Large Re-emergence of Anthropogenic Carbon Into the Ocean’s Surface Mixed Layer Sustained by the Ocean’s Overturning Circulation

We evaluate the output from a widely used ocean carbon cycle model to identify the subduction and obduction (re-emergence) rates of anthropogenic carbon (Cant) for climatological conditions during the World Ocean Circulation Experiment (WOCE) era in 1995 using a new set of Lagrangian diagnostic tools. The principal scientific value of the Lagrangian diagnostics is in providing a new means to connect Cant re-emergence pathways to the relatively rapid renewal timescales of mode waters through the overturning circulation. Our main finding is that for this model with 2.04 PgC/yr of uptake of Cant via gas exchange, the subduction and obduction rates across the base of the mixed layer (MLbase) are 4.96 PgC/yr and 4.50 PgC/yr, respectively, which are twice as large as the gas exchange at the surface. Given that there is net accumulation of 0.17 PgC/yr in the mixed layer itself, this implies the residual downward Cant transport of 1.40 PgC/yr across the MLbase is associated with diffusion. Importantly, the net patterns for subduction and obduction transports of Cant mirror the large-scale patterns for transport of water volume, thereby illustrating the processes controlling Cant uptake. Although the net transfer across the MLbase by compensating subduction and obduction is relatively smaller than the diffusion, localized pattern of Cant subduction and obduction implies significant regional impacts. The median timescale for re-emergence of obducting particles is short (less than 10 years), indicating that re-emergence should contribute to limiting future carbon uptake through its contribution to perturbing the Revelle factor for surface waters

Ocean Acidification from Below in the Tropical Pacific

Identifying ocean acidification and its controlling mechanisms is an important priority within the broader question of understanding how sustained anthropogenic CO2 emissions are harming the health of the ocean. Through extensive analysis of observational data products for ocean inorganic carbon, here we quantify the rate at which acidification is proceeding in the western tropical Pacific Warm Pool, revealing ‐0.0013 ±0.0001 yr‐1 for pH and ‐0.0083±0.0007 yr‐1 for the saturation index of aragonite for the years 1985‐2016. However, the mean rate of total dissolved inorganic carbon increase (+0.81 ±0.06 μmol kg‐1 yr‐1) sustaining acidification was ~20% slower than what would be expected if it were simply controlled by the rate of atmospheric CO2 increase and transmitted through local air‐sea CO2 equilibration. Joint Lagrangian and Eulerian model diagnostics indicate that the acidification of the Warm Pool occurs primarily through the anthropogenic CO2 that invades the ocean in the extra‐tropics, is transported to the tropics through the thermocline shallow overturning circulation, and then re‐emerges into surface waters within the tropics through the Equatorial Undercurrent from below. An interior residence time of several years to decades, acting in conjunction with the accelerating CO2 growth in the atmosphere, can be expected to contribute to modulating the rate of Warm Pool acidification. Key Points Progress of ocean acidification in the western tropical Pacific Warm Pool was identified using the data of oceanic CO2 measurements The rate of oceanic CO2 increase here was ~20% lower than that expected from the growth rate of the mixing ratio of CO2 in the atmosphere Inter‐gyre exchange of anthropogenic CO2 within the thermocline predominantly controls the rate of acidification in this regio