying systems for which established spectroscopic methods are prohibitive or
inappropriate
Do the UK government's new Quality and Outcomes Framework (QOF) scores adequately measure primary care performance? A cross-sectional survey of routine healthcare data
BACKGROUND
General practitioners' remuneration is now linked directly to the scores attained in the Quality and Outcomes Framework (QOF). The success of this approach depends in part on designing a robust and clinically meaningful set of indicators. The aim of this study was to assess the extent to which measures of health observed in practice populations are correlated with their QOF scores, after accounting for the established associations between health outcomes and socio-demographics.
METHODS
QOF data for the period April 2004 to March 2005 were obtained for all general practices in two English Primary Care Trusts. These data were linked to data for emergency hospital admissions (for asthma, cancer, chronic obstructive pulmonary disease, coronary hear disease, diabetes, stroke and all other conditions) and all cause mortality for the period September 2004 to August 2005. Multilevel logistic regression models explored the association between health outcomes (hospital admission and death) and practice QOF scores (clinical, additional services and organisational domains), age, sex and socio-economic deprivation.
RESULTS
Higher clinical domain scores were generally associated with lower admission rates and this was significant for cancer and other conditions in PCT 2. Higher scores in the additional services domain were associated with higher admission rates, significantly so for asthma, CHD, stroke and other conditions in PCT 1 and cancer in PCT 2. Little association was observed between the organisational domain scores and admissions. The relationship between the QOF variables and mortality was less clear. Being female was associated with fewer admissions for cancer and CHD and lower mortality rates. Increasing age was mainly associated with an increased number of events. Increasing deprivation was associated with higher admission rates for all conditions and with higher mortality rates.
CONCLUSION
The associations between QOF scores and emergency admissions and mortality were small and inconsistent, whilst the impact of socio-economic deprivation on the outcomes was much stronger. These results have implications for the use of target-based remuneration of general practitioners and emphasise the need to tackle inequalities and improve the health of disadvantaged groups and the population as a whole
Bifurcated polarization rotation in bismuth-based piezoelectrics
ABO3 perovskite-type solid solutions display a large variety of structural and physical properties, which can be tuned by chemical composition or external parameters such as temperature, pressure, strain, electric, or magnetic fields. Some solid solutions show remarkably enhanced physical properties including colossal magnetoresistance or giant piezoelectricity. It has been recognized that structural distortions, competing on the local level, are key to understanding and tuning these remarkable properties, yet, it remains a challenge to experimentally observe such local structural details. Here, from neutron pair-distribution analysis, a temperature-dependent 3D atomic-level model of the lead-free piezoelectric perovskite Na0.5Bi0.5TiO3 (NBT) is reported. The statistical analysis of this model shows how local distortions compete, how this competition develops with temperature, and, in particular, how different polar displacements of Bi3+ cations coexist as a bifurcated polarization, highlighting the interest of Bi-based materials in the search for new lead-free piezoelectrics
Parabolic groups acting on one-dimensional compact spaces
Given a class of compact spaces, we ask which groups can be maximal parabolic
subgroups of a relatively hyperbolic group whose boundary is in the class. We
investigate the class of 1-dimensional connected boundaries. We get that any
non-torsion infinite f.g. group is a maximal parabolic subgroup of some
relatively hyperbolic group with connected one-dimensional boundary without
global cut point. For boundaries homeomorphic to a Sierpinski carpet or a
2-sphere, the only maximal parabolic subgroups allowed are virtual surface
groups (hyperbolic, or virtually ).Comment: 10 pages. Added a precision on local connectedness for Lemma 2.3,
thanks to B. Bowditc
Orbital Dimer Model for Spin-Glass State in YMoO
The formation of a spin glass usually requires both structural disorder and
frustrated magnetic interactions. Consequently, the origin of spin-glass
behaviour in YMoO in which magnetic Mo ions occupy a
frustrated pyrochlore lattice with minimal compositional disorder has been
a longstanding question. Here, we use neutron and X-ray pair-distribution
function (PDF) analysis to develop a disorder model that resolves apparent
incompatibilities between previously-reported PDF, EXAFS and NMR studies and
provides a new and physical mechanism for spin-glass formation. We show that
Mo ions displace according to a local "2-in/2-out" rule on each Mo
tetrahedron, driven by orbital dimerisation of Jahn-Teller active Mo
ions. Long-range orbital order is prevented by the macroscopic degeneracy of
dimer coverings permitted by the pyrochlore lattice. Cooperative O
displacements yield a distribution of MoOMo angles, which in turn
introduces disorder into magnetic interactions. Our study demonstrates
experimentally how frustration of atomic displacements can assume the role of
compositional disorder in driving a spin-glass transition.Comment: 6 pages, 3 figure
Eradication of poliomyelitis in South Africa
An international campaign under the leadership of the World Health Organisation is underway to eradicate polio from the world by the year 2000. South Africa may already be free of polio. However, to ensure eradication we need to move from a polio control programme to a polio eradication programme. This necessitates the institution of a surveillance programme for acute flaccid paralysis (AFP) and improvement of the delivery of polio vaccine. All children with AFP (including those with suspected GuillainBarre syndrome) should be investigated with stool culture to exclude polio. Primary care services need strengthening so that oral polio vaccine coverage greater than 90% is achieved in all regions by all authorities. Outbreak response activities need to be developed. Consideration needs to be given to national immunisation days and mopping-up activities
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