Polyimides containing oxyethylene units. Part 4: Polymerization of dianhydrides containing ether linkages

The development of new composite resins for various aerospace applications is attempted. Although it is highly desirable that these polymers be soluble in order to facilitate processing, they must display considerable solvent-resistance in use. A recent approach has involved the synthesis of a new series of polyimides containing flexible linkages. The polymers were prepared by the polymerization of aromatic dianhydrides with diamines containing oxyethylene linkages. For example, the polymerization of 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) with 1,2-bis(4-aminophenoxy)ethane (1a) and bis2-(4-aminophenoxy)ethylether (lb), afforded highly crystalline polyimides that were completely insoluble. However, a polyimide that was amorphous and soluble was obtained from the polymerization of BTDA and an isomer of lb, i.e., bis2-(3-aminophenoxy)ethyl ether (4b). In an attempt to obtain a soluble, amorphous polyimide that could be annealed into a crysalline state, block copolymers of 1b and 4b and BTDA were prepared. Copolymers containing less than 20 weight % 1b were soluble in organic solvents. However, these polymers did not crystallize when heated above their Tg's. Copolymers containing higher levels of 1b were semicrystalline and insoluble. The polymerization of the diamines containing oxyethylene linkages with 4,4'-oxydiphthalic anhydride (ODPA) and a new dianhydride, i.e., 4,4'-oxyethyleneoxyethyleneoxydiphthalic anhydride (OEDA) was investigated. It was postulated that the use of these more flexible dianhydrides would result in more processable polyimides

Warm terrestrial planet with half the mass of Venus transiting a nearby star

The advent of a new generation of radial velocity instruments has allowed us to break the one Earth-mass barrier. We report a new milestone in this context with the detection of the lowest-mass planet measured so far using radial velocities: L 98-59 b, a rocky planet with half the mass of Venus. It is part of a system composed of three known transiting terrestrial planets (planets b to d). We announce the discovery of a fourth nontransiting planet with a minimum mass of 3.06_{-0.37}^{+0.33} MEarth and an orbital period of 12.796_{-0.019}^{+0.020} days and report indications for the presence of a fifth nontransiting terrestrial planet. With a minimum mass of 2.46_{-0.82}^{+0.66} MEarth and an orbital period 23.15_{-0.17}^{+0.60} days, this planet, if confirmed, would sit in the middle of the habitable zone of the L 98-59 system. L 98-59 is a bright M dwarf located 10.6 pc away. Positioned at the border of the continuous viewing zone of the James Webb Space Telescope, this system is destined to become a corner stone for comparative exoplanetology of terrestrial planets. The three transiting planets have transmission spectrum metrics ranging from 49 to 255, which makes them prime targets for an atmospheric characterization with the James Webb Space Telescope, the Hubble Space Telescope, Ariel, or ground-based facilities such as NIRPS or ESPRESSO. With an equilibrium temperature ranging from 416 to 627 K, they offer a unique opportunity to study the diversity of warm terrestrial planets. L 98-59 b and c have densities of 3.6_{-1.5}^{+1.4} and 4.57_{-0.85}^{+0.77} this http URL^{-3}, respectively, and have very similar bulk compositions with a small iron core that represents only 12 to 14 % of the total mass, and a small amount of water. However, with a density of 2.95_{-0.51}^{+0.79} this http URL^{-3} and despite a similar core mass fraction, up to 30 % of the mass of L 98-59 d might be water

Optical and near-infrared stellar activity characterization of the early M dwarf Gl~205 with SOPHIE and SPIRou

The stellar activity of M dwarfs is the main limitation for discovering and characterizing exoplanets orbiting them since it induces quasi-periodic RV variations. We aim to characterize the magnetic field and stellar activity of the early, moderately active, M dwarf Gl205 in the optical and nIR domains. We obtained high-precision quasi-simultaneous spectra in the optical and nIR with the SOPHIE spectrograph and SPIRou spectropolarimeter between 2019 and 2022. We computed the RVs from both instruments and the SPIRou Stokes V profiles. We used ZDI to map the large-scale magnetic field over the time span of the observations. We studied the temporal behavior of optical and nIR RVs and activity indicators with the Lomb-Scargle periodogram and a quasi-periodic GP regression. In the nIR, we studied the equivalent width of Al I, Ti I, K I, Fe I, and He I. We modeled the activity-induced RV jitter using a multi-dimensional GP regression with activity indicators as ancillary time series. The optical and nIR RVs have similar scatter but nIR shows a more complex temporal evolution. We observe an evolution of the magnetic field topology from a poloidal dipolar field in 2019 to a dominantly toroidal field in 2022. We measured a stellar rotation period of Prot=34.4$\pm$0.5 d in the longitudinal magnetic field. Using ZDI we measure the amount of latitudinal differential rotation (DR) shearing the stellar surface yielding rotation periods of Peq=32.0$\pm$1.8 d at the stellar equator and Ppol=45.5$\pm$0.3 d at the poles. We observed inconsistencies in the activity indicators' periodicities that could be explained by these DR values. The multi-dimensional GP modeling yields an RMS of the RV residuals down to the noise level of 3 m/s for both instruments, using as ancillary time series H$\alpha$ and the BIS in the optical, and the FWHM in the nIR.Comment: 41 pages, 24 figures. Accepted for publication in A&A. Improved quality of figures and reduced size of Appendi

Metallicities in M dwarfs: Investigating different determination techniques

Deriving metallicities for solar-like stars follows well-established methods, but for cooler stars such as M dwarfs, the determination is much more complicated due to forests of molecular lines that are present. Several methods have been developed in recent years to determine accurate stellar parameters for these cool stars (Teff ≲ 4000 K). However, significant differences can be found at times when comparing metallicities for the same star derived using different methods. In this work, we determine the effective temperatures, surface gravities, and metallicities of 18 well-studied M dwarfs observed with the CARMENES high-resolution spectrograph following different approaches, including synthetic spectral fitting, analysis of pseudo-equivalent widths, and machine learning. We analyzed the discrepancies in the derived stellar parameters, including metallicity, in several analysis runs. Our goal is to minimize these discrepancies and find stellar parameters that are more consistent with the literature values. We attempted to achieve this consistency by standardizing the most commonly used components, such as wavelength ranges, synthetic model spectra, continuum normalization methods, and stellar parameters. We conclude that although such modifications work quite well for hotter main-sequence stars, they do not improve the consistency in stellar parameters for M dwarfs, leading to mean deviations of around 50–200 K in temperature and 0.1–0.3 dex in metallicity. In particular, M dwarfs are much more complex and a standardization of the aforementioned components cannot be considered as a straightforward recipe for bringing consistency to the derived parameters. Further in-depth investigations of the employed methods would be necessary in order to identify and correct for the discrepancies that remain

An unusually low-density super-Earth transiting the bright early-type M-dwarf GJ 1018 (TOI-244)

Small planets located at the lower mode of the bimodal radius distribution are generally assumed to be composed of iron and silicates in a proportion similar to that of the Earth. However, recent discoveries are revealing a new group of low-density planets that are inconsistent with that description. We intend to confirm and characterize the TESS planet candidate TOI-244.01, which orbits the bright ($K$ = 7.97 mag), nearby ($d$ = 22 pc), and early-type (M2.5 V) M-dwarf star GJ 1018 with an orbital period of 7.4 days. We used Markov Chain Monte Carlo methods to model 57 precise radial velocity measurements acquired by the ESPRESSO spectrograph together with TESS photometry and complementary HARPS data. We find TOI-244 b to be a super-Earth with a radius of $R_{\rm p}$ = 1.52 $\pm$ 0.12 $\rm R_{\oplus}$ and a mass of $M_{\rm p}$ = 2.68 $\pm$ 0.30 $\rm M_{\oplus}$. These values correspond to a density of $\rho$ = 4.2 $\pm$ 1.1 $\rm g \cdot cm^{-3}$, which is below what would be expected for an Earth-like composition. We find that atmospheric loss processes may have been efficient to remove a potential primordial hydrogen envelope, but high mean molecular weight volatiles such as water could have been retained. Our internal structure modeling suggests that TOI-244 b has a $479^{+128}_{-96}$ km thick hydrosphere over a 1.17 $\pm$ 0.09 $\rm R_{\oplus}$ solid structure composed of a Fe-rich core and a silicate-dominated mantle compatible with that of the Earth. On a population level, we find two tentative trends in the density-metallicity and density-insolation parameter space for the low-density super-Earths, which may hint at their composition. With a 8$\%$ precision in radius and 12$\%$ precision in mass, TOI-244 b is among the most precisely characterized super-Earths, which, together with the likely presence of an extended hydrosphere, makes it a key target for atmospheric observations.Comment: Accepted for publication in A&

An unusually low-density super-Earth transiting the bright early-type M-dwarf GJ 1018 (TOI-244)

Context. Small planets located at the lower mode of the bimodal radius distribution are generally assumed to be composed of iron and silicates in a proportion similar to that of the Earth. However, recent discoveries are revealing a new group of low-density planets that are inconsistent with that description. Aims. We intend to confirm and characterize the TESS planet candidate TOI-244.01, which orbits the bright (K = 7.97 mag), nearby (d = 22 pc), and early-type (M2.5 V) M-dwarf star GJ 1018 with an orbital period of 7.4 days. Methods. We used Markov chain Monte Carlo methods to model 57 precise radial velocity measurements acquired by the ESPRESSO spectrograph together with TESS photometry and complementary HARPS data. Our model includes a planetary component and Gaussian processes aimed at modeling the correlated stellar and instrumental noise. Results. We find TOI-244 b to be a super-Earth with a radius of Rp = 1.52 ± 0.12 R⊕ and a mass of Mp = 2.68 ± 0.30 M⊕. These values correspond to a density of ρ = 4.2 ± 1.1 g cm−3, which is below what would be expected for an Earth-like composition. We find that atmospheric loss processes may have been efficient to remove a potential primordial hydrogen envelope, but high mean molecular weight volatiles such as water could have been retained. Our internal structure modeling suggests that TOI-244 b has a 479−96+128 km thick hydrosphere over a 1.17 ± 0.09 R⊕ solid structure composed of a Fe-rich core and a silicate-dominated mantle compatible with that of the Earth. On a population level, we find two tentative trends in the density-metallicity and density-insolation parameter space for the low-density super-Earths, which may hint at their composition. Conclusions. With a 8% precision in radius and 12% precision in mass, TOI-244 b is among the most precisely characterized super-Earths, which, together with the likely presence of an extended hydrosphere, makes it a key target for atmospheric observations