140 research outputs found
High pressure torsion of nickel powders obtained by electrodeposition
A new synthesis route for the production of bulk nanostructured materials is presented.
Fine Ni powder was made by selected appropriate electrolysis conditions. A
compact material with an average grain size below 40 nm was obtained by subsequent
cold pressing. Then, using the high pressure torsion (HPT) deformation technique dense
bulk nanocrystalline Ni was achieved. The detailed structural investigations of the asprepared
and HPT deformed Ni powder, including X-ray diffraction (XRD) and transmission
electron microscopy (TEM), reveal in both cases the presence of a face centered
cubic (FCC) phase without presence of any oxides. Coherently scattering domain size
measurements by XRD show a value of 24 nm for the as-deposited powder and an even
smaller value of 13.5 nm after HPT deformation. In addition, optical emission spectroscopy
was employed to determine the impurity content of the obtained nanostructured
material, showing a relatively low content of 0.9 % carbon and oxygen. The microhardness
increased after deformation from (1.5 ± 0.08) GPa for the as-deposited Ni powder
to (6.6 ± 0.2) GPa for the HPT deformed Ni powder.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2061
Nanocrystalline Zr3Al Made through Amorphization by Repeated Cold Rolling and Followed by Crystallization
The intermetallic compound Zr3Al is severely deformed by the method of
repeated cold rolling. By X-ray diffraction it is shown that this leads to
amorphization. TEM investigations reveal that a homogeneously distributed
debris of very small nanocrystals is present in the amorphous matrix that is
not resolved by X-ray diffraction. After heating to 773 K, the crystallization
of the amorphous structure leads to a fully nanocrystalline structure of small
grains (10 - 20 nm in diameter) of the non-equilibrium Zr2Al phase. It is
concluded that the debris retained in the amorphous phase acts as nuclei. After
heating to 973 K the grains grow to about 100 nm in diameter and the compound
Zr3Al starts to form, that is corresponding to the alloy composition
Electrochemical approaches to design materials for potential sensing and energy related applications
Extended conference abstrac
Structure and Strength of Dislocation Junctions: An Atomic Level Analysis
The quasicontinuum method is used to simulate three-dimensional
Lomer-Cottrell junctions both in the absence and in the presence of an applied
stress. The simulations show that this type of junction is destroyed by an
unzipping mechanism in which the dislocations that form the junction are
gradually pulled apart along the junction segment. The calculated critical
stress needed for breaking the junction is comparable to that predicted by line
tension models. The simulations also demonstrate a strong influence of the
initial dislocation line directions on the breaking mechanism, an effect that
is neglected in the macroscopic treatment of the hardening effect of junctions.Comment: 4 pages, 3 figure
Electrochemical approaches in synthesis of high surface area materials
It is the aim of our work to carry out fundamental studies on designing and synthesizing high surface area functionalized foam and ordered structures for their potential sensing and energy related applications. We combine electrochemical synthesis with structural studies on different length scales including transmission electron microscopy. Templates are directly grown by electrodeposition, either by hydrogen bubble formation or by utilizing of ordered structures formed by anodic electrochemical oxidation. [1-3] We employed an elegant approach to obtain open, foam deposits of Ni and Ni alloys, by using electrodeposition at high current densities, to promote hydrogen evolution and bubble templating (cf. Fig.1). [1] In the next step, the high surface area of such materials was funtionalized by Pd utilizing galvanic displacement reaction. Electrochemical testing of the obtained open foam deposits shows promissing catalytical activity for hydrogen evolution in alkaline environments, as well as methanol and ethanol oxidation. In the case of fabrication of nanodendritic Ag simultaneously grown with porous anodic aluminium oxide we accomplished well anchored dendritic Ag nanostructures [2] of long-term stability [3].
1. L. D. Rafailović, C. Gammer, C. Rentenberger, T. Trišović, C. Kleber, H. P. Karnthaler, Nano Energy, 2 (2012) 523 https://doi.org/10.1016/j.nanoen.2012.12.004
2. L.D. Rafailovic, C. Gammer, C. Rentenberger, T. Trisovic, C. Kleber, H.P. Karnthaler, Adv. Mater. 27 (2015) 6438 https://doi.org/10.1002/adma.201502451
3. L.D. Rafailovic, C. Gammer, J. Srajer, T. Trisovic, J. Rahel, H.P. Karnthaler; RSC Adv., 6 (2016) 33348, https://doi.org/10.1039/c5ra26632
Mesoscopic Analysis of Structure and Strength of Dislocation Junctions in FCC Metals
We develop a finite element based dislocation dynamics model to simulate the
structure and strength of dislocation junctions in FCC crystals. The model is
based on anisotropic elasticity theory supplemented by the explicit inclusion
of the separation of perfect dislocations into partial dislocations bounding a
stacking fault. We demonstrate that the model reproduces in precise detail the
structure of the Lomer-Cottrell lock already obtained from atomistic
simulations. In light of this success, we also examine the strength of
junctions culminating in a stress-strength diagram which is the locus of points
in stress space corresponding to dissolution of the junction.Comment: 9 Pages + 4 Figure
Non-canonical metabolic pathways in the malaria parasite detected by isotope-tracing metabolomics
The malaria parasite, Plasmodium falciparum, proliferates rapidly in human erythrocytes by actively scavenging multiple carbon sources and essential nutrients from its host cell. However, a global overview of the metabolic capacity of intraerythrocytic stages is missing. Using multiple
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