Near-infrared remote sensing of Los Angeles trace gas distributions from a mountaintop site

The Los Angeles basin is a significant anthropogenic source of major greenhouse gases (CO2 and CH4) and the pollutant CO, contributing significantly to regional and global climate change. We present a novel approach for monitoring the spatial and temporal distributions of greenhouse gases in the Los Angeles basin using a high-resolution spectroscopic remote sensing technique. A new Fourier transform spectrometer called CLARS-FTS has been deployed since May, 2010, at Jet Propulsion Laboratory (JPL)'s California Laboratory for Atmospheric Remote Sensing (CLARS) on Mt. Wilson, California, for automated long-term measurements of greenhouse gases. The instrument design and performance of CLARS-FTS are presented. From its mountaintop location at an altitude of 1673 m, the instrument points at a programmed sequence of ground target locations in the Los Angeles basin, recording spectra of reflected near-IR solar radiation. Column-averaged dry-air mole fractions of greenhouse gases (XGHG) including XCO2, XCH4, and XCO are retrieved several times per day for each target. Spectra from a local Spectralon® scattering plate are also recorded to determine background (free tropospheric) column abundances above the site. Comparisons between measurements from LA basin targets and the Spectralon® plate provide estimates of the boundary layer partial column abundances of the measured species. Algorithms are described for transforming the measured interferograms into spectra, and for deriving column abundances from the spectra along with estimates of the measurement precision and accuracy. The CLARS GHG measurements provide a means to infer relative, and possibly absolute, GHG emissions

In situ multi-frequency measurements of magnetic susceptibility as an indicator of planetary regolith maturity

Space weathering is now generally accepted to modify the optical and magnetic properties of airless planetary regoliths such as those on the Moon and Mercury. Under micrometeorite and ion bombardment, ferrous iron in such surfaces is reduced to metallic iron spheres, found in amorphous coatings on almost all exposed regolith grains. The size and number distribution of these particles and their location in the regolith all determine the nature and extent of the optical and magnetic changes. These parameters in turn reflect the formation mechanisms, temperatures, and durations involved in the evolution of the regolith. Studying them in situ is of intrinsic value to understanding the weathering process, and useful for determining the maturity of the regolith and providing supporting data for interpreting remotely sensed mineralogy. Fine-grained metallic iron has a number of properties that make it amenable to magnetic techniques, of which magnetic susceptibility is the simplest and most robust. The magnetic properties of the lunar regolith and laboratory regolith analogues are therefore reviewed and the theoretical basis for the frequency dependence of magnetic susceptibility presented. Proposed here is then an instrument concept using multi-frequency measurements of magnetic susceptibility to confirm the presence of fine grained magnetic material and attempt to infer its quantity and size distribution. Such an instrument would be invaluable on a future mission to an asteroid, the Moon, Mercury or other airless rocky Solar System body

Operation of Third Generation JPL Electronic Nose on the International Space Station

Copyright © 2009 SAE International The Third Generation ENose is an air quality monitor designed to operate in the environment of the US Lab on the International Space Station (ISS). It detects a selected group of analytes at target concentrations in the ppm regime at an environmental temperature range of 18- 30 oC, relative humidity from 25- 75 % and pressure from 530 to 760 torr. This device was installed and activated on ISS on Dec. 9, 2008 and has been operating continuously since activation. Data are downlinked and analyzed weekly. Results of analysis of ENose monitoring data show the short term presence of low concentration of alcohols, octafluoropropane and formaldehyde as well as frequent short term unknown events

Conductometric Sensors for Detection of Elemental Mercury Vapor

Several organic and inorganic materials have been tested for possible incorporation into a sensing array in order to add elemental mercury vapor to the suite of chemical species detected. Materials have included gold films, treated gold films, polymer-carbon composite films, gold-polymer-carbon composite films and palladium chloride sintered films. The toxicity of mercury and its adverse effect on human and animal health has made environmental monitoring of mercury in gas and liquid phases important (1,2). As consumer products which contain elemental mercury, such as fluorescent lighting, become more widespread, the need to monitor environments for the presence of vapor phase elemental mercury will increase. Sensors in use today to detect mercury in gaseous streams are generally based on amalgam formation with gold or other metals, including noble metals and aluminum. Recently, NASA has recognized a need to detect elemental mercury vapor in the breathing atmosphere of the crew cabin in spacecraft and has requested that such a capability be incorporated into the JPL Electronic Nose (3). The detection concentration target for this application is 10 parts-per-billion (ppb), or 0.08 mg/m3. In order to respond to the request to incorporate mercury sensing into the JPL Electronic Nose (ENose) platform, it was necessary to consider only conductometric methods of sensing, as any other transduction method would have required redesign of the platform. Any mercury detection technique which could not be incorporated into the existing platform, such as an electrochemical technique, could not be considered

Development of the Third Generation JPL Electronic Nose for International Space Station Technology Demonstration

Copyright © 2007 SAE International The capabilities of the JPL Electronic Nose have been expanded to include characteristics required for a Technology Demonstration schedule on the International Space Station (ISS) in 2008-2009 [1,2]. Concurrently, to accommodate specific needs on ISS, the processes, tools and analyses which influence all aspects of development of the device have also been expanded. The Third Generation ENose developed for this program uses two types of sensor substrates, newly developed inorganic and organic sensor materials, redesigned electronics, onboard near real-time data analysis and power and data interfaces specifically for ISS. This paper will discuss the Third Generation ENose with a focus on detection of mercury in the parts-per-billion range

Expanding the Capabilities of the JPL Electronic Nose for an International Space Station Technology Demonstration

An array-based sensing system based on polymer/carbon composite conductometric sensors is under development at JPL for use as an environmental monitor in the International Space Station. Sulfur dioxide has been added to the analyte set for this phase of development. Using molecular modeling techniques, the interaction energy between SO2 and polymer functional groups has been calculated, and polymers selected as potential SO2 sensors. Experiment has validated the model and two selected polymers have been shown to be promising materials for SO2 detection