376 research outputs found
Photo-induced volume changes in selenium. Tight-binding molecular dynamics study
Tight-binding molecular dynamics simulations of photo-excitations in small Se
clusters (isolated Se ring and helical Se chain) and glassy Se networks
(containing 162 atoms) were carried out in order to analyse the photo induced
instability inside the amorphous selenium. In the cluster systems after taking
an electron from the highest occupied molecular orbital to the lowest
unoccupied molecular orbital a bond breaking occurs. In the glassy networks
photoinduced volume expansion was observed and at the same time the number of
coordination defects changed significantly due to illumination
Carrier-Induced Magnetic Circular Dichloism in the Magnetoresistive Pyrochlore Tl2Mn2O7
Infrared magnetic circular dichloism (MCD), or equivalently magneto-optical
Kerr effect, has been measured on the Tl2Mn2O7 pyrochlore, which is well known
for exhibiting a large magnetoresistance around the Curie temperature T_C ~ 120
K. A circularly polarized, infrared synchrotron radiation is used as the light
source. A pronounced MCD signal is observed exactly at the plasma edge of the
reflectivity near and below T_c. However, contrary to the conventional behavior
of MCD for ferromagnets, the observed MCD of Tl2Mn2O7 grows with the applied
magnetic field, and not scaled with the internal magnetization. It is shown
that these results can be basically understood in terms of a classical
magnetoplasma resonance. The absence of a magnetization-scaled MCD indicates a
weak spin-orbit coupling of the carriers in Tl2Mn2O7. We discuss the present
results in terms of the microscopic electronic structures of Tl2Mn2O7.Comment: 5 pages, 5 figures, submitted to J. Phys. Soc. Jp
Electrical properties of a-antimony selenide
This paper reports conduction mechanism in a-\sbse over a wide range of
temperature (238K to 338K) and frequency (5Hz to 100kHz). The d.c. conductivity
measured as a function of temperature shows semiconducting behaviour with
activation energy E= 0.42 eV. Thermally induced changes in the
electrical and dielectric properties of a-\sbse have been examined. The a.c.
conductivity in the material has been explained using modified CBH model. The
band conduction and single polaron hopping is dominant above room temperature.
However, in the lower temperature range the bipolaron hopping dominates.Comment: 9 pages (RevTeX, LaTeX2e), 9 psfigures, also at
http://pu.chd.nic.in/ftp/pub/san16 e-mail: gautam%[email protected]
Intermediate Valence Model for the Colossal Magnetoresistance in Tl_{2}Mn_{2}O_{7}
The colossal magnetoresistance exhibited by Tl_{2}Mn_{2}O_{7} is an
interesting phenomenon, as it is very similar to that found in perovskite
manganese oxides although the compound differs both in its crystalline
structure and electronic properties from the manganites. At the same time,
other pyrochlore compounds, though sharing the same structure with
Tl_{2}Mn_{2}O_{7}, do not exhibit the strong coupling between magnetism and
transport properties found in this material. Mostly due to the absence of
evidence for significant doping into the Mn-O sublattice, and the tendency of
Tl to form conduction bands, the traditional double exchange mechanism
mentioned in connection with manganites does not seem suitable to explain the
experimental results in this case. We propose a model for Tl_{2}Mn_{2}O_{7}
consisting of a lattice of intermediate valence ions fluctuating between two
magnetic configurations, representing Mn-3d orbitals, hybridized with a
conduction band, which we associate with Tl. This model had been proposed
originally for the analysis of intermediate valence Tm compounds. With a
simplified treatment of the model we obtain the electronic structure and
transport properties of Tl_{2}Mn_{2}O_{7}, with good qualitative agreement to
experiments. The presence of a hybridization gap in the density of states seems
important to understand the reported Hall data.Comment: 8 pages + 5 postscript fig
Correlated percolation and the correlated resistor network
We present some exact results on percolation properties of the Ising model,
when the range of the percolating bonds is larger than nearest-neighbors. We
show that for a percolation range to next-nearest neighbors the percolation
threshold Tp is still equal to the Ising critical temperature Tc, and present
the phase diagram for this type of percolation. In addition, we present Monte
Carlo calculations of the finite size behavior of the correlated resistor
network defined on the Ising model. The thermal exponent t of the conductivity
that follows from it is found to be t = 0.2000 +- 0.0007. We observe no
corrections to scaling in its finite size behavior.Comment: 16 pages, REVTeX, 6 figures include
Electronic transport and optical properties of proton-implanted amorphous 2CdO Ă GeO 2 Âźlms
Abstract Films of amorphous 2CdO Ă GeO 2 with the band gap of 3.4 eV were prepared by rf sputtering. Protons were implanted into the Âźlms at doses 2 Ă 10 14 ±2 Ă 10 16 cm Ă2 . On going from 2 Ă 10 14 to 2 Ă 10 16 cm Ă2 , dc conductivity at 300 K increased from 10 1 S cm Ă1 and its activation energy fell from 3 Ă 10 19 cm Ă3 ), which is larger by several orders of magnitude than that of existing amorphous semiconductors. No degradation of visible transparency was observed in all implanted samples. The optical conductivity may be described by the classical Drude formula with a single relaxation time, 2X7 Ă 10 Ă15 s. X-ray radial distribution function revealed that the local structure around Cd 2 (coordination number; 4) in the amorphous state is close to that of crystalline Cd 2 GeO 4 and the amorphous state has a distribution of Cd±O±Cd bond angles. We assume that the electronic transport properties of the present material primarily originate from the extended conduction bands composed of Cd 5s orbitals.
Origin and pressure dependence of ferromagnetism in A2Mn2O7 pyrochlores (A=Y, In, Lu, and Tl)
Non-conventional mechanisms have been recently invoked in order to explain
the ferromagnetic ground state of A2Mn2O7 pyrochlores (A=Y, In, Lu and Tl) and
the puzzling decrease of their Curie temperatures with applied pressure. Here
we show, using a perturbation expansion in the Mn-O hopping term, that both
features can be understood within the superexhange model, provided that the
intra-atomic oxygen interactions are properly taken into account. An additional
coupling between the Mn ions mediated by the In(5s)/Tl(6s) bands yields the
higher Tc's of these two compounds, this mechamism enhancing their
ferromagnetism for higher pressures.Comment: 7 pages and 2 figures submitted to Phys. Rev. B, missing text adde
First order transition and phase separation in pyrochlores with colossal-magnetoresistance
TlMnO pyrochlores present colossal magnetoresistance (CMR)
around the long range ferromagnetic ordering temperature (T). The
character of this magnetic phase transition has been determined to be first
order, by purely magnetic methods, in contrast to the second order character
previously reported by Zhao et al. (Phys. Rev. Lett. 83, 219 (1999)). The
highest CMR effect, as in TlCdMnO, corresponds to a
stronger first order character. This character implies a second type of
magnetic interaction, besides the direct superexchange between the Mn
ions, as well as a phase coexistence. A model is proposed, with a complete
Hamiltonian (including superexchange and an indirect interaction), which
reproduce the observed phenomenology.Comment: 6 pages. Figures include
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