Germylene complexes of tungsten pentacarbonyls W(CO)5{double bond, long}GeCl2 and W(CO)5{double bond, long}Ge{double bond, long}W(CO)5: Electrochemical synthesis and quantum-chemical computations

Convenient synthetic route to prepare the germylene complexes of tungsten pentacarbonyls, W(CO)5{double bond, long}GeCl2 and W(CO)5{double bond, long}Ge{double bond, long}W(CO)5, electrochemically is developed. Combined quantum-chemical/IR spectroscopic approach is used for identification of the synthesized compounds. Good agreement between theoretical and experimental spectra can be regarded as one of the proofs of their supposed structures. © 2007 Elsevier B.V. All rights reserved

European consensus statement on essential colposcopy

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IR and UV study of reversible water-induced structural transformations of poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) and poly(cobalt 1,1′-ferrocenediyl-bis(H-phosphinate))

© 2018 Elsevier B.V. Recently new flexible and hydrolytically stable metal-organic framework [M(H2O)2(Fc(PHOO)2)·2H2O]n, M = Co has been synthesized by the use of synthetic technique, described earlier for M = Mn [1]. The heating of both complexes leads to elimination of water molecules and in the case of Co complex is accompanied by change of its color from orange to dark blue. The corresponding structural changes are reversible and are reflected in vibrational and electronic absorption spectra. Analysis of IR, Raman and UV–vis spectra of complexes shows the same structures of Mn and Co complexes before and after heating and suggests that both Mn and Co coordination polyhedra undergo reversible changes under heating from octahedral to tetrahedral form with ferrocene part remaining unchanged

Unexpected ligand effect on the catalytic reaction rate acceleration for hydrogen production using biomimetic nickel electrocatalysts with 1,5-diaza-3,7-diphosphacyclooctanes

© 2015 Elsevier B.V. All rights reserved. The two new nickel complexes [Ni(PR2NPh(CH)Ph2)2]2+ (where R = Ph or o-Py) with cyclic 1,5-diaza-3,7-diphosphacyclooctane ligands have been synthesized. All complexes are effective electrocatalysts for hydrogen production using [(DMF)H]+ as proton source in acetonitrile. The bulky benzhydryl substituent at nitrogen atom leads to higher catalytic activity comparison to benzyl. The introduction o-Py substituents at phosphorus as additional basic center is caused by the changing of voltage-current picture and significantly catalytic current enhancement. TOFs being 100 and 15200 s-1 for R = Ph and o-Py, respectively

Seeding time on irrigated rice

Em seis experimentos de campo, semeados em outubro, novembro e dezembro de 1978 e 1979, foram estudados os efeitos da brusone (Pyricularia oryzae Cav.) e de temperatura baixas (frio) sobre a produção das cultivares de arroz (Oryza sativa L.) Bluebelle, EEA 406, IRGA 408, Dawn e Caloro. Os resultados permitiram concluir que a época de semeadura influi na produtividade do arroz e que a produção das épocas tardias (dezembro) é mais prejudicada pelos danos da brusone e do frio, simultaneamente. Determinou-se, também, que as cultivares estudadas apresentam comportamentos diversos quanto à sua sensibilidade a esses fatores, e que a semeadura em épocas precoces - outubro e novembro - oferece à cultura maiores possibilidades de escapar desses danos. A brusone foi mais danosa sobre as cultivares Caloro e EEA 406, enquanto que o frio prejudicou mais a produção de IRGA 408 e Dawn. A cultivar Bluebelle, de ciclo precoce, sofreu os efeitos de ambos os fatores de maneira mais suave e apresentou maiores chances de escape. Não foram obtidas correlações satisfatórias entre os danos da brusone e as condições meteorológicas.At six field experiments, seeded in October, November and December of 1978 and 1979, the rice blast disease (Pyricularia oryzae Cav.) and low temperature effects on the grain yield of the rice cultivars Bluebelle, EEA 406, IRGA 408, Dawn, and Caloro, were studied. The results showed that seeding time had effect on rice yield, and in the later seeding times, in December the yield was reduced simultaneously by the rice blast disease and cold. It was also determinated that the rice cultivars show differences on susceptibility to these factors, and that the early seeding, at October and November, gives the cultivation more chances for the rice crop lo escape from both blast and cold damages. The rice blast disease attack was more severe on the rice cultivars Caloro and EEA 406. On the other hand, the low temperatures injured more the rice cultivars IRGA 408 and Dawn. The Bluebelle, a short growth duration variety has more chances lo escape from these losses. No satisfactory correlation was obtained between the rice blast disease losses and the metheorological conditions

The main types of mental information processing: a systematic structural method

The article describes the main types of mental information processing in the context of a systematic structural method. The author analyses the semantic theories of information. The author reviews the mechanisms of information processing and its qualitative properties. The article describes the mechanism of textual presupposition accommodation.El artículo en el marco de un enfoque sistémico-estructural describe las principales direcciones del procesamiento de la información mental. El artículo analiza las teorías semánticas de la información, examina los mecanismos de procesamiento de la información y sus características cualitativas, describe los mecanismos para restaurar la presuposición del texto

Germylene complexes of tungsten pentacarbonyls W(CO)5{double bond, long}GeCl2 and W(CO)5{double bond, long}Ge{double bond, long}W(CO)5: Electrochemical synthesis and quantum-chemical computations

Convenient synthetic route to prepare the germylene complexes of tungsten pentacarbonyls, W(CO)5{double bond, long}GeCl2 and W(CO)5{double bond, long}Ge{double bond, long}W(CO)5, electrochemically is developed. Combined quantum-chemical/IR spectroscopic approach is used for identification of the synthesized compounds. Good agreement between theoretical and experimental spectra can be regarded as one of the proofs of their supposed structures. © 2007 Elsevier B.V. All rights reserved

National Axiology in the Treatise of SA Yesenin "The Keys of Mary" Study on the Mental Features of the Russian Person

The article tells about the national axiology, codes and archetypes of Russian culture which were highlighted in the 1918 treatise by the poet Sergei Yesenin. Much attention is paid to the archetype of the ship / boat, which is dominant for Russian culture. This archetype is found in folklore, in folk drama, in funeral rites. The image of the ship is relevant to Russian literature. In this regard, parallels are drawn with the works of Lermontov and Voloshin. Russian embroidery turns out to be typologically significant; since a ship drawing, an ornament is observed in it. The folkloristic commentary on the text of the treatise and the reconstruction of a large cultural space allow us to show the great importance of ornament, embroidery for Yesenin's poetics and the Russian national image of the world as a whole